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Volumetric and Optical Properties of Dimethylvinylethoxysilane with n-Alkanes (C7 to C10) at Temperatures in the Range (298.15 to 318.15) K

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Abstract

Densities and refractive indices are investigated for four binary mixture systems of dimethylvinylethoxysilane with n-heptane, n-octane, n-nonane and n-decane at different temperatures (298.15, 303.15, 308.15, 313.15 and 318.15 K) and atmospheric pressure. From these experimental data, the excess molar volume, isobaric coefficient of thermal expansion, deviation in refractive index, molar refraction, and deviation in the molar refraction have been calculated. The computed quantities have been fitted with the Redlich–Kister equation to derive the coefficients and estimate the standard deviations. The values of the partial excess volume at infinite dilution were calculated using the coefficients of the Redlich–Kister smoothing equation. The effects of composition and temperature on these properties are discussed.

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References

  1. Dong, H., Yue, Y., Wu, C., Lai, G.Q.: Excess molar volumes of 2,4,6,8-tetramethylcyclotetrasiloxane with benzene, toluene, and xylene at T = (288.15, 298.15, and 308.15) K. J. Chem. Eng. Data 57, 1050–1056 (2012)

    Article  CAS  Google Scholar 

  2. Zhang, Y.D., Dong, H., Yue, Y., Wu, C.: Effect of temperature and composition on the density, refractive index, and excess quantities of binary mixtures of 2,4,6,8-tetramethyl-2,4,6,8-tetraethenylcyclotetrasiloxane with aromatic hydrocarbons. J. Chem. Thermodyn. 57, 114–130 (2013)

    Article  CAS  Google Scholar 

  3. Yu, L.J., Dong, H., Wu, C., Zhang, Y.D.: The density, refractive index, and thermodynamic behaviour of binary mixtures of 1,3-diethenyl-1,1,3,3-tetramethyldisiloxane with aromatic hydrocarbons. J. Chem. Thermodyn. 72, 139–151 (2014)

    Article  CAS  Google Scholar 

  4. Zhang, Y.D., Dong, H., Wu, C., Yu, L.J.: Thermophysical properties of binary mixtures of triethoxysilane, methyltriethoxysilane, vinyltriethoxysilane and 3-mercaptopropyltriethoxysilane with ethylbenzene at various temperatures. J. Chem. Thermodyn. 76, 45–55 (2014)

    Article  CAS  Google Scholar 

  5. Yu, L.J., Hu, Y.Q., Dong, H., Wu, C.: The physicochemical properties of 1,3,5-trimethyl-1,3,5-tris(3,3,3-trifluoropropyl)cyclotrisiloxane with various aromatic hydrocarbons at T = (308.15 to 323.15) K. J. Chem. Thermodyn. 96, 117–126 (2016)

    Article  CAS  Google Scholar 

  6. Brown, I., Ewald, A.H.: Liquid–vapour equilibria. II. The system benzene–n-heptane. Aust. J. Chem. 4, 198–212 (1951)

    Article  Google Scholar 

  7. Pomerantz, P.: Synthesis and physical properties of n-heptane and 2,2,4-trimethylpentane. J. Res. Nat. Bur. Stand. 48, 76–81 (1952)

    Article  CAS  Google Scholar 

  8. Fang, S., Fu, Y.Y., Wang, Q., Zhang, G.Y.: Mixing properties of tris(2-ethylhexyl) phosphate with alkanes at different temperatures and data treatment using several correlation equations based on Eyring’s absolute reaction theory. J. Mol. Liq. 154, 111–116 (2010)

    Article  CAS  Google Scholar 

  9. Fang, S., Zhao, C.X., He, C.H.: Densities and viscosities of binary mixtures of tri-n-butyl phosphate + cyclohexane, + n-heptane at T = (288.15, 293.15, 298.15, 303.15, and 308.15) K. J. Chem. Eng. Data 53, 2244–2246 (2008)

    Article  CAS  Google Scholar 

  10. Yang, X., Xing, Y., Li, D., Guo, Y.S., Fang, W.J.: Volumetric and viscous properties at several temperatures for binary mixtures of n-methylpiperazine with methylcyclohexane or n-heptane. J. Chem. Eng. Data 55, 2914–2916 (2010)

    Article  CAS  Google Scholar 

  11. Landaverde-Cortes, D.C., Estrada-Baltazar, A., Iglesias-Silva, G.A.: Densities and viscosities of MTBE + heptane or octane at p = 0.1 MPa from (273.15 to 363.15) K. J. Chem. Eng. Data 52, 1226–1232 (2007)

    Article  CAS  Google Scholar 

  12. Lei, Y.T., Chen, Z.Y., An, X.Q., Huang, M.J., Shen, W.G.: Measurements of density and heat capacity for binary mixtures {x benzonitrile + (1 − x) (octane or nonane)}. J. Chem. Eng. Data 55, 4154–4161 (2010)

    Article  CAS  Google Scholar 

  13. González, E.J., Calvar, N., Gómez, E., Domínguez, Á.: Separation of benzene from alkanes using 1-ethyl-3-methylpyridinium ethylsulfate ionic liquid at several temperatures and atmospheric pressure: effect of the size of the aliphatic hydrocarbons. J. Chem. Thermodyn. 42, 104–109 (2010)

    Article  CAS  Google Scholar 

  14. Rathnam, M.V., Mankumare, S., Kumar, M.S.S.: Density, viscosity, and speed of sound of (methyl benzoate + cyclohexane), (methyl benzoate + n-hexane), (methyl benzoate + heptane), and (methyl benzoate + octane) at temperatures of (303.15, 308.15, and 313.15) K. J. Chem. Eng. Data 55, 1354–1358 (2010)

    Article  CAS  Google Scholar 

  15. Balán, J., Morávková, L., Linek, J.: Excess molar volumes of the (cyclohexane + pentane, or hexane, or heptane, or octane, or nonane) systems at the temperature 298.15 K. Chem. Pap. 61, 497–501 (2007)

    Article  CAS  Google Scholar 

  16. Lago, A., Rivas, M.A., Legido, J., Iglesias, T.P.: Study of static permittivity and density of the systems (n-nonane + monoglyme or diglyme) at various temperatures. J. Chem. Thermodyn. 41, 257–264 (2009)

    Article  CAS  Google Scholar 

  17. Landaverde-Cortes, D.C., Iglesias-Silva, G.A.: Densities and viscosities of MTBE + nonane or decane at p = 0.1 MPa from (273.15 to 363.15) K. J. Chem. Eng. Data 53, 288–292 (2008)

    Article  CAS  Google Scholar 

  18. de Cominges, B.E., Pineiro, M.M., Mascato, E., Mosteiro, L., Lglesias, T.P., Legido, J.L.: Relative permittivities of binary mixtures of 1-butanol + n-alkane at 298.15 K. J. Therm. Anal. Calorim. 72, 129–133 (2003)

    Article  Google Scholar 

  19. Prezhdo, O.V., Switek, L., Zubkova, V.V., Prezhdo, V.V.: The role of intermolecular interactions in the electro-optical Kerr effect in liquid alkanes. Acta Phys. Pol. A 108, 429–447 (2005)

    Article  CAS  Google Scholar 

  20. Sabater, G., Ortega, J.: Excess properties and isobaric vapor–liquid equilibria for four binary systems of alkyl (methyl to butyl) methanoates with decane. Fluid Phase Equilibr. 291, 18–31 (2010)

    Article  CAS  Google Scholar 

  21. Vaisarová, V., Chvalovský, V.: Organosilicon compounds. LVI. Dipole moments of substituted vinylsilanes and phenylsilanes. Collect. Czech. Chem. Commun. 33, 859–865 (1968)

    Article  Google Scholar 

  22. Redlich, O., Kister, A.T.: Algebraic representation of thermodynamic properties and the classification of solutions. Ind. Eng. Chem. 40, 345–348 (1948)

    Article  Google Scholar 

  23. Rodríguez, A., Canosa, A.J., Tojo, J.: Binary mixture properties of methyl tert-butyl ether with hexane or heptane or octane or nonane from 288.15 K to 298.15 K. J. Chem. Eng. Data 44, 666–671 (1999)

    Article  Google Scholar 

  24. Domańska, U.: The excess molar volumes of (hydrocarbon + branched chain ether) systems at 298.15 K and 308.15 K, and the application of PFP theory. Fluid Phase Equilib. 130, 207–222 (1996)

    Article  Google Scholar 

  25. Liu, H., Zhu, L.: Excess molar volumes and viscosities of binary systems of butylcyclohexane with n-alkanes (C7 to C14) at T = 293.15 K to 313.15 K. J. Chem. Eng. Data 59, 369–375 (2014)

    Article  CAS  Google Scholar 

  26. Kermanpour, F., Niakan, H.Z., Sharifi, T.: Density and viscosity measurements of binary alkanol mixtures from (293.15 to 333.15) K at atmospheric pressure. J. Chem. Eng. Data 58, 1086–1091 (2013)

    Article  CAS  Google Scholar 

  27. Peralta, R.D., Infante, R., Cortez, G., Cisneros, A., Wisniak, J.: Densities and excess volumes of benzene with ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene at 298.15 K. Thermochim. Acta 398, 39–46 (2003)

    Article  CAS  Google Scholar 

  28. Krakowiak, J., Śmiechowski, M.: Excess molar volume and viscosity deviation for binary mixtures of γ-butyrolactone with dimethyl sulfoxide. J. Chem. Thermodyn. 110, 57–64 (2017)

    Article  CAS  Google Scholar 

  29. Gómez, E., González, B., Calvar, N., Tojo, E., Domínguez, Á.: Physical properties of pure 1-ethyl-3-methylimidazolium ethylsulfate and its binary mixtures with ethanol and water at several temperatures. J. Chem. Eng. Data 51, 2096–2102 (2006)

    Article  CAS  Google Scholar 

  30. Brocos, P., Piñeiro, Á., Bravo, R., Amigo, A.: Refractive indices, molar volumes and molar refractions of binary liquid mixtures: concepts and correlations. Phys. Chem. Chem. Phys. 5, 550–557 (2003)

    Article  CAS  Google Scholar 

  31. Sudhakar, S.D., Chandrashekhar, P.P., Dilip, V.P.: Density, speed of sound, and refractive index of aqueous binary mixtures of some glycol ethers at T = 298.15 K. J. Chem. Eng. Data 55, 3962–3968 (2010)

    Article  CAS  Google Scholar 

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Acknowledgements

This work was supported by the school-enterprise cooperation project for University Access Engineer of Zhejiang (Grant No. FG2017204).

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Authors and Affiliations

  1. Taizhou Vocational College of Science & Technology, Taizhou, 318020, China

    Jing Jin

  2. Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Hangzhou Normal University, Hangzhou, 311121, China

    Fangjun Shao, Hong Dong & Chuan Wu

  3. Collaborative Innovation Center for the Manufacture of Fluorine and Silicone Fine Chemicals and Materials, Hangzhou, 311121, China

    Hong Dong & Chuan Wu

Authors
  1. Jing Jin
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  2. Fangjun Shao
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  3. Hong Dong
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  4. Chuan Wu
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Correspondence to Hong Dong or Chuan Wu.

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Jin, J., Shao, F., Dong, H. et al. Volumetric and Optical Properties of Dimethylvinylethoxysilane with n-Alkanes (C7 to C10) at Temperatures in the Range (298.15 to 318.15) K. J Solution Chem 48, 82–103 (2019). https://doi.org/10.1007/s10953-019-00843-9

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