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Preparation and characterization of a novel host (zeolite NaY)/guest (copper(II) complex of a new bidentate Schiff base ligand) nanocomposite material (HGNM): a comparison between catalytic reactivity of free and encapsulated complexes in oxidation of benzyl alcohol and aldol condensation

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Abstract

A copper(II) complex of 4-((E)-(4-(1H-benzo[d]imidazol-2-yl)phenyl)diazenyl)-2-((E)-(4-hydroxyphenylimino) methyl)phenol (HL) was encapsulated in zeolite NaY by flexible ligand method. The structure of encapsulated complex was characterized by spectroscopic (electronic and FT-IR), XRD, TGA, BET and elemental analysis data. Furthermore, catalytic activity of the neat and encapsulated complexes was studied in oxidation of benzyl alcohol and aldol condensation. The encapsulated complex was more reactive and stable than the corresponding free complex. Nanocomposite material was enough stable to be reused for several times. Finally, the reaction parameters were optimized for oxidation of benzyl alcohol and aldol condensation.

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Acknowledgments

We gratefully acknowledge the financial support from the Research Council of Arak University.

Ethical standards

The experiments comply with the current laws of the Islamic Republic of Iran.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Arak University, Arak, 38156-8-8349, Iran

    Akbar Mobinikhaledi, Mojgan Zendehdel & Parvin Safari

Authors
  1. Akbar Mobinikhaledi
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  2. Mojgan Zendehdel
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  3. Parvin Safari
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Correspondence to Parvin Safari.

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Mobinikhaledi, A., Zendehdel, M. & Safari, P. Preparation and characterization of a novel host (zeolite NaY)/guest (copper(II) complex of a new bidentate Schiff base ligand) nanocomposite material (HGNM): a comparison between catalytic reactivity of free and encapsulated complexes in oxidation of benzyl alcohol and aldol condensation. J Porous Mater 21, 565–577 (2014). https://doi.org/10.1007/s10934-014-9803-x

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