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Effective Reduction of Cr(VI) and Organic Dyes Using Pd NPs/Fe3O4@nanocellulose as a Recoverable Catalyst in Aqueous Media

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Abstract

In this work, the extract of the roots plant of Chelidonium majus (greater celandine) was used to synthesize a magnetically reusable Pd nanoparticles supported by Fe3O4@nanocellulose through a green synthesis method. The Pd NPs/Fe3O4@nanocellulose catalyst as an impressive catalyst was prepared via reduction of Pd2+ ions using Chelidonium majus extract as bioreductant agent. The synthesized Pd NPs/Fe3O4@nanocellulose was characterized using vibrating sample magnetometer, field emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction analysis, energy-dispersive X-ray spectroscopy, fourier transform infrared spectroscopy and thermogravimetric analysis techniques. This heterogeneous catalyst represented excellent activity for full degradation of Cr(VI) in the presence of formic acid at 50 °C, and reduction of methylene blue, methyl orange, rhodamine B and congo red in the presence of NaBH4 as a reducing agent at room temperature. The synthesized catalyst was also reused four times for the reduction reactions without significant activity loss.

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Authors and Affiliations

  1. Department of Chemistry, Qaemshahr Branch, Islamic Azad University, Qaemshahr, Iran

    Elmira Kalantari, Mohammad A. Khalilzadeh & Daryoush Zareyee

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  1. Elmira Kalantari
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  2. Mohammad A. Khalilzadeh
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  3. Daryoush Zareyee
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Correspondence to Mohammad A. Khalilzadeh.

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Kalantari, E., Khalilzadeh, M.A. & Zareyee, D. Effective Reduction of Cr(VI) and Organic Dyes Using Pd NPs/Fe3O4@nanocellulose as a Recoverable Catalyst in Aqueous Media. J Inorg Organomet Polym 31, 319–330 (2021). https://doi.org/10.1007/s10904-020-01784-3

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