Abstract
Magnetic and magnetocaloric properties of La0.65−x □ x Ca0.35MnO3 (≤ x ≤ 0.15) perovskite manganites were investigated. Our polycrystalline samples were elaborated using sol–gel method. The Rietveld refinement shows that all our samples are single phase and crystallize in the orthorhombic structure with Pbnm space group. Lanthanum deficiency leads to a decrease of the unit cell volume. The surface morphology was carried out using scanning electron microscopy (SEM). Magnetization measurements versus temperature in a magnetic applied field of 50 mT showed that all our deficient samples exhibit a paramagnetic–ferromagnetic transition with decreasing temperature. With increasing lanthanum deficiency, the Curie temperature T c decreases from 275 K for x = 0 to 257 K and for x = 0.15. A large magnetic entropy change |ΔS M |, deduced from isothermal magnetization curves, has been observed in our samples with a peak centred around their respective transition temperature. The maximum of the magnetic entropy change \( \vert {\Delta } S_{M}^{\text {Max}}\vert \) under a magnetic field change of 5 T is found to decrease from 5.11 J/kg/ K for x = 0 to 3.98 J/kg K and for x = 0.15. The relative cooling power decreases from 237.5J/kg for x = 0 to 217.4 J/kg −1 and for x = 0.15.
Similar content being viewed by others
References
Heremans, J.: J. Phys. D 26, 1149 (1993)
Venkatesan, T., Rajeswari, M., Dong, Z.-W., Ogale, S.B., Ramesh, R.: Philos. Trans. R. Soc. Lond. Ser. A 356, 1661 (1998)
Jin, S., Tiefel, T.H., McCormack, M., Fastnacht, R.A., Ramesh, R., Chen, L.H.: Science 264, 413 (1994)
Zener, C.: Phys. Rev 82, 403 (1951)
Anderson, P.W., Hasegawa, H.: Phys. Rev 100, 675 (1955)
de Genes, P.G: Phys. Rev 118, 141 (1960)
Guo, Z.B., Du, Y.W., Feng, D.: Phys. Rev. Lett 78, 1142 (1997)
Guo, Z.B., Du, Y.W.: Appl. Phys. Lett 70, 904 (1997)
Pecharsky, V.K., Gschneidner, K.A. Jr.: J. Mat. 167, L179–L184 (1997)
Pecharsky, V.K., Gschneidner, K.A. Jr.: Phys. Rev. Lett 78, 4494 (1997)
Phan, M.H., Yu, S.C., Magn, J.: Magn. Mater 308, 325 (2007)
Koubaa, M., Cheikhrouhou-Koubaa, W., Cheikhrouhoua, A., Haghiri-Gosnet, A.-M.: Physica B 403, 2477–2483 (2008)
Koubaa, M., Cheikhrouhou Koubaa, W., Cheikhrouhou, A.: Phys. Procedia 2, 997–1004 (2009)
Gordon, J.E., Marcenat, C., Franck, J.P., Isaac, I., Zhang, G., Lortz, R., Meingast, C., Bouquet, F., Fisher, R.A., Phillips, N.E.: Phys. Rev. B 65, 024441 (2001)
Schiffer, P.E., Ramirez, A.P., Bao, W., Cheong, S.W.: Phys. Rev. Lett 75, 3336 (1995)
Cheikh-Rouhou Koubaa, W., Koubaa, M., Cheikhrouhou, A.: J. Alloys Compd 470, 42 (2009)
Rodriguez-Carvajal, J.: FULLPROF 2000–2005, Laboratoire Leon Briouillon (CEA-CNRS)
Kuo, J.H., Anderson, H.U., Sparlin, D.M.: J. Solid State Chem 83, 52 (1989)
Shannon, R.D.: Acta Cryst A32, 751 (1976)
Cheikhrouhou-Koubaa, W., Koubaa, M., Cheikhrouhou, A., Boujelben, W., Haghiri-Gosnet, A.-M.: J. Alloys Comp 455, 67 (2008)
Singh, N.K., Suresh, K.G., Nigam, A.K.: Solid State Commun 127, 373–377 (2003)
McMichael, R.D., Ritter, J.J., Shull, R.D.: J. Appl. Phys 73, 6946 (1993)
Pecharsky, V.K., Gschneidner, K.A., Tsokol, A.O.: Rep. Prog. Phys 68, 1479 (2005)
Acknowledgments
This work has been supported by the Tunisian Ministry of Higher Education, Scientific Research and Information and Communication Technology
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Sellami-Jmal, E., Marzouki, A., Cheikhrouhou-Koubaa, W. et al. Deficiency Effect on Magnetic and Magnetocaloric Properties of La0.65−x □ x Ca0.35MnO3 Manganites Synthesized Using Sol–Gel Technique. J Supercond Nov Magn 28, 831–838 (2015). https://doi.org/10.1007/s10948-014-2813-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10948-014-2813-8