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Combination of N’-N’-di-n-hexyl-thiodiglycolamide and 2,2’-[(2-ethylhexyl)imino]bis[N,N-bis(2-ethylhexyl) acetamide] for the enhanced adsorption of palladium ions from simulated high-level liquid waste

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Abstract

A N’-N’-di-n-hexyl-thiodiglycolamide and 2,2’-[(2-ethylhexyl)imino]bis[N,N-bis(2-ethylhexyl)acetamide] impregnated porous silica-based adsorbent was prepared for enhancing the adsorption of palladium ions from simulated high-level liquid waste. The adsorbent exhibited a relatively fast palladium response and selectivity without the use of additional modification reagents. Palladium ions were adsorbed over a wide nitric acid range of 0.6−5 M and a broad temperature range of 288−323 K. The uniform distribution of adsorbed palldium ions onto the study adsorbent was confirmed by PIXE. Successful recovery of more than 90% of the palladium ions was achieved using 0.1 M thiourea via separation by column experiments. Based on the obtained data, it is expected that the prepared adsorbent can be used for the practical separation of palladium ions from high-level liquid waste.

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Authors and Affiliations

  1. Department of Quantum Science and Energy Engineering, Graduate School of Engineering, Tohoku University, Sendai, 6-6-01-2 Aza-Aoba-Aramaki, Aoba-ku, Miyagi, 980-8579, Japan

    Masahiko Kubota, Hao Wu & Seong-Yun Kim

  2. Japan Nuclear Fuel Chemical Analysis Co. Ltd, Rokkasho-mura, Kamikita-gun, Aomori, 039-3212, Japan

    Masahiko Kubota

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  1. Masahiko Kubota
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  2. Hao Wu
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Correspondence to Seong-Yun Kim.

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Kubota, M., Wu, H. & Kim, SY. Combination of N’-N’-di-n-hexyl-thiodiglycolamide and 2,2’-[(2-ethylhexyl)imino]bis[N,N-bis(2-ethylhexyl) acetamide] for the enhanced adsorption of palladium ions from simulated high-level liquid waste. J Radioanal Nucl Chem 331, 1731–1740 (2022). https://doi.org/10.1007/s10967-022-08230-3

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  • DOI: https://doi.org/10.1007/s10967-022-08230-3

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