Skip to main content
Log in

Adsorption of nickel on rhyolitic Slovak bentonites

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Radioisotope of nickel 63Ni is an important product of the neutron activation in engineering materials of nuclear power plants. Adsorption of nickel on Slovak rhyolitic bentonites Jelšový potok, Kopernica and Lastove was studied using batch method. Radionuclide 63Ni was used as a tracer. In this paper, we focused on effects of contact time, pH, competitive cations and equilibrium study. This study showed that Slovak rhyolitic bentonites are a promising candidate for removal of radionickel from aqueous solutions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Navrátil O, Hála J, Kopunec R, Lešetický L, Macášek F, Mikulaj V (1985) Jaderná chemie. Academia, Praha

    Google Scholar 

  2. Konya J, Nagy NM (2012) Nuclear and Radiochemsitry. Elsevier, Oxford, p 418

    Google Scholar 

  3. Chmielewská E, Kuruc J (2008) Odpady. Nakladanie stuhým neaktívnym a rádioaktívnym odpadom. Univerzita Komenského, Bratislava, p 336 s

    Google Scholar 

  4. Adamcová R, Haasová Z (2005) Vybrané fyzikálne vlastnosti bentonitu pre úložisko rádioaktívneho odpadu. Mineralia Slovaca 37(3):387–389

    Google Scholar 

  5. Adamcová R, Frankovská J, Durmeková T (2009) Engineering geological clay research for a radioactive waste repository in Slovakia. Acta geologica slovaca 1–2:71–82

    Google Scholar 

  6. Galamboš M, Rosskopfová O, Rajec P (2011) Geotechnické požiadavky na bentonitové bariéry v hlbinných úložiskách pre rádioaktívny odpad a vyhoreté jadrové palivo. Bezpečnost jaderné energie 19(57):38–44

    Google Scholar 

  7. Galamboš M, Rosskopfová O, Kufčáková J, Rajec P (2011) Utilization of Slovak bentonites in deposition of high-level radioactive waste and spent nuclear fuel. J Radioanal Nucl Chem 288(3):765–777

    Article  Google Scholar 

  8. Adamcova R (2002) Retardation capability of mineral linings of waste disposal sites. Acta Geologica Universitatis Comenianae 57:5–33

    CAS  Google Scholar 

  9. Stríček I, Šucha V, Uhlík P, Madejová J (2006) Zvetrávanie smektitu na ložiskách bentonitu. Mineralia Slovaca 38:337–342

    Google Scholar 

  10. Andrejkovičová S, Madejová J, Czímerová A, Galko I, Dohrmann R, Komadel P (2006) Mineralogy and chemistry of Fe-rich bentonite from the Lieskovec deposit (Central Slovakia). Geol Carpath 57(5):371–378

    Google Scholar 

  11. Andrejkovičová S, Janotka I, Komadel P (2008) Evaluation of geotechnical properties of bentonite from Lieskovec deposit, Slovakia. Appl Clay Sci 38(2–4):297–303

    Article  Google Scholar 

  12. Osacký M, Honty M, Madejová J, Bakas T, Šucha V (2009) Experimental interactions of Slovak bentonites with metallic iron. Geol Carpath 60(6):535–543

    Article  Google Scholar 

  13. Kolaříková I, Přikryl R, Hanus R, Jelínek E (2005) Thermal loading of smectite-rich rocks: natural processes vs. laboratory experiments. Appl Clay Sci 29(3–4):215–223

    Article  Google Scholar 

  14. Přikryl R, Ryndová T, Boháč J, Weishauptová Z (2003) Microstructures and physical properties of “backfill”clays: comparison of residual and sedimentary montmorillonite clays. Appl Clay Sci 23(1–4):149–156

    Article  Google Scholar 

  15. Stríček I, Šucha V, Uhlík P, Madejová J, Galko I (2009) Mineral stability of Fe-rich bentonite in the Mock-Up-CZ experiment. Geol Carpath 60(5):431–436

    Google Scholar 

  16. Osacký M, Šucha V, Czímerová J, Madejová J (2010) Reaction of smectites with iron in a nitrogen atmosphere at 75°C. Appl Clay Sci 50(2):237–244

    Article  Google Scholar 

  17. Lee JO, Kang IM, Cho WJ (2010) Smectite alteration and its influence on the barrier properties of smectite clay for a repository. Appl Clay Sci 47:99–104

    Article  CAS  Google Scholar 

  18. Kolaříková I, Švandová J, Přikryl R, Vinšová H, Jedináková-Křižová V, Zeman J (2010) Mineralogical changes in bentonite barrier within Mock-Up-CZ experiment. Appl Clay Sci 47(1–2):10–15

    Article  Google Scholar 

  19. Deepthi Rani R, Sasidhar P (2012) Geochemical and thermodynamic aspects of sorption of strontium on kaolinite dominated clay samples at Kalpakkam. Environ Earth Sci 65(4):1265–1274

    Article  CAS  Google Scholar 

  20. Zhang M, Zhang H, Jia L, Cui S (2012) Salt content impact on the unsaturated property of bentonite–sand buffer backfilling materials. Nucl Eng Des http://dx.doi.org/10.1016/j.nucengdes.2012.05.012

  21. Yıldız B, Erten HN, Kış M (2011) The sorption behavior of Cs+ ion on clay minerals and zeolite in radioactive waste management: sorption kinetics and thermodynamics. J Radioanal Nucl Chem 288:475–483

    Article  Google Scholar 

  22. Frankovská J, Prítrský J, Kordík J (2011) Vplyv vlastností kontaminantu a horninového prostredia na migráciu rádionuklidov. Geotechnika 4:39–44

    Google Scholar 

  23. Alaniz CD, Regil EO, Cruz GJC, Torres JR, Monroy JL (2012) Composition and properties of tectosilicate-uranium layers of soil. Eur J Chem 3(1):32–36

    Article  CAS  Google Scholar 

  24. Šucha V, Środoň J, Clauer N, Elsass F, Eberl DD, Kraus I, Madejova J (2001) Weathering of smectite and illite-smectite under temperate climatic conditions. Clay Miner 36:403–419

    Article  Google Scholar 

  25. Uhlík P, Majzlan J (2004) Conditions of mixed-layer illite-smectite formation at the deposit Dolná Ves on the southwest margin of Kremnica stratovolcano. Mineralia Slovaca 36:331–338

    Google Scholar 

  26. Honty M, Uhlík P, Šucha V, Čaplovičová M, Francu J, Clauer N, Biroň A (2004) Smectite-to-illite alteration on salt-bearing Bentonites (The East Slovak Basin). Clays Clay Miner 52(5):533–551

    Article  CAS  Google Scholar 

  27. Šucha V, Uhlík P, Madejová J, Petit S, Kraus I, Puškelová Ľ (2007) Particle properties of hydrothermal ammonium-bearing illite-smectite. Clays Clay Miner 55(1):36–44

    Article  Google Scholar 

  28. Andrejkovičová S, Pentrák M, Jankovič Ľ, Komadel P (2010) Sorption of heavy metal cations on rhyolitic and andesitic bentonites from Central Slovakia. Geol Carpath 61(2):163–171

    Google Scholar 

  29. Rajec P, Mátel L, Orechovská J, Šúcha J, Novák I (1996) Sorption of radionuclides on inorganic sorbents. J Radioanal Nucl Chem Art 208(2):477–486

    Article  CAS  Google Scholar 

  30. Meunier A, Velde B, Griffault L (1998) The reactivity of bentonites: a review. An application to clay barrier stability for nuclear waste storage. Clay Miner 33:187–196

    Article  CAS  Google Scholar 

  31. Mockovčiaková A, Orolínová Z (2009) Adsorption properties of modified bentonite clay. Cheminé Technologija 1(50):47–50

    Google Scholar 

  32. Jedináková-Křížová V, Zeman J, Vinšová H, Hanslík E (2010) Bentonite stability, speciation and migration behaviour of some critical radionuclides. J Radioanal Nucl Chem 286:719–727

    Article  Google Scholar 

  33. Galamboš M, Rosskopfová O, Paučová V, Rajec P, Adamcová R (2010) Sorpčné vlastnosti bentonitových bariér. Bezpečnost jaderné energie 18(56):37–39

    Google Scholar 

  34. Mockovčiaková A, Orolínová Z, Škvarla J (2010) Enhancement of the bentonite properties. J Hazard Mater 180:274–281

    Article  Google Scholar 

  35. Chang P, Wang X, Yu S, Wu W (2007) Sorption of Ni(II) on Na-rectorite from aqueous solution: effect of pH, ionic strength and temperature. Colloids Surf A 302:75–81

    Article  CAS  Google Scholar 

  36. Vieira MGA, Gimenes ML, da Silva MGC (2009) Modelling of the process of adsorption of nickel in bentonite clay. Chem Eng Trans 17:421–426

    Google Scholar 

  37. Hu T, Tan L (2012) Sorption/desorption of radionickel on/from Na-montmorillonite: kinetic and thermodynamic studies. J Radioanal Nucl Chem 292:103–112

    Article  CAS  Google Scholar 

  38. Brtáňová A, Melichová Z, Komadel P (2012) Sorption of Cu2+ from aqueous solution by Slovak bentonites. Ceram Silik 56(1):55–60

    Google Scholar 

  39. Liu Z, Yang J, Zhang Z, Chen L, Dong Y (2012) Study of 63Ni(II) sorption on CMC-bound bentonite from aqueous solutions. J Radioanal Nucl Chem 291:801–809

    Article  CAS  Google Scholar 

  40. Přikryl R, Weishauptová Z (2010) Hierarchical porosity of bentonite-based buffer and its modification due to increased temperature and hydration. Appl Clay Sci 47(1–2):163–170

    Article  Google Scholar 

  41. Šucha V (2001) Íly v geologických procesoch. Acta Geologica Universitas Comenianae, Bratislava, p 159 s

    Google Scholar 

  42. Kraus I, Číčel B, Šamajová E et al (1982) Origin and distribution of clays resulting from alteration of rhyolite volcanic rocks in Central Slovakia. Geol Zbor Geol Carpath 33(3):269–275

    CAS  Google Scholar 

  43. Koděra P, Uhlík P, Šottník P. et al. (2012) Fieldtrip Guide, Advanced enviromental geology 1. Mineral resources suitable for enviromental application. Banská Štiavnica, Slovakia

  44. Bailey SE, Olin TJ, Bricka RM, Adrian DD (1999) A review of potentially low-cost sorbents for heavy metals. Wat Res 33(11):2469–2479

    Article  CAS  Google Scholar 

  45. Fischer K (2002) Removal of heavy metals from soil components and soil by natural chelating agents. Water Air Soil Pollut 137:267–286

    Article  CAS  Google Scholar 

  46. Hu QH, Weng JQ, Wang JS (2010) Anthropogenic radionuclides in the environment. J Environ Radioact 101(6):426–437

    Article  CAS  Google Scholar 

  47. Vereš J, Orolínová Z, Mockovčiaková A, Jakabský Š (2010) Removal of nickel by natural and magnetically modified bentonite. Water Treatment Technologies for the Removal of High Toxicity Pollutants. Springer, Netherlands, pp 289–294

    Google Scholar 

  48. Malamis S, Katsou E, Haralambous KJ (2011) Study of Ni(II), Cu(II), Pb(II), and Zn(II) Removal Using Sludge and Minerals Followed by MF/UF. Water Air Soil Pollut 218:81–92

    Article  CAS  Google Scholar 

  49. Vieira MGA, Almeida Neto AF, Gimenes ML, da Silva MGC (2010) Sorption kinetics and equilibrium for the removal of nickel ions from aqueous phase on calcined Bofe bentonite clay. J Hazard Mater 177:362–371

    Article  CAS  Google Scholar 

  50. Pathak PN, Choppin GR (2006) Nickel(II) sorption on hydrous silica: a kinetic and thermodynamic study. J Radioanal Nucl Chem 268(3):467–473

    Article  CAS  Google Scholar 

  51. Hannachi Y, Shapovalov NA, Hannachi A (2010) Adsorption of Nickel from aqueous solution by the use of low-cost adsorbents. Korean J Chem Eng 27(1):152–158

    Article  CAS  Google Scholar 

  52. Zahng H, Chen L, Zhang L, Yu X (2011) Impact of environmental conditions on the adsorption behavior of radionuclide Ni(II) onto hematite. J Radioanal Nucl Chem 287:357–365

    Article  Google Scholar 

  53. Mou J, Wang G, Shi W, Zhang S (2012) Impact of environmental conditions on the sorption behavior of radionuclide 63Ni(II) onto hierarchically structured γ-MnO2. J Radioanal Nucl Chem 292:161–170

    Article  CAS  Google Scholar 

  54. Yang ST, Sheng GD, Guo ZQ, Tan XL, Xu JZ, Wang XK (2012) Investigation of radionuclide 63Ni(II) sequestration mechanisms on mordenite by batch and EXAFS spectroscopy study. Sci China Ser B: Chem. doi:10.1007/s11426-011-4482-9

    Google Scholar 

  55. Yang S, Li J, Lu Y, Chen Y, Wang X (2009) Sorption of Ni(II) on GMZ bentonite: effects of pH, ionic strength, foreign ions, humic acid and temperature. Appl Radiat Isot 67:1600–1608

    Article  CAS  Google Scholar 

  56. Zhi-rong L, Shao-qi Z (2010) Adsorption of copper and nickel on Na-bentonite. Process Saf Environ Prot 88:62–66

    Article  Google Scholar 

  57. Chen L, Gao B, Lu S, Dong Y (2011) Sorption study of radionickel on attapulgite as a function of pH, ionic strength and temperature. J Radioanal Nucl Chem 288:851–858

    Article  CAS  Google Scholar 

  58. Tahir SS, Rauf N (2003) Thermodynamic studies of Ni(II) adsorption onto bentonite from aqueous solution. J Chem Thermodyn 35:2003–2009

    Article  CAS  Google Scholar 

  59. Shao DD, Xu D, Wang SW, Fang QH, Wu WS, Dong YH, Wang XK (2009) Modeling of radionickel sorption on MX-80 bentonite as a function of pH and ionic strength. Sci China Ser B-Chem 52(3):362–371

    Article  CAS  Google Scholar 

  60. Fan Q, Shao D, Lu Y, Wu W, Wang X (2009) Effect of pH, ionic strength, temperature and humic substances on the sorption of Ni(II) to Na-attapulgite. Chem Eng J 150:188–195

    Article  CAS  Google Scholar 

  61. Song X, Wang S, Chen L, Zhang M, Dong Y (2009) Effect of pH, ionic strength and temperature on the sorption of radionickel on Na-montmorillonite. Appl Radiat Isot 67:1007–1012

    Article  CAS  Google Scholar 

  62. Galamboš M, Kufčáková J, Rajec P (2009) Sorption of strontium on Slovak bentonites. J Radioanal Nucl Chem 281(3):347–357

    Article  Google Scholar 

  63. Galamboš M, Kufčáková J, Rajec P (2009) Adsorption of cesium on domestic bentonites. J Radioanal Nucl Chem 281(3):485–492

    Article  Google Scholar 

  64. Galamboš M, Kufčáková J, Rosskopfová O, Rajec P (2010) Adsorption of cesium and strontium on natrified bentonites. J Radioanal Nucl Chem 283(3):803–813

    Article  Google Scholar 

  65. Galamboš M, Paučová V, Kufčáková J, Rosskopfová O, Rajec P, Adamcová R (2010) Cesium sorption on Bentonites and Montmorillonite K10. J Radioanal Nucl Chem 284(1):55–64

    Article  Google Scholar 

  66. Galamboš M, Daňo M, Rosskopfová O, Šeršeň F, Kufčáková J, Adamcová R, Rajec P (2012) Effect of gamma-irradiation on adsorption properties of Slovak bentonites. J Radioanal Nucl Chem 292(2):481–492

    Article  Google Scholar 

  67. Galamboš M, Suchánek P, Rosskopfová O (2012) Sorption of antropogenic radionuclides on natural and synthetic inorganic sorbents. J Radioanal Nucl Chem 293(2):613–633

    Article  Google Scholar 

  68. Galamboš M, Magula M, Daňo M, Osacký M, Rosskopfová O, Rajec P (2012) Comparative study of cesium adsorption on dioctahedral and trioctahedral smectites. J Radioanal Nucl Chem 293(3):829–837

    Article  Google Scholar 

  69. Galamboš M, Osacký M, Rosskopfová O, Krajňák A, Rajec P (2012) Comparative study of strontium adsorption on dioctahedral and trioctahedral smectites. J Radioanal Nucl Chem 293(3):889–897

    Article  Google Scholar 

  70. Zhang H, Yu X, Chen L, Geng J (2010) Investigation of radionuclide 63Ni (II) sorption on ZSM—5 zeolite. J Radioanal Nucl Chem 286:249–258

    Article  CAS  Google Scholar 

  71. Plyasunova NV, Zhang Y, Muhammed M (1998) Critical evaluation of thermodynamics of complex formation of heavy ions in aqueous solution. IV. Hydrolysis and hydroxo-complexes of Ni2+ at 298, 15 K. Hydrometallurgy 48:43–63

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Galamboš.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Krajňák, A., Pivarčiová, L., Rosskopfová, O. et al. Adsorption of nickel on rhyolitic Slovak bentonites. J Radioanal Nucl Chem 304, 587–593 (2015). https://doi.org/10.1007/s10967-014-3832-4

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-014-3832-4

Keywords

Navigation