Abstract
Shape memory filaments have significant implications in smart wearable textiles, biomedical sutures, and additive manufacturing. However, the deterioration of shape memory performance over a range of temperature and strain limits their use in many high-end applications. This investigation reports the shape memory properties of segmented polyurethane filament and its detailed chemical and thermo-mechanical characterization. Shape memory polyurethane (SMPU) based on poly(1,6-hexanediol adipate) (PHA), 4,4′-diphenylmethane diisocyanate (MDI), and 1,4-butanediol (BDO) shows the transition temperature near body temperature. Hard segment and soft segment content in SMPU is 28.5% and 71.5% by weight. SMPU filament exhibited excellent shape recovery (~ 98%) and higher shape fixity (~ 80%) at a strain of 20%, 40%, and 60% and temperature of 30 ℃ and 50 ℃. Results have been supported by thermal and X-ray analysis. The cause of high fixity has been discussed in detail. Experimental results indicated higher crystallization and melting enthalpy. The cyclic test of SMPU filament showed almost complete shape recovery with no change in shape fixity under different thermo-mechanical conditions.
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References
Mather PT, Luo X et al (2009) Shape Memory Polymer Research. Annu Rev Mater Res 39:445–471. https://doi.org/10.1146/annurev-matsci-082908-145419
Hu J, Meng H et al (2012) A review of stimuli-responsive polymers for smart textile applications. Smart Mater Struct 21:053001. https://doi.org/10.1088/0964-1726/21/5/053001
Sokolowski W, Metcalfe A et al (2007) Medical applications of shape memory polymers. Biomed Mater 2:S23–S27. https://doi.org/10.1088/1748-6041/2/1/S04
Hu J, Zhu Y, Huang H, Lu J (2012) Recent advances in shape–memory polymers: Structure, mechanism, functionality, modeling and applications. Prog Polym Sci 37:1720–1763. https://doi.org/10.1016/j.progpolymsci.2012.06.001
Leng J, Lan X et al (2011) Shape-memory polymers and their composites: Stimulus methods and applications. Prog Mater Sci 56:1077–1135. https://doi.org/10.1016/j.pmatsci.2011.03.001
Gupta P, Narayana H et al (2020) Shape memory polymers for design of smart stocking. In: Gefen A (ed) Innovations and Emerging Technologies in Wound Care. Elsevier, Academic Press, pp 141–154.
Kumar B, Hu J et al (2016) A smart orthopedic compression device based on a polymeric stress memory actuator. Mater Des 97:222–229. https://doi.org/10.1016/j.matdes.2016.02.092
Kumar B, Hu J et al (2016) Smart medical stocking using memory polymer for chronic venous disorders. Biomaterials 75:174–181. https://doi.org/10.1016/j.biomaterials.2015.10.032
Gong T, Li W et al (2012) Remotely actuated shape memory effect of electrospun composite nanofibers. Acta Biomater 8:1248–1259. https://doi.org/10.1016/j.actbio.2011.12.006
Lendlein A, Jiang H et al (2005) Light-induced shape-memory polymers. Nature 434:879–882. https://doi.org/10.1038/nature03496
Zhu Y, Hu J et al (2012) Rapidly switchable water-sensitive shape-memory cellulose/elastomer nano-composites. Soft Matter 8:2509–2517. https://doi.org/10.1039/C2SM07035A
Cho JW, Kim JW et al (2005) Electroactive Shape-Memory Polyurethane Composites Incorporating Carbon Nanotubes. Macromol Rapid Commun 26:412–416. https://doi.org/10.1002/marc.200400492
Meng Q, Hu J et al (2007) Polycaprolactone-based shape memory segmented polyurethane fiber. J Appl Polym Sci 106:2515–2523. https://doi.org/10.1002/app.26764
Meng Q, Hu J et al (2007) An electro-active shape memory fibre by incorporating multi-walled carbon nanotubes. Smart Mater Struct 16:830–836. https://doi.org/10.1088/0964-1726/16/3/032
Meng Q, Hu J et al (2009) The influence of heat treatment on the properties of shape memory fibers. II. Tensile properties, dimensional stability, recovery force relaxation, and thermomechanical cyclic properties. J Appl Polym Sci 111:1156–1164. https://doi.org/10.1002/app.29165
Lendlein A, Kelch S (2002) Shape-Memory Polymers. Angew Chem Int Ed 41:2034–2057. https://doi.org/10.1002/1521-3773(20020617)41:12%3c2034::AID-ANIE2034%3e3.0.CO;2-M
Ahmad M, Luo J et al (2011) Synthesis and Characterization of Polyurethane-Based Shape-Memory Polymers for Tailored Tg around Body Temperature for Medical Applications. Macromol Chem Phys 212:592–602. https://doi.org/10.1002/macp.201000540
Meng Q, Liu J et al (2009) A smart hollow filament with thermal sensitive internal diameter. J Appl Polym Sci 113:2440–2449. https://doi.org/10.1002/app.30203
Kai D, Prabhakaran MP et al (2016) Elastic poly( ε -caprolactone)-polydimethylsiloxane copolymer fibers with shape memory effect for bone tissue engineering. Biomed Mater 11:015007. https://doi.org/10.1088/1748-6041/11/1/015007
Meng Q, Hu J et al (2007) Morphology, phase separation, thermal and mechanical property differences of shape memory fibres prepared by different spinning methods. Smart Mater Struct 16:1192–1197. https://doi.org/10.1088/0964-1726/16/4/030
Ji F, Zhu Y et al (2006) Smart polymer fibers with shape memory effect. Smart Mater Struct 15:1547–1554. https://doi.org/10.1088/0964-1726/15/6/006
Yang Q, Li G (2014) Investigation into stress recovery behavior of shape memory polyurethane fiber. J Polym Sci Part B: Polym Phys 52:1429–1440. https://doi.org/10.1002/polb.23582
Garg H, Mohanty J et al Polyethylenimine-Based Shape Memory Polyurethane with Low Transition Temperature and Excellent Memory Performance. Macromolecular Materials and Engineering 305(8):2000215. https://doi.org/10.1002/mame.202000215
Jerald Maria Antony G, Aruna ST (2018) Enhanced mechanical properties of acrylate based shape memory polymer using grafted hydroxyapatite. J Polym Res 25:120. https://doi.org/10.1007/s10965-018-1511-9
Hu JL, Zeng YM et al (2003) Influence of Processing Conditions on the Microstructure and Properties of Shape Memory Polyurethane Membranes. Text Res J 73:172–178. https://doi.org/10.1177/004051750307300214
Jung YC, Kim JH et al (2012) Fabrication of Transparent, Tough, and Conductive Shape-Memory Polyurethane Films by Incorporating a Small Amount of High-Quality Graphene. Macromol Rapid Commun 33:628–634. https://doi.org/10.1002/marc.201100674
Kang SM, Lee SJ, Kim BK (2012) Shape memory polyurethane foams. Express Polym Lett 6:63–69. https://doi.org/10.3144/expresspolymlett.2012.7
Zhu Y, Hu J et al (2006) Development of shape memory polyurethane fiber with complete shape recoverability. Smart Mater Struct 15:1385–1394. https://doi.org/10.1088/0964-1726/15/5/027
Tian X, Bai H et al (2011) Bio-inspired Heterostructured Bead-on-String Fibers That Respond to Environmental Wetting. Adv Funct Mater 21:1398–1402. https://doi.org/10.1002/adfm.201002061
Garces I, Aslanzadeh S et al (2019) Effect of Moisture on Shape Memory Polyurethane Polymers for Extrusion-Based Additive Manufacturing. Materials 12:244. https://doi.org/10.3390/ma12020244
Zhu Y, Hu J et al (2007) Effect of steaming on shape memory polyurethane fibers with various hard segment contents. Smart Mater Struct 16:969–981. https://doi.org/10.1088/0964-1726/16/4/004
Lin JR, Chen LW (1998) Study on shape-memory behavior of polyether-based polyurethanes. I. Influence of the hard-segment content. J Appl Polym Sci 69:1563–1574. https://doi.org/10.1002/(SICI)1097-4628(19980822)69:8%3c1563::AID-APP11%3e3.0.CO;2-W
Lin JR, Chen LW (1998) Study on shape-memory behavior of polyether-based polyurethanes. II. Influence of soft-segment molecular weight. J Appl Polym Sci 69:1575–1586. https://doi.org/10.1002/(SICI)1097-4628(19980822)69:8%3c1575::AID-APP12%3e3.0.CO;2-U
Hu JL, Ji FL et al (2005) Dependency of the shape memory properties of a polyurethane upon thermomechanical cyclic conditions. Polym Int 54:600–605. https://doi.org/10.1002/pi.1745
Revathi A, Rao S et al (2013) Effect of strain on the thermomechanical behavior of epoxy based shape memory polymers. J Polym Res 20:113. https://doi.org/10.1007/s10965-013-0113-9
Narayana H, Hu J et al (2017) Stress-memory polymeric filaments for advanced compression therapy. Journal of Materials Chemistry B 5:1905–1916. https://doi.org/10.1039/C6TB03354G
Meng Q, Hu J (2008) Influence of heat treatment on the properties of shape memory fibers. I. Crystallinity, hydrogen bonding, and shape memory effect. J Appl Polym Sci 109:2616–2623. https://doi.org/10.1002/app.28363
Kaursoin J, Agrawal AK (2007) Melt spun thermoresponsive shape memory fibers based on polyurethanes: Effect of drawing and heat-setting on fiber morphology and properties. J Appl Polym Sci 103:2172–2182. https://doi.org/10.1002/app.25124
Trovati G, Sanches EA et al (2010) Characterization of polyurethane resins by FTIR, TGA, and XRD. J Appl Polym Sci 115:263–268. https://doi.org/10.1002/app.31096
Rohindra D, Lata R et al (2019) Crystallization behavior in miscible blends of poly(ε-caprolactone) and poly(hexylene adipate) with similar thermal properties studied by time-resolved Fourier transform infrared spectroscopy. POLYMER CRYSTALLIZATION 2:e10037. https://doi.org/10.1002/pcr2.10037
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Gupta, P., Garg, H., Mohanty, J. et al. Excellent memory performance of poly (1,6-hexanediol adipate) based shape memory polyurethane filament over a range of thermo-mechanical parameters. J Polym Res 27, 382 (2020). https://doi.org/10.1007/s10965-020-02345-5
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DOI: https://doi.org/10.1007/s10965-020-02345-5