Abstract
In this study, the accelerated weathering of PLA and its biocomposites produced with agro-industrial waste agave fibers was evaluated to better understand the lifetime of these materials. The effects of the fiber content, the fiber treatment with glycidyl methacrylate grafted PLA, and the fiber/matrix adhesion on the degradation of the materials were also analyzed. The biocomposites were prepared by dry blending, followed by compression molding using untreated and chemically modified agave fibers. The chemical treatment promoted a better fiber–matrix adhesion and lower fiber pull-outs resulting in high tensile and flexural strength values (similar to the neat PLA even with 40 wt% of fiber). Once the modification of the fiber–matrix was observed to be effective, the effect of accelerated weathering over compatibilized and uncompatibilized biocomposites was evaluated. The results showed that after accelerated weathering, the crystallinity of the biocomposites increased significantly, causing that the impact strength remains constant and, in some cases, even improved. At the same time, tensile and flexural properties were noticeably decreased. Nevertheless, the treated fibers which have better adhesion to the matrix led a better resistance to weathering degradation, which is confirmed by higher dimensional stability and lower decreases in tensile and flexural properties than biocomposites with untreated fibers.
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Ligot S, Benali S, Ramy-Ratiarison R, Murariu M, Snyders R, Dubois P (2015) Mater Sci Eng Adv Res 1:20. https://doi.org/10.24218/msear.2015.04
Awal A, Rana M, Sain M (2015) Mech Mater 80:87. https://doi.org/10.1016/j.mechmat.2014.09.009
Bordes P, Pollet E, Avérous L (2009) Prog Polym Sci 34:125. https://doi.org/10.1016/j.progpolymsci.2008.10.002
Farah S, Anderson DG, Langer R (2016) Adv Drug Deliv Rev 107:367. https://doi.org/10.1016/j.addr.2016.06.012
Murariu M, Dubois P (2016) Adv Drug Deliv Rev 107:17. https://doi.org/10.1016/j.addr.2016.04.003
Way C, Wu DY, Cram D, Dean K, Palombo E (2013) J Polym Environ 21:54. https://doi.org/10.1007/s10924-012-0462-1
Mukherjee T, Kao N (2011) J Polym Environ 19:714. https://doi.org/10.1007/s10924-011-0320-6
Torres-Tello EV, Robledo-Ortíz JR, González-García Y, Pérez-Fonseca AA, Jasso-Gastinel CF, Mendizábal E (2017) Ind Crops Prod 99:117. https://doi.org/10.1016/j.indcrop.2017.01.035
Kovacevic Z, Bischof S, Fan M (2015) Composites Part B Eng 78:122. https://doi.org/10.1016/j.compositesb.2015.02.034
Consejo Regulador del Tequila (2020) https://www.crt.org.mx/images/Documentos/EstrategiaSustentabilidad.pdf. Accessed Sept 2020
Cisneros-López EO, Pérez-Fonseca AA, González-García Y, Ramírez-Arreola DE, González-Nuñez R, Rodrigue D, Robledo-Ortíz JR (2018) Adv Polym Technol 37:2528. https://doi.org/10.1002/adv.21928
Pérez-Fonseca AA, Robledo-Ortíz JR, Moscoso-Sánchez FJ, Fuentes-Talavera FJ, Rodrigue D, González-Núñez R (2015) J Polym Environ 23:126. https://doi.org/10.1007/s10924-014-0706-3
Cisneros-López EO, Pérez-Fonseca AA, Fuentes-Talavera FJ, ANzaldo J, González-Núñez R, Rodrigue D, Robledo-Ortíz JR (2016) Polym Eng Sci 56:856. https://doi.org/10.1002/pen.24314
Pérez-Fonseca AA, Robledo-Ortíz JR, González-Núñez R, Rodrigue D (2016) J Appl Polym Sci 133:43750. https://doi.org/10.1002/app.43750
González-López ME, Robledo-Ortíz JR, Manríquez-González R, Silva-Guzmán JA, Pérez-Fonseca AA (2018) Compos Interfaces 25:515. https://doi.org/10.1080/09276440.2018.1439622
González-López ME, Pérez-Fonseca AA, Cisneros-López EO, Manríquez-González R, Ramírez-Arreola DE, Rodrigue D, Robledo-Ortíz JR (2019) J Polym Envrion 27:61. https://doi.org/10.1007/s10924-018-1308-2
Cisneros-López EO, González-López ME, Pérez-Fonseca AA, González-Núñez R, Rodrigue D, Robledo-Ortíz JR (2017) Compos Interfaces 24:35. https://doi.org/10.1080/09276440.2016.1184556
Deka BK, Maji TK (2011) Composites Part A Appl Sci Manuf 42:2117. https://doi.org/10.1016/j.compositesa.2011.09.023
Zhang H (2014) Mater Des 59:130. https://doi.org/10.1016/j.matdes.2014.02.048
Wang Y, Weng Y, Wang L (2014) Polym Test 36:119. https://doi.org/10.1016/j.polymertesting.2014.04.001
Nguyen TC, Ruksakulpiwat C, Rugmai S, Soontaranon S, Ruksakulpiwat Y (2017) Compos Sci Technol 143:106. https://doi.org/10.1016/j.compscitech.2017.02.032
Khan BA, Na H, Chevali V, Warner P, Zhu J, Wang H (2018) J Mater Sci Technol 34:387. https://doi.org/10.1016/j.jmst.2017.03.004
Martín del Campo AS, Robledo-Ortíz JR, Arellano M, Jasso-Gastinel CF, Silva-Jara JM, López-Naranjo EJ, Pérez-Fonseca AA (2020) Rev Mex Ing Quim 19:455. https://doi.org/10.24275/rmiq/Mat627
Sood M, Dwivedi G (2018) Egypt J Pet 27:775. https://doi.org/10.1016/j.ejpe.2017.11.005
Kyutoku H, Maeda N, Sakamoto H, Nishimura H, Yamada K (2019) Carbohydr Polym 203:95. https://doi.org/10.1016/j.carbpol.2018.09.033
Xie Y, Xiao Z, Grüneberg T, Militz H, Hill CAS, Steuernagel L, Mai C (2010) Compos Sci Technol 70:2003. https://doi.org/10.1016/j.compscitech.2010.07.024
Islam MS, Pickering KL, Foreman NJ (2010) Polym Degrad Stab 95:59. https://doi.org/10.1016/j.polymdegradstab.2009.10.010
Pickett JE (2018). In: Kutz M (ed) Handbook of environmental degradation of materials, 3rd edn. Elsevier, New York, p 163. https://doi.org/10.1016/C2016-0-02081-8
Ratanawilai T, Taneerat K (2018) Constr Build Mater 172:349. https://doi.org/10.1016/j.conbuildmat.2018.03.266
Koo GH, Jang J (2008) J Fiber Polym 9:674. https://doi.org/10.1007/s12221-008-0106-1
Harmean AS, Khalina A, Azowa I, Hassan MA, Tarmian A, Jawaid M (2015) Polym Compos 36:576. https://doi.org/10.1002/pc.22974
Mathew AP, Oksman K, Sain M (2006) J Appl Polym Sci 101:300. https://doi.org/10.1002/app.23346
Jiang A, Xu X, Wu H (2016) Polym Compos 37:802. https://doi.org/10.1002/pc.23237
Mohanty AK, Misra M, Hinrichsen G (2000) Macromol Mater Eng 276–277:1. https://doi.org/10.1002/(SICI)1439-2054(20000301)276:1<1::AID-MAME1>3.0.CO;2-W
Varsavas SD, Kaynak C (2018) Mater Today Commun 15:344. https://doi.org/10.1016/j.mtcomm.2017.11.008
Turku I, Kärki T (2016) Composites Part A Appli Sci Manuf 81:305. https://doi.org/10.1016/j.compositesa.2015.11.028
Badji C, Soccalingame L, Garay H, Bergeret A, Bénézet JC (2017) Polym Degrad Stab 137:162. https://doi.org/10.1016/j.polymdegradstab.2017.01.010
Lizarraga-Laborín LL, Quiroz-Castillo JM, Encinas-Encinas JC, Castillo-Ortega MM, Burruel-Ibarra SE, Romero-García J, Tores-Ochoa JA, Cabrera-Germán D, Rodríguez-Félix DE (2018) Polym Degrad Stab 155:43. https://doi.org/10.1016/j.compositesa.2015.11.028
Chun KS, Husseinsyah S (2014) J Thermoplast Compos Mater 27:1. https://doi.org/10.1177/0892705712475008
Dong Y, Ghataura A, Takagi H, Haroosh HJ, Nakagaito AN, Lau KT (2014) Composites Part A Appli Sci Manuf 63:76. https://doi.org/10.1016/j.compositesa.2014.04.003
Sajna VP, Mohanty S, Nayak SK (2016) Polym Adv Technol 27:515. https://doi.org/10.1002/pat.3698
Arias A, Heuzey MC, Huneault MA (2013) Cellulose 20:439. https://doi.org/10.1007/s10570-012-9836-8
Kaynak C, Erdogan AR (2016) Polym Adv Technol 27:812. https://doi.org/10.1002/pat.3721
Sawpan MA, Islam MR, Beg MDH, Pickering K (2019) J Polym Environ 27:942. https://doi.org/10.1007/s10924-019-01405-2
Kaynak C, Sari B (2016) Appl Clay Sci 121–122:86. https://doi.org/10.1016/j.clay.2015.12.025
Spiridon I, Darie RN, Kangas H (2016) Compos Part B Eng 92:19. https://doi.org/10.1016/j.compositesb.2016.02.032
Spiridon I, Darie-Nita RN, Bele A (2018) J Clean Prod 172:2567. https://doi.org/10.1016/j.jclepro.2017.11.154
Kim KW, Lee BH, Kim HJ (2012) J Therm Anal Calorim 108:1131. https://doi.org/10.1007/s10973-011-1350-y
Spiridon I, Leluk K, Resmerita AM, Darie RN (2015) Compos Part B Eng 69:342. https://doi.org/10.1016/j.compositesb.2014.10.006
Tsuji H, Sugiyama H, Sato Y (2012) J Polym Environ 20:706. https://doi.org/10.1007/s10924-012-0424-7
Yang W, Dominici F, Fortunati E, Kenny JM, Puglia D (2015) Ind Crops Prod 77:833. https://doi.org/10.1016/j.indcrop.2015.09.057
Lv S, Liu X, Gu J, Jiang Y, Tan H, Zhang Y (2017) Constr Build Mater 144:525. https://doi.org/10.1016/j.conbuildmat.2017.03.209
Tsuji H, Echizen Y, Saha SK, Nishimura Y (2005) Macromol Mater Eng 290:1192. https://doi.org/10.1002/mame.200500278
Darie RN, Vlad S, Anghel N, Doroftei F, Tamminen T, Spiridon I (2015) Polym Adv Technol 26:941–952. https://doi.org/10.1002/pat.3506
Lila MK, Shukla K, Komal UK, Singh I (2019) Composites Part B Eng 156:121. https://doi.org/10.1016/j.compositesb.2018.08.068
Lv S, Gu J, Tan H, Zhang Y (2018) J Clean Prod 203:328. https://doi.org/10.1016/j.jclepro.2018.08.266
Acknowledgements
The authors acknowledge the State Council of Science and Technology of Jalisco (COECyTJAL) for the grant FODECIJAL 8107 − 2019 and the Mexican National Council of Science and Technology (CONACyT) for a scholarship (A.S. Martín del Campo, #742432).
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Martín del Campo, A.S., Robledo-Ortíz, J.R., Arellano, M. et al. Accelerated Weathering of Polylactic Acid/Agave Fiber Biocomposites and the Effect of Fiber–Matrix Adhesion. J Polym Environ 29, 937–947 (2021). https://doi.org/10.1007/s10924-020-01936-z
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DOI: https://doi.org/10.1007/s10924-020-01936-z