Abstract
Isotopes of hydrogen (3H, 2H) and oxygen (18O) are perfect candidates for groundwater tracers. A survey of isotopic composition of 34 groundwater samples and one Lake from Vojvodina region (Serbia) is presented here. Tritium activity concentration and stable isotope composition (δ2H, δ18O), as well as deuterium excess, were determined. The groundwater samples lie on the groundwater regression line. Minor deviations and a few lower deuterium excess values indicate waters recharged in a different climate regime and subjected to evaporation, respectively. According to the obtained results, most of the analyzed groundwater can be characterized as modern waters, recharged mostly from precipitation.
Similar content being viewed by others
Notes
ISO 5667-3:2012. Water quality—Sampling - Part 3: Preservation and handling of water samples.
ISO 5667-11:2009. Water quality—Sampling - Part 11: Guidance on sampling of groundwaters.
References
Clark I, Fritz P (1997) Environmental isotopes in hydrogeology. Lewis Publishing, Boca Raton, p 328
Cook PG, Herczeg AL (2000) Environmental tracers in subsurface hydrology. Springer, New York. ISBN 978-0-7923-7707-8
Suckow A (2014) The age of groundwater—definitions, models and why we do not need this term. Appl Geochem 50:222–230
Münnich KO (1957) Messung natürlichen Radiokohlenstoffs mit einem CO2-Proportionalzählrohr, Ph.D. thesis, Universität Heidelberg, Heidelberg, West Germany
IAEA (2013) isotope methods for dating old groundwater. International Atomic Energy Agency, Vienna
Mook WG (2001) Environmental isotopes in the hydrological cycle, principles and applications, vols I, IV, V, technical documents in hydrology no. 39, IAEA-UNESCO
Santos IR, Zhang C, Mahera DT, Atkins ML, Holland R, Morgenstern U, Li L (2017) Assessing the recharge of a coastal aquifer using physical observations, tritium, groundwater chemistry and modeling. Sci Total Environ 580:367–379
Kazemi GA, Lehr JH, Perrochet P (2006) Groundwater age. Wiley, New York. ISBN 978-0-471-71819-2
Kralik M (2015) How to estimate mean residence times of groundwater. Procedia Earth Planet Sci 13:301–306
Lucas LL, Unterweger MP (2000) Comprehensive review and critical evaluation of the half-life of tritium. J Res Natl Inst Stand Technol 105:541–549
Rohden C, Kreuzer A, Chen Z, Kipfer R, Aeschbach-Hertig W (2010) Characterizing the recharge regime of the strongly exploited aquifers of the North China Plain by environmental tracers. Water Resour Res 46(5), CiteID W05511
Gröning M, Rozanski K (2003) Uncertainty assessment of environmental tritium measurements in water. Accred Qual Assur 8(7–8):359–366
Nikolov J, Krajcar Bronić I, Todorović N, Stojković I, Barešić J, Petrović-Pantić T (2018) Tritium in water: hydrology and health implications. In: Marija J (ed) Tritium advances in research and application. NOVA Science Publisher, New York, pp 157–213. ISBN 978-1-53613-507-7
Janković M, Janković B, Todorović D, Ignjatović L (2012) Tritium concentration analysis in atmospheric precipitation in Serbia. J Environ Sci Health A Tox Hazard Subst Environ Eng 47(5):669–674. https://doi.org/10.1080/10934529.2012.660039
Vreča P, Krajcar Bronić I, Horvatinčić N, Barešić J (2006) Isotopic characteristics of precipitation in Slovenia and Croatia: comparison of continental and maritime stations. J Hydrol 330(3–4):457–469. https://doi.org/10.1016/j.jhydrol.2006.04.0
Vreča P, Krajcar Bronić I, Leis A, Brenčić M (2008) Isotopic composition of precipitation in Ljubljana (Slovenia). Geologija (Ljubljana) 51:169–182
Vreča P, Krajcar Bronić I, Leis A, Demšar M (2014) Isotopic composition of precipitation at the station Ljubljana (Reaktor), Slovenia—period 2007–2010. Geologija 57:217–230
Krajcar Bronić I, Vreča P, Horvatinčić N, Barešić J, Obelić B (2006) Distribution of hydrogen, oxygen and carbon isotopes in the atmosphere of Croatia and Slovenia. Arhiv za higijenu rada i toksikologiju 57:23–29
Tomić M, Lazić M (2017) Healing waters of Vojvodina as a potential for development of the spa tourism, Educatio. Zadužbina Andrejević, Belgrade, p 119. ISBN 978-86-525-0300-1
Aksin V, Milosavljević S (1982) Geothermal research of SAP Vojvodina—research and use, Novi Sad, Serbia
Demić I, Vukićević Z (2005) Thermal spa “Banja Kanjiža”—an example of successful utilization of geothermal energy. In: Proceedings world geothermal congress 2005, Antalya, Turkey, 24–29 April 2005
Bašić Đ, Petrović J, Marić M, Dragutinović G, Gvozdenac B, Štrbac D (2009) Possibilities of using the energy potential of geothermal waters in Vojvodina region (on Serbian), Prometej, Novi Sad
Protić D (1995) Mineral and thermal water of Serbia. Special issue of Geoinstitute, Belgrade, book 17, p 269
Nikolov J, Todorović N, Janković M, Voštinar M, Bikit I, Vesković M (2013) Different methods for tritium determination in surface water by LSC. Appl Radiat Isotopes 71:51–56
Rozanski K, Gröning M (2004) Tritium assay in water samples using electrolytic enrichment and liquid scintillation spectrometry. In: Quantifying uncertainty in nuclear analytical measurements, IAEA-TECDOC-1401, IAEA, Vienna, pp 195–217
Gröning M, Auer R, Brummer D, Jaklitsch M, Sambandam C, Tanweer A, Tatzber H (2009) Increasing the performance of tritium analysis by electrolytic enrichment. Isotopes Environ Health Stud 45(2):118–125. https://doi.org/10.1080/10256010902872042
Barešić J, Krajcar Bronić I, Horvatinčić N, Obelić B, Sironić A, Kožar-Logar J (2011) Tritium activity measurement of water samples using liquid scintillation counter and electrolytical enrichment. In: Proceedings of the eight symposium of the croatian radiation protection association, 13–15 April 2011. Krk. Zagreb: HDZZ, pp 461–467
Barešić J, Horvatinčić N, Krajcar Bronić I, Obelić B (2010) Comparison of two techniques for low-level tritium measurement—gas proportional and liquid scintillation counting. In: Proceedings of the third European IRPA congress, full papers of poster presentations, Helsinki, Finland, June 2010: IRPA, 2010. P12-21-1-P12-21-5, pp 1988–1992. http://www.irpa2010europe.com/pdfs/proceedings/S12-P12.pdf
Currie LA (1968) Limits of qualitative detection and quantification determination. Anal Chem 40(3):587–593
Picarro webpage (2018). http://www.picarro.com/technology/cavity_ring_down_spectroscopy
Busch KW, Busch MA (1997) Cavity ring-down spectroscopy: an ultra trace absorption measurement technique. In: ACS symposium series 720, Oxford
Motzer W (2007) Tritium age dating of groundwater. In: Hydro visions, vol 16, no 2. Groundwater Resources Association of California (2007)
Mazor E (2003) Chemical and isotopic groundwater hydrology. CRC Press, Boca Raton. ISBN 978-0824747046
Gibson JJ, Reid R (2010) Stable isotope fingerprint of open-water evaporation losses and effective drainage area fluctuations in a subarctic shield watershed. J Hydrol 381:142–150
Golobočanin D, Ogrinc N, Bondzić A, Miljević N (2007) Isotopic characteristics of meteoric waters in the Belgrade region. Isotop Environ Health Stud 43:355–367
Gat JR, Dansgaard W (1972) Stable isotope survey of the freshwater occurrences in Israel and the Jordan Rift Valley. J Hydrol 16:177–211
Cruz-San J, Araguas L, Rozanski K, Benavente J, Cardenal J, Hidalgo MC, Garcia-Lopez S, Martinez-Garrido JC, Moral F, Olias M (1992) Sources of precipitation over South-Eastern Spain and groundwater recharge—an isotopic study. Tellus 44B:226–236
Rozanski K, Araguas-Araguas L, Gonfiantini R (1993) Isotopic patterns in modern global precipitation. Geophys Monogr 78:1–36
Craig H (1961) Isotope variations in meteoric waters. Science 133:1702–1703
Acknowledgements
The authors acknowledge the financial support of the Ministry of Education, Science and Technological Development of Republic of Serbia, within the projects No. OI171002 and III43002, and the Provincial Secretariat for higher education and scientific research within the project "Radionuclides in drinking water and cancer incidence in Vojvodina" No. 142-451-2447/2018. This study was a part of the project No. 114-451-2538/2014 financed by Provincial Secretariat for higher education and scientific research of AP Vojvodina.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Nikolov, J., Krajcar Bronić, I., Todorović, N. et al. A survey of isotopic composition (2H, 3H, 18O) of groundwater from Vojvodina. J Radioanal Nucl Chem 320, 385–394 (2019). https://doi.org/10.1007/s10967-019-06469-x
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-019-06469-x