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Polyvinyl Alcohol/EuBa2Ca2Cu3O9−x Composites: Dielectric and Mechanical Properties

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Abstract

In the present work, the influence of EuBa2Ca2Cu3O9−x (coded as Eu-1223) ceramic additive on the mechanical and dielectric properties of poly(vinyl alcohol) (PVA) polymer were investigated for the first time. PVA/Eu-1223 polymer-ceramic thick film composites were prepared by solution casting method with different ceramic contents varying from 1 to 5%. The surface morphology of the samples were studied with scanning electron microscope revealed that adding higher concentration of Eu-1223 increases the roughness of the surface as well as the fragility of the PVA. Thermogravimetric analyses results revealed that the increasing Eu-1223 additive enhances slightly both the thermal and oxidative stability of the PVA. Furthermore, FTIR analysis of the composite displayed new FTIR transmittance peaks that can be attributed to the formation of a reaction between the PVA polymer chain and the ceramic additive. The mechanical properties in the context of stress–strain curves of the samples unveiled that increasing ceramic doping improves the Young’s modulus of PVA films. The impedance and dielectric properties of the samples recorded at room temperature indicated a space charge polarization regardless of the doping concentration. The complex electrical modulus analysis also pointed out a pure conduction process. The Nyquist and phase angle plots defined the grain and grain boundary properties along with the ideal capacitor ability of the composites. Especially, the lower ε′ and ε″ values were achieved for the 5% Eu-1223 additive level concentration. This work brings out that 5% Eu-1223 added PVA thick film may be suggested as a low dielectric loss dielectric material for supercapacitor applications.

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References

  1. H.M. Shiri, A. Ehsani, Bull. Chem. Soc. Jpn 89, 1201 (2016)

    Article  CAS  Google Scholar 

  2. C.-T. Huang, L.K. Shrestha, K. Ariga, S. Hsu, J. Mater. Chem. B 5, 8854 (2017)

    Article  CAS  Google Scholar 

  3. N. Follain, B. Alexandre, C. Chappey, L. Colasse, P. Médéric, S. Marais, Compos. Sci. Technol. 136, 18 (2016)

    Article  CAS  Google Scholar 

  4. T. Kitao, Y. Zhang, S. Kitagawa, B. Wang, T. Uemura, Chem. Soc. Rev. 46, 3108 (2017)

    Article  CAS  PubMed  Google Scholar 

  5. Y. Oaki, Bull. Chem. Soc. Jpn 90, 776 (2017)

    Article  CAS  Google Scholar 

  6. F. Sciortino, G. Rydzek, F. Grasset, M.L. Kahn, J.P. Hill, S. Chevance, F. Gauffre, K. Ariga, Phys. Chem. Chem. Phys. (PCCP) 20(24), 2761 (2018)

    Article  CAS  Google Scholar 

  7. M. Gon, K. Tanaka, Y. Chujo, Bull. Chem. Soc. Jpn. 90, 463 (2017)

    Article  CAS  Google Scholar 

  8. K.R. Reddy, K.-P. Lee, A.I. Gopalan, J. Nanosci. Nanotechnol. 7, 3117 (2007)

    Article  CAS  PubMed  Google Scholar 

  9. K.R. Reddy, W. Park, B.C. Sin, J. Noh, Y. Lee, J. Colloid Interface Sci. 335, 34 (2009)

    Article  CAS  PubMed  Google Scholar 

  10. K.R. Reddy, B.C. Sin, K.S. Ryu, J. Noh, Y. Lee, Synth. Met. 159, 1934 (2009)

    Article  CAS  Google Scholar 

  11. Y.R. Lee, S.C. Kim, H. Lee, H.M. Jeong, A.V. Raghu, K.R. Reddy, B.K. Kim, Macromol. Res. 19, 66 (2011)

    Article  CAS  Google Scholar 

  12. S.H. Choi, D.H. Kim, A.V. Raghu, K.R. Reddy, H.-I. Lee, K.S. Yoon, H.M. Jeong, B.K. Kim, J. Macromol. Sci. B 51, 197 (2012)

    Article  CAS  Google Scholar 

  13. S.J. Han, H.-I. Lee, H.M. Jeong, B.K. Kim, A.V. Raghu, K.R. Reddy, J. Macromol. Sci. B 53, 1193 (2014)

    Article  CAS  Google Scholar 

  14. D.R. Son, A.V. Raghu, K.R. Reddy, H.M. Jeong, J. Macromol. Sci. B 55, 1099 (2016)

    Article  CAS  Google Scholar 

  15. M.U. Khan, K.R. Reddy, T. Snguanwongchai, E. Haque, V.G. Gomes, Colloid. Polym. Sci. 294, 1599 (2016)

    Article  CAS  Google Scholar 

  16. K.R. Reddy, H.M. Jeong, Y. Lee, A.V. Raghu, J. Polym. Sci. A 48, 1477 (2010)

    Article  CAS  Google Scholar 

  17. S.K. Marka, M.A. Mohiddon, M.D. Prasad, V.V. Srikanth, Superlattices Microstruct. 83, 530 (2015)

    Article  CAS  Google Scholar 

  18. X. Zhao, Q. Zhang, D. Chen, P. Lu, Macromolecules 43(5), 2357 (2010)

    Article  CAS  Google Scholar 

  19. D. Chen, X. Wang, T. Liu, X. Wang, J. Li, ACS Appl. Mater. Interfaces 2(7), 2005 (2010)

    Article  CAS  Google Scholar 

  20. A. Das, S. Sinha, A. Mukherjee, A. Meikap, Mater. Chem. Phys. 167, 286 (2015)

    Article  CAS  Google Scholar 

  21. S. Mitra, O. Mondal, D.R. Saha, A. Datta, S. Banerjee, D. Chakravorty, J. Phys. Chem. C 115(29), 14285 (2011)

    Article  CAS  Google Scholar 

  22. N. Theophile, H.K. Jeong, Chem. Phys. Lett. 669, 125 (2017)

    Article  CAS  Google Scholar 

  23. Y.-S. Ye, M.-Y. Cheng, X.-L. Xie, J. Rick, Y.-J. Huang, F.-C. Chang, B.-J. Hwang, J. Power Sources 239, 424 (2013)

    Article  CAS  Google Scholar 

  24. A. Joshi, A. Bajaj, R. Singh, P. Alegaonkar, K. Balasubramanian, S. Datar, Nanotechnology 24(45), 455705 (2013)

    Article  CAS  PubMed  Google Scholar 

  25. S. Lim, B. Kang, D. Kwak, W.H. Lee, J.A. Lim, K. Cho, J. Phys. Chem. C 116(13), 7520 (2012)

    Article  CAS  Google Scholar 

  26. J. Wang, X. Wang, C. Xu, M. Zhang, X. Shang, Polym. Int. 60(5), 816 (2011)

    Article  CAS  Google Scholar 

  27. B. Kord, B. Malekian, H. Yousefi, A. Najafi, Maderas. Ciencia y tecnología 18(4), 743 (2016)

    Google Scholar 

  28. A. Islam, Z. Imran, T. Yasin, N. Gull, S.M. Khan, M. Shafiq, A. Sabir, M.A. Munawar, M.H. Raza, T. Jamil, Mater. Res. 18(6), 1256 (2015)

    Article  CAS  Google Scholar 

  29. J. Selvi, S. Mahalakshmi, V. Parthasarathy, J. Inorg. Organomet. Polym Mater. 27(6), 1918 (2017)

    Article  CAS  Google Scholar 

  30. S.F. Bdewi, O.G. Abdullah, B.K. Aziz, A.A. Mutar, J. Inorg. Organomet. Polym Mater. 26(2), 326 (2016)

    Article  CAS  Google Scholar 

  31. X. Liu, Q. Chen, L. Lv, X. Feng, X. Meng, Catal. Commun. 58, 30 (2015)

    Article  CAS  Google Scholar 

  32. M. Hatami, M. Ahmadipour, S. Asghari, J. Inorg. Organomet. Polym. Mater. 27(4), 1072 (2017)

    Article  CAS  Google Scholar 

  33. P.B. Bhargav, B. Sarada, A. Sharma, V. Rao, J. Macromol. Sci. A 47(2), 131 (2009)

    Article  CAS  Google Scholar 

  34. M. Makled, E. Sheha, T. Shanap, M. El-Mansy, J. Adv. Res. 4, 531 (2013)

    Article  CAS  PubMed  Google Scholar 

  35. M. Hema, S. Selvasekarapandian, D. Arunkumar, A. Sakunthala, H. Nithya, J. Non-Cryst. Solids 355, 84 (2009)

    Article  CAS  Google Scholar 

  36. D. Ray, A. Himanshu, T. Sinha, Indian J. Pure Appl. Phys. 43, 787 (2005)

    CAS  Google Scholar 

  37. K. Hemalatha, G. Sriprakash, M. Ambika Prasad, R. Damle, K. Rukmani, J. App. Phys. 118, 154103 (2015)

    Article  CAS  Google Scholar 

  38. S. More, R. Dhokne, S. Moharil, Mater. Res. Express 4, 055302 (2017)

    Article  CAS  Google Scholar 

  39. R. Sengwa, S. Choudhary, Express Polym. Lett. 4(9), 559 (2010)

    Article  CAS  Google Scholar 

  40. C.-C. Yang, Y.-J. Lee, ECS Trans. 13, 1 (2008)

    Article  Google Scholar 

  41. Y. Zhu, S. Xia, G. Liu, W. Jin, J. Membr. Sci. 349, 341 (2010)

    Article  CAS  Google Scholar 

  42. M. Pietrzyńska, M. Czerwiński, A. Voelkel, Eur. J. Pharm. Sci. 105, 195 (2017)

    Article  CAS  PubMed  Google Scholar 

  43. T. Badapanda, V. Senthil, S. Anwar, L. Cavalcante, N. Batista, E. Longo, Curr. Appl. Phys. 13, 1490 (2013)

    Article  Google Scholar 

  44. S.K. Pasha, K. Deshmukh, M.B. Ahamed, K. Chidambaram, M. Mohanapriya, N. Raj, Adv. Polym. Technol. 36(3), 352 (2015)

    Article  CAS  Google Scholar 

  45. Z.G. Özdemir, M. Kılıç, Y. Karabul, B.S. Mısırlıoğlu, ÖA. Çataltepe, O. İçelli, Mater. Sci. Semicond. Process. 63, 196 (2017)

    Article  CAS  Google Scholar 

  46. R.H. Perry’s, C. Chilton, Chemical Engineers’ Handbook, 5th edn. (McGraw-Hill, New York, 1984)

    Google Scholar 

  47. J. Gao, H. Yin, A. Wang, T. Jiang, Powder Technol. 237, 537 (2013)

    Article  CAS  Google Scholar 

  48. N. Bhat, M. Nate, M. Kurup, V. Bambole, S. Sabharwal, Nucl. Instrum. Methods Phys. Res. Sect. B 237, 585 (2005)

    Article  CAS  Google Scholar 

  49. J. Lee, T. Isobe, M. Senna, J. Colloid Interface Sci. 177, 490 (1996)

    Article  CAS  Google Scholar 

  50. P.R. Kumar, K. Janardhana, K. Balakrishna, T. Sheela, Procedia Eng. 141, 83 (2016)

    Article  CAS  Google Scholar 

  51. I. Elashmawi, N. Hakeem, M.S. Selim, Mater. Chem. Phys. 115, 132 (2009)

    Article  CAS  Google Scholar 

  52. I. Omkaram, R.S. Chakradhar, J.L. Rao, Physica B 388, 318 (2007)

    Article  CAS  Google Scholar 

  53. N.-H. Li, S.-G. Sun, J. Electroanal. Chem. 436, 65 (1997)

    Article  CAS  Google Scholar 

  54. S. Nasrazadani, E. Eureste, Application of FTIR for quantitative Lime Analysis, Citeseer, University of North Texas, Report Number 5-9028-01-1, 2008

  55. F.B. Reig, J.G. Adelantado, M.M. Moreno, Talanta 58, 811 (2002)

    Article  CAS  PubMed  Google Scholar 

  56. R. Gillard, H. Silver, J. Wood, Spectrochim. Acta 20, 63 (1964)

    Article  CAS  Google Scholar 

  57. K. Nakamoto, Infared Spectra of Inorganic and Coordination Compounds, 1st edn. (Wiley, New York, 1963)

    Google Scholar 

  58. K. Mevada, V. Patel, K. Patel, Arch. Phy. Res. 3, 258 (2012)

    CAS  Google Scholar 

  59. M. Trivedi, R.M. Tallapragada, A. Branton, D. Trivedi, O. Latiyal, S. Jana, J. Lasers Opt. Photonics 2(2), 1000122 (2015)

    Google Scholar 

  60. S.S. Acharyya, S. Ghosh, R. Bal, Green Chem. 17, 3490 (2015)

    Article  CAS  Google Scholar 

  61. J. Ahmad, K. Deshmukh, M.B. Hägg, Int. J. Polym. Anal. Charact. 18, 287 (2013)

    Article  CAS  Google Scholar 

  62. L.W. Chan, J.S. Hao, P.W.S. Heng, Chem. Pharm. Bull. 47, 1412 (1999)

    Article  CAS  Google Scholar 

  63. K.-J. Lin, S.-C. Lee, K.-F. Lin, J. Polym. Res. 21, 611 (2014)

    Article  CAS  Google Scholar 

  64. H. Liu, P. Bandyopadhyay, N.H. Kim, B. Moon, J.H. Lee, Polym. Test. 50, 49 (2016)

    Article  CAS  Google Scholar 

  65. N. Rithin Kumar, V. Crasta, R.F. Bhajantri, B. Praveen, J. Polym. 2014, 846140 (2014)

    Google Scholar 

  66. H. Rahmouni, M. Smari, B. Cherif, E. Dhahri, K. Khirouni, Dalton Trans. 44, 10457 (2015)

    Article  CAS  PubMed  Google Scholar 

  67. B. Kim, W. Cho, W. Lee, S. Kim, R. Jalili, S. Park, G.G. Wallace, K. Yu, S.-J. Chang, Synth. Met. 193, 110 (2014)

    Article  CAS  Google Scholar 

  68. C. Liu, M. Liu, F. Li, H. Cheng, Appl. Phys. Lett. 92(14), 143108 (2008)

    Article  CAS  Google Scholar 

  69. Z.G. Özdemir, N.Y. Canli, B. Senkal, Y. Gürsel, M. Okutan, J. Mol. Liq. 211, 442 (2015)

    Article  CAS  Google Scholar 

  70. L. Wang, H. Ji, S. Wang, L. Kong, X. Jiang, G. Yang, Nanoscale 5, 3793 (2013)

    Article  CAS  PubMed  Google Scholar 

  71. M.H. Suhail, M. Ghazi, M. Al-hamdany, Int. J. Emerg. Res. Manag.Technol. 5(6), 24 (2016)

    Google Scholar 

  72. N. Adam, A.L. Uğur, A. Altındal, A. Erdoğmuş, Polyhedron 68, 32 (2014)

    Article  CAS  Google Scholar 

  73. S. More, R. Dhokne, S. Moharil, Polym. Bull. 75, 909 (2018)

    Article  CAS  Google Scholar 

  74. A.K. Roy, K. Prasad, A. Prasad, Process. Appl. Ceram. 7(2), 81 (2013)

    Article  CAS  Google Scholar 

  75. C.V.S. Reddy, X. Han, Q.-Y. Zhu, L.-Q. Mai, W. Chen, Microelectron. Eng. 83(2), 281 (2006)

    Article  CAS  Google Scholar 

  76. T. Prakash, K.P. Prasad, R. Kavitha, S. Ramasamy, B. Murty, J. Appl. Phys. 102(10), 104104 (2007)

    Article  CAS  Google Scholar 

  77. J. Liu, C.-G. Duan, W.-G. Yin, W.-N. Mei, R.W. Smith, J.R. Hardy, J. Chem. Phys. 119(5), 2812 (2003)

    Article  CAS  Google Scholar 

  78. C.A. Angell, Chem. Rev. 90(3), 523 (1990)

    Article  CAS  Google Scholar 

  79. R. Gerhardt, J. Phys. Chem. Solids 55(12), 1491 (1994)

    Article  CAS  Google Scholar 

  80. I. Hodge, M. Ingram, A. West, J. Electroanal. Chem. Interfacial Electrochem. 74(2), 125 (1976)

    Article  CAS  Google Scholar 

  81. S.G. Rathod, R. Bhajantri, V. Ravindrachary, T. Sheela, P. Pujari, J. Naik, B. Poojary, J. Polym. Res. 22, 6 (2015)

    Article  CAS  Google Scholar 

  82. S. Elliott, Adv. Phys. 36(2), 135 (1987)

    Article  CAS  Google Scholar 

  83. A. Ghosh, Phys. Rev. B 41(3), 1479 (1990)

    Article  CAS  Google Scholar 

  84. T. Tiwari, N. Srivastava, P. Srivastava, Int. J. Electrochem. 2013, 1 (2013)

    Article  CAS  Google Scholar 

  85. P. Lunkenheimer, A. Loidl, Phys. Rev. Lett. 91, 207601 (2003)

    Article  CAS  PubMed  Google Scholar 

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Acknowledgements

This research was supported by Yildiz Technical University Scientific Research Projects Coordination Department with the Project Number of 2014-01-01-GEP04. The authors also would like to thank Assoc. Prof. Dr. Dolunay Şakar Daşdan for her kind efforts during the FTIR measurements.

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  1. Department of Physics, Faculty of Arts and Sciences, Yildiz Technical University, Davutpasa, Esenler, 34220, Istanbul, Turkey

    B. Süngü Mısırlıoğlu, Z. Güven Özdemir, B. Aksakal & C. Denktaş

  2. Department of Chemical Engineering, Faculty of Chemical and Metallurgical Engineering, Yildiz Technical University, Davutpasa, Esenler, 34220, Istanbul, Turkey

    Y. Salt & B. Tırnakçı

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  1. B. Süngü Mısırlıoğlu
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Mısırlıoğlu, B.S., Özdemir, Z.G., Aksakal, B. et al. Polyvinyl Alcohol/EuBa2Ca2Cu3O9−x Composites: Dielectric and Mechanical Properties. J Inorg Organomet Polym 28, 1968–1979 (2018). https://doi.org/10.1007/s10904-018-0877-9

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