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Microstructure characterization of one high-speed extrusion coating polyethylene resin fractionated by solvent gradient fractionation

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Abstract

One low density polyethylene (LDPE) resin with high-speed extrusion coating property is fractionated through solvent gradient fractionation (SGF) technique using 1,2,4-trimethylbenzene (TMB) and ethyl cellosolve (ECS) as good/poor solvent pair at 115 °C. The pristine sample and its fractions are characterized by high-temperature gel permeation chromatography (HT-GPC) coupled with triple detectors (refractive index RI, light scattering LS, viscometer VIS), 13C–nuclear magnetic resonance spectroscopy (13C–NMR), differential scanning calorimetry (DSC) and successive self-nucleation/annealing (SSA) thermal fractionation. By adjusting the ratio of good/poor solvent, the obtained fractions show their molecular weight from 1.58 × 103 g/mol to 4.76 × 105 g/mol. It is found that the fractions with high molecular weight (fractions 10–13) occupy about 55.85% in resin. Particularly, the molecular weight distribution (MWD) of most fractions is in the range of 1.1–1.2. Each fraction contains more short chain branch (SCB) and less long chain branch (LCB) simultaneously. With increasing the molecular weight, the branching content shows no regular change. The lowest SCB and total branch content regions correspond to molecular weight 1.97 × 104 to 4.10 × 104 g/mol. The melting and crystallization temperatures of fractions firstly increase and then decrease with the molecular weight. The crystallinity decreases gradually from 51.7% to 31.1%. In the SSA thermal fractionation, each fraction shows a broad range of endotherm with multiple melting peaks in DSC curve corresponding to the different methylene sequence length (MSL) (L n and L w ). The longest L n (L w ) region occurs in the molecular weight of 8.95 × 103 to 3.14 × 104 g/mol. The relationship between chain microstructure and properties is also discussed.

Graphical Abstract

One coating LDPE resin is effectively fractionated by solvent gradient fractionation using TMB/ECS as good/poor solvent pair according to molecular weight. The component with high molecular weight is more than that with low molecular weight. Higher molecular weight and LCB improve the melt strength synergetically, and suitable component with low molecular weight provides better flowability.

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Acknowledgments

This study was supported by the project from the PetraChina Company Limited (Grant No.: PRIKY15035).

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Authors and Affiliations

  1. College of Materials Science and Engineering, Jilin University, Changchun, 130022, China

    Pei Li & Guangping Sun

  2. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China

    Pei Li, Yanhu Xue, Xiaoxue Wu, Xiangling Ji & Shuqin Bo

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  1. Pei Li
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  2. Yanhu Xue
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  3. Xiaoxue Wu
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  4. Guangping Sun
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  5. Xiangling Ji
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Correspondence to Guangping Sun or Xiangling Ji.

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Li, P., Xue, Y., Wu, X. et al. Microstructure characterization of one high-speed extrusion coating polyethylene resin fractionated by solvent gradient fractionation. J Polym Res 25, 113 (2018). https://doi.org/10.1007/s10965-018-1480-z

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  • DOI: https://doi.org/10.1007/s10965-018-1480-z

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