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CO2 capture of amino functionalized three-dimensional worm-hole mesostructured MSU-J silica

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Abstract

Tetraethylenepentamine (TEPA) was employed to functionalize the large-pore mesoporous silica (denoted MSU-J) with 3D worm-hole framework structures which was prepared through a supramolecular hydrogen-bonding assembly pathway from low-cost H2NCH(CH3)CH2[OCH2CH(CH3)]33NH2 (D2000) as structure-directing porogens and tetraethylorthosilioate as the silica source for capturing CO2. The resultant adsorbents were characterized by FT-IR, Transmission electron microscopy (TEM), N2 adsorption/desorption and thermogravimetric analysis. Textural properties, elemental analysis and TEM measurement of the samples showed a severe pore filling of MSU-J as TEPA loading was increased to 70 wt%. CO2 adsorption isotherms measured at different temperatures revealed the optimal adsorption temperature is 25 °C. The adsorption capacity of MSU-J with different TEPA loading contents was calculated. As a result, 50 wt% of TEPA supported on as-synthesized MSU-J achieved the highest capacity with the value of 164.3 mg/g under the conditions of 99.99 % CO2 at 25 °C and 0.1 MPa. Repeated adsorption/desorption cycles revealed that amine-impregnated materials was very efficient for less apparent decrease in CO2 adsorption capacity even after 6 adsorption–regeneration cycles.

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References

  1. D.S. Dao, H. Yamada, K. Yogo, Ind. Eng. Chem. Res. 52, 13810 (2013)

    Article  CAS  Google Scholar 

  2. N. Hiyoshi, K. Yogo, T. Yashima, Microporous Mesoporous Mater. 84, 357 (2005)

    Article  CAS  Google Scholar 

  3. C. Song, Catal. Today 115, 2 (2006)

    Article  CAS  Google Scholar 

  4. J.S. Lee, J.H. Kim, J.T. Kim, J.K. Suh, J.M. Lee, C.H. Lee, J. Chem. Eng. Data 47, 1237 (2002)

    Article  CAS  Google Scholar 

  5. F. Dreisbach, R. Staudt, J. Keller, Adsorption 5, 215 (1999)

    Article  CAS  Google Scholar 

  6. J. Merel, M. Clausse, F. Meunier, Ind. Eng. Chem. Res. 47, 209 (2008)

    Article  CAS  Google Scholar 

  7. J. Wei, L. Liao, Y. Xiao, P. Zhang, Y. Shi, J. Environ. Sci. 22, 1558 (2010)

    Article  CAS  Google Scholar 

  8. X. Zhang, X. Zheng, S. Zhang, B. Zhao, WWu Ind, Eng. Chem. Res. 51, 15163 (2012)

    Article  CAS  Google Scholar 

  9. R.W. Baker, Ind. Eng. Chem. Res. 41, 1393 (2002)

    Article  CAS  Google Scholar 

  10. A. Demessence, D.M. D’Alessandro, M.L. Foo, J.R. Long, J. Am. Chem. Soc. 131, 8784 (2009)

    Article  CAS  Google Scholar 

  11. M.B. Yue, L.B. Sun, Y. Cao, Y. Wang, Z.J. Wang, J.H. Zhu, Chem. Eur. J. 14, 3442 (2008)

    Article  CAS  Google Scholar 

  12. S. Kim, J. Ida, V.V. Guliants, Y. Lin, J. Phys. Chem. 109, 6287 (2005)

    Article  CAS  Google Scholar 

  13. W.J. Son, J.S. Choi, W.S. Ahn, Microporous Mesoporous Mater. 113, 31 (2008)

    Article  CAS  Google Scholar 

  14. X. Xu, C. Song, J.M. Andresen, B.G. Miller, A.W. Scaroni, Energy Fuels 16, 1463 (2002)

    Article  CAS  Google Scholar 

  15. H.Y. Huang, R.T. Yang, D. Chinn, C.L. Munson, Ind. Eng. Chem. Res. 42, 2427 (2003)

    Article  CAS  Google Scholar 

  16. W.J. Stevens, K. Lebeau, M. Mertens, G. Van Tendeloo, P. Cool, E.F. Vansant, J. Phys. Chem. 110, 9183 (2006)

    Article  CAS  Google Scholar 

  17. M.B. Yue, Y. Chun, Y. Cao, X. Dong, J.H. Zhu, Adv. Funct. Mater. 16, 1717 (2006)

    Article  CAS  Google Scholar 

  18. J. Wei, J. Shi, H. Pan, W. Zhao, Q. Ye, Y. Shi, Microporous Mesoporous Mater. 116, 399 (2008)

    Article  Google Scholar 

  19. V. Zelenak, Da Halamova, L. Gaberova, E. Bloch, P. Llewellyn, Microporous Mesoporous Mater. 116, 358 (2008)

    Article  CAS  Google Scholar 

  20. F. Zheng, D.N. Tran, B.J. Busche, G.E. Fryxell, R.S.A. ddleman, T.S. Zemanian, C.L. Aardahl, Ind. Eng. Chem. Res. 44, 3099 (2005)

    Article  CAS  Google Scholar 

  21. M.R. Mello, D. Phanon, G.Q. Silveira, P.L. Llewellyn, C.M. Ronconi, Microporous Mesoporous Mater. 143, 174 (2011)

    Article  CAS  Google Scholar 

  22. R. Sanz, G. Calleja, A. Arencibia, E.S. Sanz-Pérez, Microporous Mesoporous Mater. 158, 309 (2012)

    Article  CAS  Google Scholar 

  23. X. Wang, V. Schwartz, J.C. Clark, X. Ma, S.H. Overbury, X. Xu, C. Song, J. Phys. Chem. 113, 7260 (2009)

    CAS  Google Scholar 

  24. N. Hiyoshi, K. Yogo, T. Yashima, Chem. Lett. 37, 1266 (2008)

    Article  CAS  Google Scholar 

  25. A. Maria Chong, X. Zhao, J Phys. Chem. 107, 12650 (2003)

    Article  Google Scholar 

  26. I. Park, Z. Wang, T.J. Pinnavaia, Chem. Mater. 17, 383 (2005)

    Article  CAS  Google Scholar 

  27. X. Yan, L. Zhang, Y. Zhang, G. Yang, Z. Yan, Ind. Eng. Chem. Res. 50, 3220 (2011)

    Article  CAS  Google Scholar 

  28. V. Zeleňák, M. Badaničová, D. Halamova, J. Čejka, A. Zukal, N. Murafa, G. Goerigk, Chem. Eng. J. 144, 336 (2008)

    Article  Google Scholar 

  29. X. Xu, C. Song, J.M. Andrésen, B.G. Miller, A.W. Scaroni, Microporous Mesoporous Mater. 62, 29 (2003)

    Article  CAS  Google Scholar 

  30. X. Yan, L. Zhang, Y. Zhang, K. Qiao, Z. Yan, S. Komarneni, Chem. Eng. J. 168, 918 (2011)

    Article  CAS  Google Scholar 

  31. S. Satyapal, T. Filburn, J. Trela, J. Strange, Energy Fuels 15, 250 (2001)

    Article  CAS  Google Scholar 

  32. C. Chen, S.T. Yang, W.S. Ahn, R. Ryoo, Chem. Commun. 24, 3627 (2009)

    Article  Google Scholar 

  33. X. Yan, L. Zhang, Y. Zhang, G. Yang, Z. Yan, Ind. Eng. Chem. Res. 50, 3220 (2011)

    Article  CAS  Google Scholar 

  34. X. Wang, H. Li, H. Liu, X. Hou, Microporous Mesoporous Mater. 142, 2 (2011)

    Google Scholar 

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Acknowledgments

This study was supported by National Natural Science Foundation (NO.51373135) and graduate starting seed fund of Northwestern Polytechnical University (NO. Z2014170).

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Authors and Affiliations

  1. Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi’an, 710072, People’s Republic of China

    Jian Jiao, Panpan Lv, Lei Wang, Shaomin Dan, Lu Qi & Yonghong Cui

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  1. Jian Jiao
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  2. Panpan Lv
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  3. Lei Wang
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  4. Shaomin Dan
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  5. Lu Qi
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  6. Yonghong Cui
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Correspondence to Jian Jiao.

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Jiao, J., Lv, P., Wang, L. et al. CO2 capture of amino functionalized three-dimensional worm-hole mesostructured MSU-J silica. J Porous Mater 21, 775–781 (2014). https://doi.org/10.1007/s10934-014-9824-5

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  • DOI: https://doi.org/10.1007/s10934-014-9824-5

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