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Low viscosity alkyd resins based on trimethylolpropane and Peruvian oil

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Abstract

The high-unsaturated fatty acid content of Sacha inchi oil (SIO), a perennial plant originally from Peru, has turned it into a potential raw material for the production of alkyd resins. In this study, different proportions of multifunctional polyols were used to prepare air-drying resins. Physicochemical characteristics (acid value, viscosity, colour, density, drying time, and hardness) of alkyds were evaluated. Moreover, FT-IR, TG–DTA, 1H-NMR and 13C-NMR characterization techniques were used. SIO-based alkyd resins prepared with trimethylolpropane exhibited low viscosities, suitable for preparing more manageable high solids protective coatings.

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The raw/processed data required to reproduce these findings cannot be shared at this time due to legal or ethical reasons.

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Acknowledgements

This research was funded by the agreement FONDECYT (Fondo Nacional de Desarrollo Científico, Tecnológico y de Innovación Tecnológica)—PUCP (Pontificia Universidad Católica del Perú); grant 166-2015-FONDECYT-DE. The authors thank the Nuclear Magnetic Resonance Laboratory (Sección Química, PUCP) for the 1H-NMR and 13C-NMR analyses. Sacha inchi oil was supplied by Amazon Health Products, Peru. The authors would like to acknowledge the Center for Materials Characterization at PUCP and R. Grieseler for the SEM images.

Funding

This research was funded by the agreement FONDECYT (Fondo Nacional de Desarrollo Científico, Tecnológico y de Innovación Tecnológica)—PUCP (Pontificia Universidad Católica del Perú); grant 166–2015-FONDECYT-D.

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Authors and Affiliations

  1. Instituto de Corrosión y Protección (ICP-PUCP), Pontificia Universidad Católica del Perú (PUCP), 15088, Avenida Universitaria 1801, Lima, Perú

    Daniel Obregón, Claudia Toledo, Antonella Hadzich & Santiago Flores

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  1. Daniel Obregón
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  2. Claudia Toledo
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  3. Antonella Hadzich
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  4. Santiago Flores
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Contributions

Daniel Obregón: Conceptualization, Methodology, Investigation, Writing—Original Draft Preparation, Supervision, Visualization and formal analysis. Claudia Toledo: Investigation and formal analysis. Antonella Hadzich: Conceptualization, Methodology, Writing- Reviewing and editing, formal analysis. Santiago Flores: Conceptualization, Methodology, Supervision, Writing- Reviewing and Editing.

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Correspondence to Daniel Obregón.

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Obregón, D., Toledo, C., Hadzich, A. et al. Low viscosity alkyd resins based on trimethylolpropane and Peruvian oil. J Polym Res 28, 203 (2021). https://doi.org/10.1007/s10965-021-02570-6

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