Abstract
Adsorption and separation performances of a microporous silica-based (DAMIA-EH + TOA)/SiO2-P adsorbent towards Pd(II) were systematically investigated under the effect of contact time, temperature, concentration of nitric acid, chromatography etc. in a simulated high-level liquid waste containing 14 kinds of representative co-existing metal ions. Successful recovery of around 97.95% Pd(II) was achieved under the elution with 0.01 M Tu (pH = 2) solution in column experiment.
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Natarajan R (2017) Reprocessing of spent nuclear fuel in India: present challenges and future programme. Prog Nucl Energy 101:118–132
Jayakumar M, Venkatesan KA, Srinivasan TG, Rao PRV (2009) Studies on the feasibility of electrochemical recovery of palladium from high-level liquid waste. Electrochim Acta 54:1083–1088
Ruhela R, Singh AK, Tomar BS, Hublia RC (2014) Separation of palladium from high level liquid waste–a review. RSC Adv 4:24344–24350
Uruga K, Sawada K, Enokida Y, Yamamoto I (2008) Vitrification of high-level radioactive waste considering the behavior of platinum group metals. Prog Nucl Energy 50:514–517
Wu Y, Kim SY, Tozawa D, Ito T, Tada T, Hitomi K, Kuraoka E, Yamazaki H, Ishii K (2012) Equilibrium and kinetic studies of selective adsorption and separation for strontium using DtBuCH18C6 loaded resin. J Nucl Sci Technol 49:320–327
Turanov AN, Karandashev VK, Proshin AN (2008) Extraction of Palladium(II) from nitric acid solutions with 1-Benzoyl-3-[6-(3-benzoyl-thioureido)-hexyl]-thiourea. Solvent Extr Ion Exch 26:360–374
Ruhela R, Sharma JN, Tomar BS, Panja S, Tripathi SC, Hubli RC, Suri AK (2010) N, N, N′, N′-tetra(2-ethylhexyl) thiodiglycolamide T(2EH)TDGA: a novel ligand for the extraction of palladium from high level liquid waste (HLLW). Radiochim Acta 98:209–214
Xu YL, Kim SY, Ito T, Tokuda H, Hitomi K, Ishii K (2015) Adsorption behavior of platinum group metals onto a silica-based (Crea + Dodec)/SiO2-P extraction resin from simulated high level liquid waste. Sep Sci Technol 50:260–266
Narita H, Tanaka M, Morisaku K (2008) Palladium extraction with N, N, N′, N′-tetra-n-octyl-thiodiglycolamide. Miner Eng 21:483–488
Ruhela R, Sharma JN, Tomar BS, Singh KK, Kumar M, Bajaj PN, Hubli RC, Suri AK (2012) Studies on hydrolytic and radiolytic stability of N, N, N′, N′-tetra-(2-ethylhexyl) thiodiglycolamide T(2EH)TDGA. Radiochim Acta 100:37–44
Ruhela R, Singh KK, Tomar BS, Sharma JN, Kumar M, Hubli RC, Suri AK (2012) Amberlite XAD-16 functionalized with 2-acetyl pyridine group for the solid phase extraction and recovery of palladium from high level waste solution. Sep Purif Technol 99:36–43
Mehrani K, Mehrani A, Amini MM, Sadeghi O, Tavassoli N (2011) Dipyridylamine-modified nanoporous silicas as new sorbents for the separation and pre-concentration of palladium. Microchim Acta 173:521–527
Xiao CL, Wang CZ, Yuan LY, Li B, He H, Wang SA, Zhao YL, Chai ZF, Shi WQ (2014) Excellent selectivity for actinides with a tetradentate 2,9-diamide-1,10-phenanthroline ligand in highly acidic solution: a hard—soft donor combined strategy. Inorg Chem 53:1712–1720
Sasaki Y, Tsubata Y, Kitatsuji Y, Sugo Y, Shirasu N, Morita Y, Kimura T (2013) Extraction behavior of metal ions by TODGA, DOODA, MIDOA, and NTaamide extractants from HNO3 to n-dodecane. Solvent Extr Ion Exch 31:401–415
Sasaki Y, Morita K, Shimazaki S, Tsubata Y, Ozawa M (2016) Masking effects for Mo, Re, Pd and Ru by S and N-donor reagents through MIDOA and Ntaamide extraction. Solvent Extr Res Dev Jpn 23:161–174
Ning SY, Zhou J, Zhang SC, Zhang W, Wei YZ (2019) Synthesis of soft N-donor isoPentyl-BTBP and study on its removal of actinides from high level liquid waste. Radiochim Acta 108:5619
Ning SY, Zhang SC, Zhang W, Zhou J, Wang SY, Wang XP, Wei YZ (2020) Separation and recovery of Rh, Ru and Pd from nitrate solution with a silica-based IsoBu-BTP/SiO2-P adsorbent. Hydrometallurgy 191:105207
Zhang SC, Ning SY, Zhou J, Wang SY, Wang XP, Wei YZ (2020) New insight into the adsorption of ruthenium, rhodium, and palladium from nitric acid solution by a silica-polymer adsorbent. Nucl Sci Tech 31:201
Wu Y, Lee CP, Mimura H, Zhang XX, Wei YZ (2018) Stable solidification of silica-based ammonium molybdophosphate byallophane: application to treatment of radioactive cesium in secondary solid wastes generated from fukushima. J Hazard Mater 341:46–54
Wang QL, Sang HJ, Chen LF, Wu Y, Wei YZ (2020) Selective separation of Pd(II) through ion exchange and oxidation-reduction with hexacyanoferrates from high-level liquid waste. Sep Purif Technol 231:115932
Yu Q, Ning SY, Zhang W, Wang XP, Wei YZ (2018) Recovery of scandium from sulfuric acid solution with a macro porous TRPO/SiO2-P adsorbent. Hydrometallurgy 181:74–81
Khayambashi A, Wang XL, Wei YZ (2016) Solid phase extraction of uranium (VI) from phosphoric acid medium using macroporous silica-based D2EHPA-TOPO impregnated polymeric adsorbent. Hydrometallurgy 164:90–96
Shu QD, Khayambashi A, Wang XP, Wei YZ (2018) Studies on adsorption of rare earth elements from nitric acid solution with macroporous silica-based bis(2-ethylhexyl)phosphoric acid impregnated polymeric adsorbent. Adsorpt Sci Technol 36:1049–1065
Wu Y, Kim SY, Tozawa D, Ito T, Tada T, Hitomi K, Kuraoka E, Yamazaki H, Ishii K (2012) Study on selective separation of cesium from high level liquid waste using a macroporous silica-based supramolecular recognition absorbent. J Radioanal Nucl Chem 293:13–20
Takeda Y, Ishida K (2001) Thin-layer chromatographic behavior of rare earths on silica gel with aqueous alkaline earth metal nitrate solutions as mobile phases. Fresenius J Anal Chem 370:371–376
Sasaki Y, Ozawa M, Kimura T, Ohashi K (2009) 2,2′-(Methylimino)bis(N, N-dioctylacetamide) (MIDOA), A new tridentate extractant for Technetium(VII), Rhenium(VII), Palladium(II), and Plutonium(IV). Solvent Extr Ion Exch 27:378–394
Petalaa E, Dimos K, Douvalis A, Bakas T, Tucek J, Zboril R, Karakassides MA (2013) Nanoscale zero-valent iron supported on mesoporous silica: characterization and reactivity for Cr(VI) removal from aqueous solution. J Hazard Mater 261:295–306
Liu RQ, Wang XP, Ning SY, Wei YZ, Yang JL, Zhao YP, Ding YQ (2015) Adsorption behavior of 241Am(III) and Eu(III) by silica/polymer-based isoHex-BTP adsorbent from nitric acid solution. Nucl Sci Tech 26:61–68
Ito T, Kim SY, Xu YL, Hitomi K, Ishii K, Nagaishi R, Kimura T (2013) Adsorption behaviors of platinum group metals in simulated high level liquid waste ssing macroporous (MOTDGA-TOA)/SiO2-P silica-based absorbent. Sep Sci Technol 48:2616–2625
Ning SY, Zhang SC, Zhou J, Zhang W, Wei YZ (2019) Salt-free separation of 241Am(III) from lanthanides by highly stable macroporous silica-polymer based Me2-CA-BTP/SiO2-P adsorbent. J Radioanal Nucl Chem 322:1023–1030
Favre-Réguillon A, Draye M, Cote G, Czerwinsky KR (2019) Insights in uranium extraction from spent nuclear fuels using dicyclohexano-18-crown-6-fate of rhenium as technetium homolog. Sep Purif Technol 209:338–342
Yuan LY, Zhu L, Xiao CL, Wu QY, Zhang N, Yu JP, Chai ZF, Shi WQ (2017) Large-Pore 3D cubic mesoporous (KIT-6) hybrid bearing a hard—soft donor combined ligand for enhancing U(VI) capture: an experimental and theoretical investigation. ACS Appl Mater Interfaces 9:3774–3784
Wu Y, Zhang XX, Kim SY, Wei YZ (2016) Simultaneous separation and recovery of Cs(I) and Sr(II) using a hybrid macrocyclic compounds loaded adsorbent. Kinetic, equilibrium and dynamic adsorption studies. J Nucl Sci Technol 53:1968–1977
Foo KY, Hameed BH (2010) Insights into the modeling of adsorption isotherm systems. Chem Eng J 156:2–10
Peng XJ, Cui Y, Ma JF, Li YL, Sun GX (2017) Extraction of lanthanide ions with N, N, N′, N′-tetrabutyl-3-oxadiglycolamide from nitric acid media. Nucl Sci Tech 87:9077
Ghosal PS, Gupta AK (2017) Determination of thermodynamic parameters from Langmuir isotherm constant-revisited. J Mol Liq 225:137–146
Zou Q, Wu Y, Shu QD, Ning SY, Wang XP, Wei YZ, Tang FD (2018) Separation of palladium along with minor actinides by isoBu-BTP/SiO2-P Adsorbent from high-level liquid waste. J Chem Eng Data 63:2931–2939
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Wu, H., Kubota, M., Osawa, N. et al. Adsorption and separation behavior of palladium(II) on a silica-based hybrid donor adsorbent from simulated high-level liquid waste. J Radioanal Nucl Chem 326, 1323–1331 (2020). https://doi.org/10.1007/s10967-020-07414-z
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DOI: https://doi.org/10.1007/s10967-020-07414-z