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Highly-efficient adsorption behavior of mesoporous Co-HDIPT toward both anionic and cationic organic dyes

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Abstract

Metal–organic frameworks (MOFs) exhibit the prominent advantages in the efficient removal of organic dyes owing to their diverse topology structure, adjustable pore parameters, high specific surface area and special affinity brought by the metal node and polydentate organic linkers. Herein, a mesoporous Co-HDIPT is synthesized successfully and employed in the adsorption tests of eight synthetic dyes for the first time involving congo red, methyl orange, reactive blue 19, basic fuchsin, malachite green, acid fuchsin, rhodamine B and acid yellow 23. These dyes are featured in different ionic nature (cationic or anionic) and functional groups. The adsorption conditions were optimized, and the adsorption kinetics and the adsorption isotherms were simulated to investigate the adsorption mechanism. Interestingly, the resulting Co-HDIPT exhibits a rapid adsorption rate toward eight organic dyes, and an extraordinary adsorption efficiency of 14,723.7 mg/g toward MG, which value is higher than the previously reported results by other MOFs-based adsorbents. To the best of our knowledge, it’s the first time to study the adsorption activities of the mesoporous Co-HDIPT, and the satisfied results would enrich the applications of mesoporous MOFs in the efficient removal of synthetic organics from the waste water.

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Acknowledgements

This work was supported by LiaoNing Science and Technology Development Foundation Guided by Central Government (2021JH6/10500141)

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  1. Faculty of Chemistry, College of Sciences, Northeastern University, Shenyang, 110819, China

    Wanhao Zheng, Zhongshuang Xu & Xia Zhang

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  1. Wanhao Zheng
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Zheng, W., Xu, Z. & Zhang, X. Highly-efficient adsorption behavior of mesoporous Co-HDIPT toward both anionic and cationic organic dyes. J Porous Mater 29, 795–806 (2022). https://doi.org/10.1007/s10934-022-01214-4

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