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Enhanced luminescent performance of 1,8-naphthalic anhydride-loaded bimodal mesoporous silicas modified by europium nitrate

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Abstract

Eu(NO3)3 was selected as an enhancer to improve the performance of luminescent hybrid bimodal mesoporous silica (LHMS), and a series of LHMS-EN(x) (Eu(NO3)3/1,8-naphthalic anhydridemolar ratio = x :1; x = 0, 0.1, 0.5, 1, 2, 2.5, and 5) samples were prepared. The influence of various Eu3+ amounts on the textural characteristics and luminescent performance of the LHMS-EN(x) samples were investigated. It is shown that Eu3+ ions played a role of fluorescence enhancer in this system, but various amounts of Eu3+ ions obviously influenced the luminescent intensity of the LHMS-EN(x) samples, with the LHMS-EN(1) sample displaying the highest luminescent intensity. The tendency of the luminescent intensity of the LHMS-EN(x) samples was gained and confirmed by that of the LHMS-EA(x) (Eu(CH3COO)3 as enhancer) and LHMS-EC(x) (Eu(Cl)3 as enhancer) samples.

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Acknowledgements

This work was supported by Natural Science Fund of Inner Mongolia (2019MS05071); the Natural Science Foundation of Shanxi Province (201901D111068) and National Natural Science Foundation of China (NSFC, 51766012). The authors gratefully acknowledge Prof. Jihong Sun in the College of Environmental and Energy Engineering, Beijing University of Technology.

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Correspondence to Suying Yan or Yuzhen Li.

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Wang, F., Yan, S., Li, Y. et al. Enhanced luminescent performance of 1,8-naphthalic anhydride-loaded bimodal mesoporous silicas modified by europium nitrate. J Porous Mater 28, 1779–1785 (2021). https://doi.org/10.1007/s10934-021-01123-y

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