Skip to main content
Log in

Phenomenological Model of Magnetocaloric Effect in La0.7Ca0.2Ba0.1MnO3 Manganite Around Room Temperature

  • Original Paper
  • Published:
Journal of Superconductivity and Novel Magnetism Aims and scope Submit manuscript

Abstract

In this work, we studied in detail the magnetic and magnetocaloric properties of the La0.7Ca0.2Ba0.1MnO3 compound according to the phenomenological model. Based on this model, the magnetocaloric parameters such as the maximum of the magnetic entropy change ΔS M and the relative cooling power (RCP) have been determined from the magnetization data as a function of temperature at several magnetic fields. The theoretical predictions are found to closely agree with the experimental measurements, which make our sample a suitable candidate for refrigeration near room temperature. In addition, field dependences of \({{\Delta } S}_{\mathrm {M}}^{\max }\) and RCP can be expressed by the power laws \({\Delta S}_{\mathrm {M}}^{\max }\approx a\)(μ 0 H)n and RCP ≈b(μ 0 H)m, where a and b are coefficients and n and m are the field exponents, respectively. Moreover, phenomenological universal curves of entropy change confirm the second-order phase transition.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. GschneidnerJr, K. A., Pecharsky, V. K., Tsokol, A. O.: Recent developments in magnetocaloric materials. Rep. Prog. Phys. 68, 1479 (2005)

    Article  ADS  Google Scholar 

  2. M’nassri, R.: Enhanced refrigerant capacity and magnetic entropy nearly flattening in (La\(_{\mathrm {2/3}}\)Ba\(_{\mathrm {1/3}}\)MnO\(_{3})_{\mathrm {1-x}}\)/(La\(_{\mathrm {2/3}}\)Ba\(_{\mathrm {1/3}}\)MnO\(_{\mathrm {2.98}})_{\mathrm {x}}\) composite. J. Supercond. Nov. Magn. doi:10.1007/s10948-016-3480-8

  3. Pecharsky, V. K., Gschneidner, K. A.: Giant magnetocaloric effect in Gd\(_{5}\)(Si\(_{2}\)Ge\(_{2})\). J. Phys. Rev. Lett 78, 4494 (1997)

    Article  ADS  Google Scholar 

  4. Wada, H., Tanabe, Y.: Giant magnetocaloric effect of MnAs\(_{\mathrm {1-x}}\)Sb\(_{\mathrm {x}}\). Appl. Phys. Lett. 79, 3302 (2001)

    Article  ADS  Google Scholar 

  5. Fujieda, S., Fujita, A., Fukamichi, K.: Large magnetocaloric effects in NaZn\(_{13}\)-type La(FexSi1−x)13compounds and their hydrides composed of icosahedral clusters. Sci. Technol. Adv. Mater 4, 339 (2003)

    Article  Google Scholar 

  6. Phan, M. H., Yu, S.C.: Review of the magnetocaloric effect in manganite materials. J. Magn. Magn. Mater 308, 325 (2007)

    Article  ADS  Google Scholar 

  7. Mehri, A., Cheikhrouhou-Koubaa, W., Koubaa, M., Cheikhrouhou, A.: Magnetocaloric properties in La\(_{\mathrm {0.5}}\)Ca0.45 K 0.05MnO3, Pr0.5Sr0.45 K 0.05MnO3, and and Nd\(_{\mathrm {0.5}}\)Sr\(_{\mathrm {0.45}}\textit {K}_{\mathrm {0.05}}\)MnO\(_{3}\) manganites. J. Supercond. Nov. Magn. 28, 3135 (2015)

    Article  Google Scholar 

  8. Sellami-Jmal, E., Marzouki, A., Cheikhrouhou-Koubaa, W., Cheikhrouhou, A., Njah, N.: Deficiency effect on magnetic and magnetocaloric properties of La\(_{\mathrm {0.65-x}}\square _{\mathrm {x}}\)Ca0.35MnO3 manganites synthesized using sol–gel technique. J. Supercond. Nov. Magn. 28, 831 (2015)

    Article  Google Scholar 

  9. Sellami-Jmal1, E., Marzouki-Ajmi, A., Cheikhrouhou-Koubaa, W., Koubaa, M., Cheikhrouhou, A., Nowak, S., Sicard, L., Ammar-Merah, S., Njah, N.: Effect of calcium deficiency on the structural, magnetic and magnetocaloric properties in La\(_{\mathrm {0.65}}\)Ca\(_{\mathrm {0.35}}\)MnO\(_{3}\) manganites oxides. J. Supercond. Nov. Magn. 28, 2409 (2015)

  10. Ezaami, A., Sellami-Jmal, E., Chaaba, I., Cheikhrouhou-Koubaa, W., Cheikhrouhou, A., Hlil, E. K.: Effect of elaborating method on magnetocaloric properties of La\(_{\mathrm {0.7}}\)Ca\(_{\mathrm {0.2}}\)Ba0.1MnO3 manganite. J. Alloys Comp. 685, 710 (2016)

    Article  Google Scholar 

  11. M’nassri, R.: Enhancement of refrigeration capacity and table-like magnetocaloric effect in LaFe\(_{\mathrm {10.7}}\)Co\(_{\mathrm {0.8}}\)Si\(_{\mathrm {1.5}}\)/La\(_{\mathrm {0.6}}\)Pr\(_{\mathrm {0.4}}\)Fe\(_{\mathrm {10.7}}\)Co\(_{\mathrm {0.8}}\)Si\(_{\mathrm {1.5}}\) composite. J. Supercond. Nov. Magn. doi:10.1007/s10948-015-3241-0

  12. Messaoui, I., Riahi, K., Cheikhrouhou–Koubaa, W., Koubaa, M., Cheikhrouhou, A., Hlil, E.K.: Phenomenological model of the magnetocaloric effect on Nd0.7Ca0.15Sr0.15MnO\(_{3}\) compound prepared by ball milling method. Ceram. Inter. 42, 6825 (2016)

    Article  Google Scholar 

  13. Wang, Z. M., Ni, G., Xu, Q. Y., Sang, H., Du, Y. W.: Magnetocaloric effect in perovskite manganites La\(_{\mathrm {0.7-x}}\)Nd\(_{\mathrm {x}}\)Ca\(_{\mathrm {0.3}}\)MnO\(_{\mathrm {3}}\)and La\(_{\mathrm {0.7}}\)Ca\(_{\mathrm {0.3}}\)MnO\(_{3}\). J. Appl. Phys. 90, 5689 (2001)

    Article  ADS  Google Scholar 

  14. Guo, Z. B., Du, Y. W., Zhu, J. S., Huang, H., Ding, W. P., Feng, D.: Large magnetic entropy change in perovskite-type manganese oxides. Phys. Rev. Lett. 78, 1142 (1997)

    Article  ADS  Google Scholar 

  15. Radaelli, P. G., Cox, D. E., Marizio, M., Sheong, S. W., Schiffer, P. E., Ramirez, A. P.: Simultaneous structural, magnetic, and electronic transitions in La1−xCaxMnO\(_{3}\) with x \(=\) 0.25 and 0.50. Phys. Rev. Lett. 75, 4488 (1995)

    Article  ADS  Google Scholar 

  16. Chen, W., Zhong, W., Hou, D. I., Gao, R. W., Feng, W. C., Zhu, M. G., Du, Y. W.: Preparation and magnetocaloric effect of self-doped La0.8−xNa0.2xMnO3+δ(\(=\) vacancies) polycrystal. J. Phys.: Condens. Matter 14, 11889 (2002)

    ADS  Google Scholar 

  17. Hamad, M. A.: Prediction of thermomagnetic properties of La0.67Ca0.33MnO3 and La\(_{\mathrm {0.67}}\)Ca\(_{\mathrm {0.33}}\)MnO3 and La0.67Sr0.33MnO3. Phase Transit. 85, 106 (2012)

    Article  Google Scholar 

  18. M’nassri, R., Cheikhrouhou, A.: Magnetocaloric effect in LaFe10.7Co0.8Si1.5 compound near room LaFe10.7Co0.8Si\(_{\mathrm {1.5}}\) compound near room temperature. J. Supercond. Nov. Magn. 27, 421 (2014)

    Article  Google Scholar 

  19. Hamad, M.A.: Magnetocaloric effect of perovskite manganites Ce\(_{\mathrm {0.67}}\)Sr\(_{\mathrm {0.33}}\)MnO\(_{3}\). J. Supercond. Nov. Magn. 26, 2981 (2013)

    Article  Google Scholar 

  20. M’nassri, R., Cheikhrouhou-Koubaa, W., Chniba Boudjada, N., Cheikhrouhou, A.: Effect of barium-deficiency on the structural, magnetic, and magnetocaloric properties of La0.6Sr0.2Ba0.2−x?xMnO3(0 ≤ x \(\le \) 0.15). J. Appl. Phys. 113, 073905 (2013)

    Article  ADS  Google Scholar 

  21. Sfifir, I., Cheikhrouhou-Koubaa, W., Koubaa, M., Cheikhrouhou, A.: Theoretical investigation of magnetocaloric effect in La06Ca02Ba\(_{015}\square _{005}\)MnO\(_{3}\) manganite. J. Supercond. Nov. Magn, doi:10.1007/s10948-016-3512-4

  22. Franco, V., Conde, A., Provenzano, V., Shull, R.D.: Scaling analysis of the magnetocaloric effect in Gd5Si2Ge1.9 X 0.1(X\(=\)Al, Cu, Ga, Mn, Fe, Co). J. Magn. Magn. Mater 322, 218 (2010)

    Article  ADS  Google Scholar 

  23. M’nassri, R.: Field dependence of magnetocaloric properties in La\(_{\mathrm {0.6}}\)Pr\(_{\mathrm {0.4}}\)Fe\(_{\mathrm {10.7}}\)Co\(_{\mathrm {0.8}}\)Si\(_{\mathrm {1.5}}\). J. Supercond. Nov. Magn. 27, 1787 (2014)

    Article  Google Scholar 

  24. Bohigas, X., Tejada, J., del Barco, E., Zhang, X. X., Sales, M.: Tunable magnetocaloric effect in ceramic perovskites. Appl. Phys. Lett. 73, 390 (1998)

    Article  ADS  Google Scholar 

  25. Makni-Chakroun, J., Omrani, H., Cheikhrouhou-Koubaa, W., Koubaa, M., Cheikhrouhou, A.: Theoretical investigation of the magnetocaloric effect on stochiometric and deficient La0.7Ca0.3MnO\(_{3}\) manganite at room temperature, J. Supercond. Nov. Magn. doi:10.1007/s10948-016-3443-0

  26. Franco, V., Blazquez, J. S., Conde, A.: Field dependence of the magnetocaloric effect in materials with a second order phase transition: a master curve for the magnetic entropy change. Appl. Phys. Lett. 89, 222512 (2006)

    Article  ADS  Google Scholar 

  27. Selmi, A., M’nassri, R., Cheikhrouhou-Koubaa, W., Chniba Boudjada, N., Cheikhrouhou, A.: Influence of transition metal doping (Fe, Co, Ni and Cr) on magnetic and magnetocaloric properties of Pr\(_{\mathrm {0.7}}\)Ca\(_{\mathrm {0.3}}\)MnO\(_{3}\) manganites. Ceramics Int. 41, 10177 (2015)

    Article  Google Scholar 

  28. Fan, J., Zhang, W., Zhang, X., Zhang, L., Zhang, Y.: Scaling analysis of PM–FM phase transition in Nd0.5Sr0.25Ca0.25MnO\(_{3}\) based on magnetic entropy change. Mater. Chem. Phys. 144, 206 (2014)

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by the Tunisian Ministry of Higher Education and Scientific Research.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. Ezaami.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ezaami, A., Sellami-Jmal, E., Cheikhrouhou-Koubaa, W. et al. Phenomenological Model of Magnetocaloric Effect in La0.7Ca0.2Ba0.1MnO3 Manganite Around Room Temperature. J Supercond Nov Magn 30, 911–916 (2017). https://doi.org/10.1007/s10948-016-3887-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10948-016-3887-2

Keywords

Navigation