Abstract
In this paper, Co3O4 nanoparticles and Co3O4 modified reduced graphene oxide (Co3O4/rGO) are successfully elaborated by hydrothermal method and used as anode materials in lithium-ion batteries. The structure, composition, and morphology of the hydrothermal powders are characterized by XRD, Raman spectroscopy, SEM, and TEM while their electrochemical performance was evaluated using cyclic voltammetry and galvanostatic charge/discharge studies. The Co3O4/rGO anode exhibit improved electrochemical performance in terms of specific capacity, reversibility and stability compared to single-component Co3O4. At 0.1 A g−1, the specific charge/discharge capacity for the pure Co3O4 is 855 mAh g−1 and 850 mAh g−1 respectively, while for Co3O4/rGO composite is about 1198 mAh g−1 and 1285 mAh g−1 respectively. It is found that the conductivity values increase with adding of the rGO from 4.4 × 10−4 Ω cm for the Co3O4 to 4.5 × 105 Ω cm for Co3O4/rGO composite. The improvement in the electrochemical capacity of the composite anode is mainly ascribed to a cooperative effect between the rGO with good electrical conductivity and the unique nano-sized Co3O4 with a short diffusion pathway for lithium ions diffusion.
Similar content being viewed by others
Data Availability
The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.
References
J.C. Deng, L.T. Kang, G.L. Bai, Y. Li, P.Y. Li, X.G. Liu, Y.Z. Yang, F. Gao, W. Liang, Solution combustion synthesis of cobalt oxides (Co3O4 and Co3O4/CoO) nanoparticles as supercapacitor electrode materials. Electrochim. Acta 132, 127–135 (2014). https://doi.org/10.1016/j.electacta.2014.03.158
C.Z. Yuan, L. Chen, B. Gao, L.H. Su, X.G. Zhang, Synthesis and utilization of RuO2xH2O nanodots well dispersed on poly(sodium 4-styrene sulfonate) functionalized multi-walled carbon nanotubes for supercapacitors. J. Mater. Chem. 19, 246–252 (2009). https://doi.org/10.1039/B811548F
S. Chen, P. Bao, L. Xiao, G. Wang, Large-scale and low-cost synthesis of graphene as high capacity anode materials for lithium-ion batteries. Carbon 64, 158–169 (2013)
S. Chen, Y. Zhao, B. Sun, Z. Ao, X. Xie, Y. Wei, G. Wang, Microwave-assisted synthesis of mesoporous Co3O4 nanoflakes for applications in lithium ion batteries and oxygen evolution reactions. ACS Appl. Mater. Interfaces 7(5), 3306–3313 (2015)
M. Jing, M. Zhou, G. Li, Z. Chen, W. Xu, X. Chen, Z. Hou, Graphene-embedded Co3O4 rose-spheres for enhanced performance in lithium-ion batteries. ACS Appl. Mater. Interfaces 9(11), 9662–9668 (2017). https://doi.org/10.1021/acsami.6b16396
K. Kang, Y.S. Meng, J. Breger, C.P. Grey, G. Ceder, Electrodes with high power and high capacity for rechargeable lithium batteries. Science 311, 977–979 (2006). https://doi.org/10.1126/science.1122152
A.S. Arico, P. Bruce, B. Scrosati, J. Tarascon, W.V. Schalkwijk, Nanostructured materials for advanced energy conversion and storage devices. Nat. Mater. 4, 366–377 (2005). https://doi.org/10.1038/nmat1368
L. Ji, Z. Lin, M. Alcoutlabi, X. Zhang, Recent developments in nanostructured anode materials for rechargeable lithium-ion batteries. Energy Environ. Sci. 4, 2682–2699 (2011). https://doi.org/10.1039/C0EE00699H
S.A. Alsherari, F. Janene, A. Moulahi, H. Shili, I. Alnhas, I. Mjejri, Vanadium oxide nanocomposite as electrode materials for lithium–ion batteries with high specific discharge capacity and long cycling life. Ionics (2022). https://doi.org/10.1007/s11581-022-04811-0
Y. Chen, Diverse structural constructions of graphene-based composites for supercapacitors and metal-ion batteries. FlatChem 36, 100453 (2022). https://doi.org/10.1016/j.flatc.2022.100453
F. Sultanov, A. Mentbayeva, S. Kalybekkyzy, A. Zhaisanova, S.-T. Myung, Z. Bakenov, Advances of graphene-based aerogels and their modifications in lithium-sulfur batteries. Carbon 201, 679–702 (2023). https://doi.org/10.1016/j.carbon.2022.09.069
Z. Cao, Y. Wang, J. Guo, J. Jia, Z. Zhang, Y. Cui, Y. Yin, M. Yang, S. Yang, CoSe-catalyzed growth of graphene sheath to construct CNF@graphene-CoSe cable/sheath heterostructure for high-performance Lithium–sulfur batteries. Carbon 204, 102–111 (2023). https://doi.org/10.1016/j.carbon.2022.11.082
M. Zhang, J. Li, C. Sun, Z. Wang, Y. Li, D. Zhang, Durable flexible dual-layer and free-standing silicon/carbon composite anode for lithium-ion batteries. J. Alloys Compd. 932, 167687 (2023). https://doi.org/10.1016/j.jallcom.2022.167687
K. Zhang, J. Zhou, F. Yang, Y. Zhang, Y. Pan, B. Zheng, Y. Li, F. Yang, A stress-control charging method with multi-stage currents for silicon-based lithium-ion batteries: theoretical analysis and experimental validation. J. Energy Storage 56, 105985 (2022). https://doi.org/10.1016/j.est.2022.105985
N. Zhang, G. Guo, B. He, J. Zhu, J. Wu, J. Qiu, Synthesis and research of MnO2–NiO composite as lithium-ion battery anode using spent Zn–Mn batteries as manganese source. J. Alloy Compd. 838, 155578 (2020). https://doi.org/10.1016/j.jallcom.2020.155578
H. Zeng, D. Liu, Y. Zhang, K.A. See, Y.S. Jun, G. Wu, J.A. Gerbec, X. Ji, G.D. Stucky, Nanostructured Mn-doped V2O5 cathode material fabricated from layered vanadium jarosite. Chem. Mater. 27(21), 7331–7336 (2015). https://doi.org/10.1021/acs.chemmater.5b02840
X. Dai, M. Zhang, T. Li, X. Cui, Y. Shi, X. Zhu, P. Wangyang, D. Yang, J. Li. Effect of current on electrodeposited MnO2 as supercapacitor and lithium-ion battery electrode. Vacuum 195, 110692 (2022). https://doi.org/10.1016/j.vacuum.2021.110692
M.A. Hadi, M.M. Kadhim, I.I. K.Al-Azawi, S.A.H. .Abdullaha, A.M.S.K. Hachim, A.M. Rheima, Evaluation of the role perfect and defect boron nitride monolayer in calcium ion batteries as a anode. Comput. Theor. Chem. 1219, 113940 (2023). https://doi.org/10.1016/j.comptc.2022.113940
R. Bekarevich, Y. Pihosh, Y. Tanaka, K. Nishikawa, Y. Matsushita, T. Hiroto, H. Ohata, T. Ohno, T. Minegishi, M. Sugiyama, T. Kitamori, K. Mitsuishi, K. Takada, Conversion reaction in the binder-free anode for fast-charging Li-ion batteries based on WO3 nanorods. ACS Appl. Energy Mater. 3(7), 6700–6708 (2020). https://doi.org/10.1021/acsaem.0c00844
L. Fan, W. Zhang, S. Zhu, Y. Lu, Enhanced lithium storage capability in li-ion batteries using porous 3D Co3O4 nanofiber anodes. Indust. Eng. Chem. Res. 56(8), 2046–2053 (2017). https://doi.org/10.1021/acs.iecr.7b00222
Y. Cao, W. Sun, C. Guo, L. Zheng, M. Yao, Y. Wang, Rational construction of yolk–shell bimetal-modified quinonyl-rich covalent organic polymers with ultralong lithium-storage mechanism. ACS Nano 16(6), 9830–9842 (2022). https://doi.org/10.1021/acsnano.2c03857
H. Wang, W. Zou, C. Liu, Y. Sun, Y. Xu, W. Sun, Y. Wang, β-ketoenamine-linked covalent organic framework with Co intercalation: improved lithium-storage properties and mechanism for high-performance lithium-organic batteries. Batteries Supercaps (2023). https://doi.org/10.1002/batt.202200434
J.S. Cho, S.Y. Lee, J.-K. Lee, Y.C. Kang, Iron telluride-decorated reduced graphene oxide hybrid microspheres as anode materials with improved Na-ion storage properties. ACS Appl. Mater. Interfaces 8, 21343–21349 (2016). https://doi.org/10.1021/acsami.6b05758
J. Qu, Y.-X. Yin, Y.-Q. Wang, Y. Yan, Y.-G. Guo, W.-G. Song, Layer structured α-Fe2O3 nanodisk/reduced graphene oxide composites as high-performance anode materials for lithium-ion batteries. ACS Appl. Mater. Interfaces 5, 3932–3936 (2013). https://doi.org/10.1021/am400670d
Y. Meng, Y. Liu, J. He, X. Sun, A. Palmieri, Y. Gu, X. Zheng, Y. Dang, X. Huang, W. Mustain, S.L. Suib, Large scale synthesis of manganese oxide/reduced graphene oxide composites as anode materials for long cycle lithium ion batteries. ACS Appl. Energy Mater. 4(6), 5424–5433 (2021). https://doi.org/10.1021/acsaem.0c03061
W. Liu, X. Yuan, One-step solvothermal route to Sn4P3-reduced graphene oxide nanohybrids as cycle-stable anode materials for sodium-ion batteries. ACS Appl. Mater. Interfaces 13(10), 12016–12024 (2021). https://doi.org/10.1021/acsami.0c23052
H. Long, M. Zhang, Q. Wang, L. Xing, S. Wang, X. Xue, Plasma-treated Co3O4/graphene nanocomposite as high performance anode of lithium-ion battery. J. Alloys Compd. 701, 200–207 (2017). https://doi.org/10.1016/j.jallcom.2017.01.108
Q. Xie, Y. Zhang, Y. Zhu, W. Fu, X. Zhang, P. Zhao, S. Wu, Graphene enhanced anchoring of nanosized Co3O4 particles on carbon fiber cloth as freestanding anode for lithium-ion batteries with superior cycling stability. Electrochim. Acta 247, 125–131 (2017). https://doi.org/10.1016/j.electacta.2017.06.167
Q. Su, W. Yuan, L. Yao, Y. Wu, J. Zhang, G. Du, Microwave-assisted synthesis of Co3O4–graphene sheet-on-sheet nanocomposites and electrochemical performances for lithium ion batteries. Mater. Res. Bull. 72, 43–49 (2015). https://doi.org/10.1016/j.materresbull.2015.07.035
Funding
The authors have not disclosed any funding.
Author information
Authors and Affiliations
Contributions
SAA: Writing, original draft, Methodology, Data curation, Conceptualization.
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest. The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Ethics Approval
Research results are not misrepresented. The results are presented clearly, honestly and without fabrication, falsification or inappropriate data manipulation. The results are appropriately placed in the context of prior and existing research. No data, text, or theories by others are presented as if they were the author’s own. This is the author’s own original work, which has not been previously published elsewhere. The manuscript is not currently being considered for publication elsewhere. The manuscript reflects the author’s own research and analysis in a truthful and complete manner. The manuscript properly credits the meaningful contributions of co-authors. All authors have been personally and actively involved in substantial work leading to the manuscript and will take public responsibility for its content.
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Alsherari, S.A. Cobalt Oxide Modified Reduced Graphene Oxide Nanocomposite as Anode Materials for Lithium-Ion Batteries. J Inorg Organomet Polym 33, 3002–3010 (2023). https://doi.org/10.1007/s10904-023-02737-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10904-023-02737-2