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Poly(vinylferrocene)/Cellulose Acetate Fibers: A New Approach for In-Situ Monitoring Process Through QCM and Electrospinning Studies

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Abstract

A poly(vinylferrocene) (PVFc)/cellulose acetate (CA) fibers were obtained using an electrospinning method. The electrospinning process was controlled in situ with a quartz crystal microbalance (QCM) system. Fiber formation was observed through adjusting PVFc concentration. Morphological characteristics depending on the changes of atomic % ratio value of PVFc/CA electrospun fibers was investigated by scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy analysis. Electrochemical behavior of PVFc/CA electrospun fibers was investigated by using cyclic voltammetry measurements based on the Fc+/Fc redox couple. The results indicated that PVFc deployed in/on the CA fibers and aggregated arbitrarily on the QCM electrode. The new PVFc/CA electrospun fibers were used for anion sensing.

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Correspondence to Aysegul Uygun Oksuz.

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Maslakci, N.N., Kiristi, M., Kuralay, F. et al. Poly(vinylferrocene)/Cellulose Acetate Fibers: A New Approach for In-Situ Monitoring Process Through QCM and Electrospinning Studies. J Inorg Organomet Polym 25, 544–550 (2015). https://doi.org/10.1007/s10904-014-0114-0

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  • DOI: https://doi.org/10.1007/s10904-014-0114-0

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