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Structure of [RuNO(NH3)3(H2O)Cl](NO3)2, product of interaction between hydroxonitrotriamminenitrosoruthenium(II) chloride and nitric acid

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Abstract

The structure of the product formed on boiling [RuNO(NH3)3(NO2)(OH)]Cl·0.5H2O in 3 M HNO3 is determined by XRD. The crystals belong to monoclinic symmetry. Crystallographic data for H11ClN6O8Ru are: a = 13.7924(4) Å, b = 6.9114(2) Å, c = 12.3577(4) Å, β = 111.863(1)°, V = 1093.27(6) Å3, Z = 4, d calc = 2.185 g/cm3, space group Cc. The structure is built of complex [RuNO(NH3)3(H2O)Cl]2+ cations and NO −3 anions. The compound is studied by IR spectroscopy and X-ray phase analysis.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    V. A. Emel’yanov & I. A. Baidina

  2. Novosibirsk State University, Novosibirsk, Russia

    V. A. Emel’yanov & E. V. Kabin

Authors
  1. V. A. Emel’yanov
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  2. E. V. Kabin
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  3. I. A. Baidina
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Correspondence to V. A. Emel’yanov.

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Original Russian Text Copyright © 2009 by V. A. Emel’yanov, E. V. Kabin, and I. A. Baidina

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Translated from Zhurnal Strukturnoi Khimii, Vol. 50, No. 3, pp. 598–601, May–June, 2009.

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Emel’yanov, V.A., Kabin, E.V. & Baidina, I.A. Structure of [RuNO(NH3)3(H2O)Cl](NO3)2, product of interaction between hydroxonitrotriamminenitrosoruthenium(II) chloride and nitric acid. J Struct Chem 50, 577–581 (2009). https://doi.org/10.1007/s10947-009-0089-9

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  • DOI: https://doi.org/10.1007/s10947-009-0089-9

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