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Mössbauer and Raman spectroscopic study of oxidation and reduction of iron oxide nanoparticles promoted by various carboxylic acid layers

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Abstract

The effect of coating with nine different carboxylic acids (glycolic, propionic, lactic, malic, tartaric, citric, mandelic, caproic and caprylic) on nanostructured magnetite (D ~ 10 nm) was studied by Raman and photoacoustic, magnetic and 57Fe Mössbauer measurements. Mössbauer spectra of frozen suspensions showed dominantly magnetically split envelopes at lower temperatures, which were evaluated by hyperfine field distribution method. Mössbauer and Raman spectroscopy indicated similar variation of relative occurrence of magnetite and maghemite phases. These results are discussed on the basis of the hypothesis that different carboxylic acids can promote either the oxidation or reduction of iron oxide nanoparticles.

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Acknowledgements

This work was supported by grants of CAPES (No A127/2013) and OTKA (No K115913 and K115784). This work was carried out within the Agreement of Cooperation between Eötvös Loránd University (Budapest) and Universidade de Brasília (Brasília).

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Authors and Affiliations

  1. Department of Physics, University of Brasília, Brasília, DF, Brazil

    Sebastiao William da Silva, Luciana Rebelo Guilherme, Aderbal Carlos de Oliveira, Vijayendra Kumar Garg, Pedro Augusto Matos Rodrigues, José Antonio Huamaní Coaquira, Queila da Silva Ferreira & Guilherme Henrique Ferreira de Melo

  2. Institute of Chemistry, Eötvös Loránd University, Budapest, Hungary

    Attila Lengyel, Roland Szalay, Zoltán Homonnay & Ernő Kuzmann

  3. Research Centre for Natural Sciences, Hungarian Academy of Sciences, Budapest, Hungary

    Zoltán Klencsár & Gyula Tolnai

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  1. Sebastiao William da Silva
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  2. Luciana Rebelo Guilherme
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Correspondence to Ernő Kuzmann.

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da Silva, S.W., Guilherme, L.R., de Oliveira, A.C. et al. Mössbauer and Raman spectroscopic study of oxidation and reduction of iron oxide nanoparticles promoted by various carboxylic acid layers. J Radioanal Nucl Chem 312, 111–119 (2017). https://doi.org/10.1007/s10967-017-5195-0

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  • DOI: https://doi.org/10.1007/s10967-017-5195-0

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