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Core-shell particles for design of high-performance polymeric materials with good transparency and toughness

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Abstract

Core-shell particles were synthesized and blended with poly(methyl methacrylate) (PMMA) in an attempt to simultaneously improve the transparency and toughness of the resulting materials. Poly(BA-co-Bd-co-St) latexes were produced by emulsion polymerization method, and confirmed by DMA. In the case of 269 nm of particle size core-shell particles’ dispersion in the PMMA matrix were remarkably improved as shown by TEM. The transmittance of PMMA/core-shell particle composites reached 86.3 %, and the Izod impact strength was eight times higher compared to PMMA resin. Altogether the results showed that Poly(BA-co-Bd-co-St) latexes could be applied to simultaneously improve the transparency and toughness of the materials and further improvements could be achieved after optimization of particle size and component.

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References

  1. Wang MS, Pinnavaia TJ (1994) Chem Mater 6:468–474

    Article  CAS  Google Scholar 

  2. Sun TL, Kurokawa T, Kuroda S, Ihsan AB, Akasaki T, Sato K, Haque MA, Nakajima T, Gong JP (2013) Nat Mater 12:932–937

    Article  CAS  Google Scholar 

  3. Malay O, Oguz O, Kosak C, Yilgor E, Yilgo I, Menceloglu YZ (2013) Polymer 54:5310–5320

    Article  CAS  Google Scholar 

  4. Goncalves G, Marques PAAP, Barros-Timmons A, Bdkin I, Singh MK, Emami N, Gracio J (2010) J Mater Chem 20:9927–9934

    Article  CAS  Google Scholar 

  5. Dhevi DM, Prabu AA, Kim H, Pathak M (2014) J Polym Res 21:503

    Article  Google Scholar 

  6. Hegde RR, Bhat GS, Spruiell JE, Benson R (2013) J Polym Res 20:323

    Article  Google Scholar 

  7. Wu XL, Qiu JH, Liu P, Sakai E (2013) J Polym Res 20:284

    Article  CAS  Google Scholar 

  8. Fu SY, Feng XQ, Laukec B, Maid YW (2008) Compos Part B 39:933–961

    Article  Google Scholar 

  9. Borggreve RJM, Gaymans RJ, Schuijer J, Ingen Housz JF (1987) Polymer 28:1489–1496

    Article  CAS  Google Scholar 

  10. Kim GM, Michler GH (1998) Polymer 39:5689–5697

    Article  CAS  Google Scholar 

  11. Liu ZH, Zhu XG, Wu LX, Li Y, Qi ZN, Choy CL, Wang FS (2001) Polymer 42:737–746

    Article  CAS  Google Scholar 

  12. Lin H, Kang SG, Day DE, Stoffer JO (1994) Compos Sci Technol 50:367–372

    Article  CAS  Google Scholar 

  13. Fraser RA, Stoeffler K, Ashrafi B, Zhang YF, Simard B (2012) Appl Mater Interfaces 4:1990–1997

    Article  CAS  Google Scholar 

  14. Bucknall CB, Partridge IK, Ward MV (1984) J Mater Sci 19:2064–2072

    Article  CAS  Google Scholar 

  15. Wright DD, Gilbert JL (1999) J Mater Sci Mater Med 10:503–512

    Article  CAS  Google Scholar 

  16. Fraser RA, Stoeffler K, Ashrafi B, Zhang YF, Simard B (2012) Appl Mater Interfaces 4:1990–1997

    Article  CAS  Google Scholar 

  17. Cheng SK, Chen CY (2004) Eur Polym J 40:1239–1248

    Article  CAS  Google Scholar 

  18. Munch E, Launey ME, Alsem DH, Saiz E, Tomsia AP, Ritchie RO (2008) Science 322:1516–1520

    Article  CAS  Google Scholar 

  19. Lovell PA, McDonald J, Saunders DEJ, Sherratt MN, Young RJ (1993) Toughened Plast I Sci Eng 3:61–77

    Article  Google Scholar 

  20. Zhao CZ, Wu GF, Zhou C, Yang HD, Zhang HX (2006) J Polym Sci B Polym Phys 44:696–702

    Article  CAS  Google Scholar 

  21. Steenbrink AC, Litvinov VM, Gaymans RJ (1998) Polymer 39:4817–4825

    Article  CAS  Google Scholar 

  22. Roberto AK (2000) Polymer blends II: Performance 28:301–331

  23. Brandrup J, Immergut EH (1975) Polymer handbook. Wiley, New York

    Google Scholar 

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Ren, L., Zhang, M.Y., Han, Y. et al. Core-shell particles for design of high-performance polymeric materials with good transparency and toughness. J Polym Res 21, 613 (2014). https://doi.org/10.1007/s10965-014-0613-2

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  • DOI: https://doi.org/10.1007/s10965-014-0613-2

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