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Structural, Mössbauer Effect, Magnetic, and Thermal Properties of Gadolinium Erbium Iron Garnet System Gd3−x Er x Fe5 O 12

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Abstract

In this article, Gd3−x Er x Fe5O12 powders with x= 0.0, 0.5, 1.0, 1.5, 2.0, 2.5, and 3.0 were prepared by solid-state reaction method. The properties of the prepared samples were examined by X-ray diffraction, Mössbauer spectroscopy, vibrating sample magnetometry, and differential scanning calorimetry. The XRD patterns of the powders show a single-phase structure and were found to agree with the standard pattern of rare earth iron garnet. Room temperature Mössbauer spectra of the powders indicate that iron is present in three magnetic sites corresponding to two octahedral sites and one tetrahedral site. The saturation magnetization increased with increasing erbium substitution, and the Curie temperature decreased slightly.

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References

  1. Gilleo, M.A.: Ferromagnetic insulators: Garnets. In: Wohlfarth, P. E (ed.) Ferromagnetic Materials, pp 1–53, North-Holland (1980)

  2. Mahmood, S.H.: Permanent magnet applications. In: Mahmood, S.H., Abu-Aljarayesh, I. (eds.) Hexaferrite Permanent Magnetic Materials, Materials Research Forum LLC, pp 153–165. Millersville, (2016)

  3. Jha, A.R.: Rare Earth Materials: Properties and Applications. CRC Press, Florida (2014)

  4. Paoletti, A.: Physics of Magnetic Garnet. North Holland (1978)

  5. Brabenec, M., Englich, J., Novak, P., Lütgemeier, H.: On the transferred hyperfine interaction in substituted YIG. Hyperfine Interact. 34, 459–461 (1987)

    Article  ADS  Google Scholar 

  6. Novák, P., Englich, J., Lütgemeier, H.: Enhancement of exchange interactions in Bi-and La-substituted Y3Fe5 O 12. Phys. Rev. B 37, 9712 (1988)

    Article  ADS  Google Scholar 

  7. Winkler, G.: Magnetic Garnets. Vieweg, Braunschweig (1981)

    Google Scholar 

  8. Geller, S., Remeika, J., Sherwood, R., Williams, H., Espinosa, G.: Magnetic study of the heavier rare-earth iron garnets. Phys. Rev. 137, A1034 (1965)

    Article  ADS  Google Scholar 

  9. Lataifeh, M., Al-Sharif, A.: Magnetization measurements on some rare-earth iron garnets. Appl. Phys. A 61, 415–418 (1995)

    Article  ADS  Google Scholar 

  10. Lataifeh, M.S.: Room temperature magnetization measurements of some substituted rare earth iron garnets. Appl. Phys. A 92, 681–685 (2008)

    Article  ADS  Google Scholar 

  11. Lataifeh, M., McCausland, M.: On the molecular field seen by Gd3+ in iron garnets. Mu’tah Lil-Buhooth Wa Al-Dirasat 9, 23–30 (1994)

    Google Scholar 

  12. Parida, S., Rakshit, S., Singh, Z.: Heat capacities, order–disorder transitions, and thermodynamic properties of rare-earth orthoferrites and rare-earth iron garnets. J. Solid State Chem. 181, 101–121 (2008)

    Article  ADS  Google Scholar 

  13. Lataifeh, M.: The field dependence and anisotropy of the hyperfine interaction of165Ho in holmium iron garnet single crystals. Mu’tah. J. Res. Stud. 9, 127–144 (1994)

    Google Scholar 

  14. Lataifeh, M.S., Lehlooh, A.F.D., Mahmood, S.: Mössbauer spectroscopy of Al substituted Fe in holmium iron garnet. Hyperfine Interact. 122, 253–258 (1999)

    Article  ADS  Google Scholar 

  15. Lataifeh, M.S., Mahmood, S., Thomas, M.F.: Mössbauer spectroscopy study of substituted rare-earth iron garnets at low temperature. Phys. B: Condens. Matter 321, 143–148 (2002)

    Article  ADS  Google Scholar 

  16. Lataifeh, M.S., Lehlooh, A.-F.D.: Mössbauer spectroscopy study of substituted yttrium iron garnets. Solid State Commun. 97, 805–807 (1996)

    Article  ADS  Google Scholar 

  17. Waerenborgh, J., Rojas, D., Shaula, A., Kharton, V., Marques, F.: Defect formation in Gd3Fe5 O 12-based garnets: A Mössbauer spectroscopy study. Mater. Lett. 58, 3432–3436 (2004)

    Article  Google Scholar 

  18. Chinnasamy, C., Greneche, J., Guillot, M., Latha, B., Sakai, T., Vittoria, C., Harris, V.: Structural and size dependent magnetic properties of single phase nanostructured gadolinium-iron-garnet under high magnetic field of 32 tesla. J. Appl. Phys. 107, 09A512 (2010)

    Article  Google Scholar 

  19. Pollmann, J., Rüter, H., Gerdau, E.: The temperature dependence of the hyperfine parameters of YIG below the Curie point. Hyperfine Interact. 122, 353–364 (1999)

    Article  ADS  Google Scholar 

  20. Vandormael, D., Grandjean, F., Hautot, D., Long, G.J.: Mössbauer spectral evidence for rhombohedral symmetry in R3Fe5 O 12 garnets with R = Y, Eu and Dy. J. Phys. Condens. Matter 13, 1759–1772 (2001)

    Article  ADS  Google Scholar 

  21. Tomáš, D., Novák, P., Štěpánková, H.: Hyperfine fields and superexchange in yttrium-iron garnet. J. Magn. Magn. Mater. 140–144, 2133–2134 (1995)

    Google Scholar 

  22. Streever, R., Caplan, P.: Nuclear-magnetic-resonance studies of Fe57 in rare-earth iron garnets. Phys. Rev. B 4, 2881 (1971)

    Article  ADS  Google Scholar 

  23. Falileev, G. N.: Calculation of the magnetization-temperature dependence of rare-earth and yttrium iron garnet solid solutions. Phys. Status Solidi (b) 96, 429 (1979)

    Article  ADS  Google Scholar 

  24. Geprägs, S., et al.: Origin of the spin Seebeck effect probed by temperature dependent measurements in Gd3Fe5 O 12. ArXiv e-prints (2014)

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Correspondence to Qassem I. Mohaidat.

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Mohaidat, Q.I., Lataifeh, M., Mahmood, S.H. et al. Structural, Mössbauer Effect, Magnetic, and Thermal Properties of Gadolinium Erbium Iron Garnet System Gd3−x Er x Fe5 O 12 . J Supercond Nov Magn 30, 2135–2141 (2017). https://doi.org/10.1007/s10948-017-4003-y

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  • DOI: https://doi.org/10.1007/s10948-017-4003-y

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