Abstract
Mesoporous magnetic nanoparticles (MNPs) were synthesized using the chemical co-precipitation method. The structure, morphology and magnetic properties of the MNPs were examined by X-ray diffraction (XRD), Mossbauer spectroscopy (MS), Brunauer–Emmett–Teller (BET) method, Transmission Electron Microscopy (TEM) and Vibrating Sample Magnetometer (VSM). The results of XRD and MS indicated that the MNPs were composed of γ-Fe2O3. TEM microphotography showed that the magnetic material was an aggregate of small spherical particles with a size of 6–12 nm. According to the BET data, the agglomeration of individual maghemite nanoparticles lead to formation of a complex mesoporous structure with the specific surface area of 88.3 m2 g−1. The average pore diameter was 5–7 nm, which correlates with the γ-Fe2O3 particles size. The VSM measurement (MS = 40.54 emu g−1, Mr = 5.27 emu g−1, HC = 88 Oe) indicated that the γ-Fe2O3 exhibited weak ferromagnetic and soft magnetic properties confirming the agglomeration of the small γ-Fe2O3 nanoparticles. The synthesized mesoporous maghemite showed excellent ability to absorb polymer protected colloidal palladium particles (Pd-PAM). The magnetic properties of MNPs were not significantly changed after modification with Pd-PAM. The resulting catalyst of Pd-PAM/MNPs showed activity (WC≡C = 3.3 × 10–6 mol s−1) and selectivity (93%) in the hydrogenation of phenylacetylene under mild conditions of 40 °C and 0.1 MPa. The Pd-PAM/MNPs catalyst can be easily recovered with an external magnet and reused for at least seven runs without significant degradation in the catalytic activity and selectivity.
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A.M. Abu-Dief, S.M. Abdel-Fatah, Beni-Suef Univ. J. Basic Appl. Sci. 7, 55 (2018)
M.B. Gawande, A.K. Rathi, P.S. Branco, R.S. Varma, Appl. Sci. 3, 656 (2013)
J. Govan, Y.K. Gun’ko, Nanomaterials 4, 222 (2014)
A. Akbarzadeh, M. Samiei, S. Davaran, Nanoscale Res. Lett. 7, 144 (2012)
O.R. Egunova, T.A. Konstantinova, S.N. Shtykov, Magnetic nanoparticles in separation and preconcentration, Izvestiya of Saratov University. New series. Ser. Chem. Biol. Ecol. (Russia) 14(4), 27 (2014). (In Russian)
L. Mohammed, H.G. Gomaa, D. Ragab, J. Zhu, Particuology 30, 1 (2017)
S. Majidi, F. Zeinali Sehrig, S.M. Farkhani, M. Soleymani Goloujeh, A. Akbarzadeh, Artificial cells. Nanomed. Biotechnol. 44(2), 722 (2014)
A.-H. Lu, E.L. Salabas, F. Schuth, Angew. Chem. Int. Ed. 46, 1222 (2007)
W. Wu, Z. Wu, T. Yu, C. Jiang, W.-S. Kim, Sci. Technol. Adv. Mater. 16, 023501 (2015)
W. Wu, Q. He, C. Jiang, Nanoscale Res. Lett. 3, 397 (2008)
M.C. Mascolo, Y. Pei, T.A. Ring, Materials 6, 5549 (2013)
Y. Wei, B. Han, X. Hu, Y. Lin, X. Wang, X. Deng, Procedia Eng. 27, 632 (2012)
M.I. Majeed, J. Guo, W. Yan, B. Tan, Polymers 8(11), 392 (2016)
M. Nazari, N. Ghasemi, H. Maddah, M.M. Motlagh, J. Nanostruct. Chem. (2014). https://doi.org/10.1007/s40097-014-0099-9
R.A. Bohara, N.D. Thorat, S.H. Pawar, RSC Adv. 6, 43989 (2016)
L.M. Rossi, N.J.S. Costa, F.P. Silva, R. Wojcieszak, Green Chem. 16, 2906 (2014)
S.-W. Chen, Z.-C. Zhang, N.-N. Zhai, C.-M. Zhong, S. Lee, Tetrahedron 71(4), 648 (2015)
J. Zhao, Y. Gui, Y. Liu, G. Wang, H. Zhang, Y. Sun, Sh Fang, Catal. Lett. 147, 1127 (2017)
R.B. Nasir Baig, R.S. Varma, ACS Sust. Chem. Eng. 2, 2155 (2014)
M. Neamtu, C. Nadejde, V. Hodoroaba, R.J. Schneider, L. Verestiuc, U. Panne, Sci. Rep. 8, 6278 (2018)
M. Zeltner, A. Schatz, M.L. Hefti, W.J. Stark, J. Mater. Chem. 21, 2991 (2011)
E.T. Talgatov, A.S. Auyezkhanova, K.S. Seitkalieva, S.N. Akhmetova, A.К. Zharmagambetova, Theor. Exp. Chem. 55, 331 (2019)
E.T. Talgatov, A.S. Auyezkhanova, N.Z. Tumabayev, S.N. Akhmetova, K.S. Seitkalieva, Y.A. Begmat, A.К. Zharmagambetova, News of NAS RK. Ser. Chem. Technol. 6, 29 (2018)
R. Massart, IEEE Trans. Magn. 17, 1247 (1981)
M. Krishna Surendra, S. Annapoorani, E.B. Ansar, P.R. Harikrishna Varma, M.S. Ramachandra Rao, J. Nanopart. Res. 16, 2773 (2014)
L. Li, D. Chen, Y. Zhang, Z. Deng, X. Ren, X. Meng, F. Tang, J. Ren, L. Zhang, Nanotechnology 18, 405102 (2007)
H. Montaseri, S. Alipour, M.A. Vakilinezhad, Res. Pharm. Sci. 12(4), 274 (2017)
A.K. Zharmagambetova, K.S. Seitkalieva, E.T. Talgatov, A.S. Auezkhanova, G.I. Dzhardimalieva, A.D. Pomogailo, Kinet. Catal. 57, 360 (2016)
I. Kazeminezhad, S. Mosivand, Acta Phys. Polonica A 125, 1210 (2014)
W. Kim, C.-Y. Suh, S.-W. Cho, K.-M. Roh, H. Kwon, K. Song, I.-J. Shon, Talanta 94, 348 (2012)
S. Navaladian, B. Viswanathan, T.K. Varadarajan, R.P. Viswanath, Nanoscale Res. Lett. 4(2), 181 (2009)
W. Cheng, K. Tang, Y. Qi, J. Sheng, Z. Liu, J. Mater. Chem. 20, 1799 (2010)
K.A. Kydralieva, G.I. Dzhardimalieva, A.A. Yurishcheva, S.J. Jorobekova, J. Inorg. Organomet. Polym. 26, 1212 (2016)
N.E. Gervits, A.A. Gippius, A.V. Tkachev, E.I. Demikhov, S.S. Starchikov, I.S. Lyubutin, A.L. Vasiliev, V.P. Chekhonin, M.A. Abakumov, A.S. Semkina, A.G. Mazhuga, Beilstein J. Nanotechnol. 10, 1964 (2019)
I.S. Lyubutin, S.S. Starchikov, C.-R. Lin, N.E. Gervits, NYu Korotkov, T.V. Bukreeva, Croat. Chem. Acta 88(4), 397 (2015)
I.N. Zakharova, M.A. Shipilin, V.P. Alekseev, A.M. Shipilin, Techn. Phys. Lett. 38(1), 55 (2012)
M.I. Khalil, Arab. J. Chem. 8, 279 (2015)
K. Woo, J. Hong, S. Choi, H.-W. Lee, J.-P. Ahn, C.S. Kim, S.W. Lee, Chem. Mater. 16, 2814 (2004)
I.S. Lyubutin, S.S. Starchikov, T.V. Bukreeva, I.A. Lysenko, S.N. Sulyanov, N.Y. Korotkov, S.S. Rumyantseva, I.V. Marchenko, K.O. Funtov, A.L. Vasiliev, Mater. Sci. Eng. C 45, 225 (2014)
L. Gutiérrez, L. de la Cueva, M. Moros, E. Mazario, S. de Bernardo, J.M. de la Fuente, M.P. Morales, G. Salas, Nanotechnology 30(11), 112001 (2019)
V.A.J. Silva et al., Magnetic and Mössbauer studies of fucan-coated magnetite nanoparticles for application on antitumoral activity, in LACAME 2012, ed. by C.A.B. Meneses, E.P. Caetano, C.E.R. Torres, C. Pizarro, L.E.Z. Alfonso (Springer, Dordrecht, 2013)
V.A.J. Silva, P.L. Andrade, M.P.C. Silva, A. Bustamante, L. De Los Santos Valladares, J. Albino, J. Magn. Magn. Mater. 343, 138 (2013)
W. Wu, X.H. Xiao, S.F. Zhang, T.C. Peng, J. Zhou, F. Ren, C.Z. Jiang, Nanoscale Res. Lett. 5, 1474 (2010)
D. Cao, H. Li, L. Pan, J. Li, X. Wang, P. Jing, X. Cheng, W. Wang, J. Wang, Q. Liu, Sci. Rep. 6, 32360 (2016)
M.U. Zulfiqar, M.U. Rahman, M. Usman, S.K. Hasanain, A. Ullah, I.W. Kim, J. Korean Phys. Soc. 65, 1925 (2014)
J. Choi, Y. Han, S. Park, J. Park, H. Kim, J. Nanomater. 2014, 580347 (2014)
F. Sotomayor, K.A. Cychosz, M. Thommes, Acc. Mater. Surf. Res. 3(2), 34 (2018)
W. Wu, X. Xiao, S. Zhang, L. Fan, T. Peng, F. Ren, C. Jiang, Nanoscale Res. Lett. 5, 116 (2009)
R. Kosydar, M. Goral, A. Drelinkiewicz, J. Stejskal, Chem. Papers 67(8), 1087 (2013)
L.B. Belykh, N.I. Skripov, T.P. Sterenchuk, K.L. Gvozdovskaya, S.B. Sanzhieva, F.K. Schmidt, J. Nanopart. Res. 21, 198 (2019)
Z. Ahmed, E.A. Gooding, K.V. Pimenov, L. Wang, S.A. Asher, J. Phys. Chem. B 113(13), 4248 (2009)
H.A. Al-Wadhaf, Catal. Ind. 7, 234 (2015)
C. Evangelisti, N. Panziera, A. D’Alessio, L. Bertinetti, M. Botavina, G. Vitulli, J. Catal. 272, 246 (2010)
F.P. da Silva, L.M. Rossi, Tetrahedron 70, 3314 (2014)
N.V. Kuchkina, EYu Yuzik-Klimova, S.A. Sorokina, A.S. Peregudov, DYu Antonov, S.H. Gage, B.S. Boris, L.Z. Nikoshvili, E.M. Sulman, D.G. Morgan, W.E. Mahmoud, A.A. Al-Ghamdi, L.M. Bronstein, Z.B. Shifrina, Macromolecules 46, 5890 (2013)
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The work was carried out with the financial support of the State Committee of Science of the Ministry of Education and Science of the Republic of Kazakhstan (Grant AR05130377).
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Talgatov, E.T., Auyezkhanova, A.S., Seitkalieva, K.S. et al. Co-precipitation synthesis of mesoporous maghemite for catalysis application. J Porous Mater 27, 919–927 (2020). https://doi.org/10.1007/s10934-020-00869-1
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DOI: https://doi.org/10.1007/s10934-020-00869-1