Abstract
A chalcone-based Schiff base (5), capable of detecting iron (III) in partially aqueous media, has been designed, then synthesized by the condensation of 3-formyl-2-hydroxyquinoline and acetophenone. To determine iron (III) ion, a simple spectrofluorimetric method was developed by using the synthesized Schiff base. The developed method was validated by analyzing the certified reference material (CRM-SA-C Sandy Soil C). During the process of the determination of iron in food samples, satisfactory accuracy was obtained for spinach and rocket. Nitric acid and hydrogen fluoride were used for the digestion of the certified reference material whereas only nitric acid was used for food samples, in a closed microwave system. Measurements were carried out by using the modified standard addition method. The standard addition graph was linear until 5.0 mg/L. in determination of iron (III). Detection and quantification limits were 0.06 and 0.20 mg/L., respectively. The presented method is simple, time-saving, cost-effective and suitable for determination of iron content of soil and foods.
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Sigel A, Sigel H, Sigel RKO (eds) (2006) Neurodegenerative diseases and metal ions: metal ions in life sciences. Wiley, London
Abbaspour N, Hurrell R, Kelishad R (2014) Review on iron and its importance for human health. J Res Med Sci 19:164–174
Aggett PJ (2012) Iron. In: Erdman JW, Macdonald IA, Zeisel SH (eds) Present knowledge in nutrition, 10th edn. Wiley-Blackwell, Washington, pp. 506–520
Murray-Kolbe LE, Beard J (2010) Iron. In: Coates PM, Betz JM, Blackman MR, et al. (eds) Encyclopedia of Dietary Supplements, 2nd edn. London and New York, pp 432–438
Ghaedi M, Niknam K, Shokrollahia A, Niknam E (2009) Determination of Cu, Fe, Pb and Zn by flame-AAS after preconcentration using sodium dodecyl sulfate coated alumina modified with complexing agent. J Chin Chem Soc 56:150–157
Dos Santos LMG, Araujo RGO, Jacob SDC, Vale MGR, Martens A, Martens IBG, Becker-Ross H (2009) Simultaneous determination of Cd and Fe in beans and soil of different regions of Brazil using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sampling. J Agric Food Chem 57:10089–10094
Da-Col JA, Domene SMA, Pereira-Filho ER (2009) Fast determination of Cd, Fe, Pb, and Zn in food using AAS. Food Anal Methods 2:110–115
Jorhem L, Engman J (2000) Determination of lead, cadmium, zinc, copper, and iron in foods by atomic absorption spectrometry after microwave digestion: NMKL collaborative study. J AOAC Int 83:1189–1203
Baezzat MR, Maleki H, Moghadamhosseyni E, Tabandeh M (2014) Determination of trace amounts of zinc, iron and copper by flame atomic absorption after their preconcentration using sodium dodecyl sulfate (sds) coated alumina nanoparticles modified with 3-mercapto-d-valin from environmental samples. Am J Anal Chem 5:1228–1238
Khayatian G, Hassanpoor S, Nasiri F, Zolali A (2012) Preconcentration, determination and speciation of iron by solid-phase extraction using dimethyl (E)-2-[(Z)-1-(acetyl)-2-hydroxy-1-Propenyl]-2-Butenedioate. Quim Nov. 35:535–540
Roldan PS, Alcântara IL, Rocha JC, Padilha CCF, Padilha PM (2004) Determination of copper, iron, nickel and zinc in fuel kerosene by FAAS after adsorption and pre-concentration on 2-aminothiazole-modified silica gel. Ecl Quím São Paulo 29:33–40
Kim SD, Lee DH, Kim JS (2008) Fluorescence spectrometric determination of aluminum(iii) ion in water using 4-chloro-2-phenyliminomethylphenol. Bull Kor Chem Soc 29:245–248
Silvia C, Lopez P, Raimundo IM Jr, Moreno-Bondi MC, Orellana G (2010) Simultaneous determination of copper, mercury and zinc in water with a tailored fluorescent bipyridine ligand entrapped in silica sol-gel. Anal Bioanal Chem 398:3127–3138
Al-Kindy SMZ, Al-Hinai KH, Suliman FEO, Al-Lawati HJ, Pillay A (2011) Development of a selective fluorimetric technique for rapid trace determination of zinc using 3-hydroxyflavone. Arab J Chem 4:147–152
Zhou Q, Liu W, Chang L, Chen F (2012) Spectral study of the interaction between 2-pyridinecarbaldehyde-p-phenyldihydrazone and ferric iron and its analytical application. Spect Chim Act Part A: Mol Biomol Spect 92:78–83
Ragos CG, Demertzis MA, Issopoulos PB (1998) A high-sensitive spectrofluorimetric method for the determination of micromolar concentrations of iron(iii) in bovine liver with 4-hydroxyquinoline. Il Farmaco 53:611–616
Shamsipur M, Sadeghi M, Garau A, Lippolis V (2013) An efficient and selective fluorescent chemical sensor based on 5-(8-hydroxy-2-quinolinylmethyl)-2,8-ditiha-5-aza-2,6-pyridinophane as a new fluoroionophore for determination of iron(iii) ions. A novel probe for iron speciation. Anal Chim Acta 761:169–177
Dutta M, Das D (2012) Recent developments in fluorescent sensors for trace-level determination of toxic-metal ions. Trends Anal Chem 32:113–132
Liu SR, Wu SP (2011) An NBD-based sensitive and selective fluorescent sensor for copper(ii) ion. J Fluoresc 21:1599–1605
Antony EJ, Raj M, Paulpandi RQ, Paulraj MS, Enoch ISMV (2015) A highly selective fluorescent sensor for Pb2+ based on a modified β-cyclodextrin. J Fluoresc 25:1031–1036
Yue Y, Zhang Y, Song W, Zhang X, Liu J, Zhuo K (2014) Manganase dioxide-mediated oxidative coupling of 1,3-dicarbonyl compounds with α,β-unsaturated ketones: direct access to 3,4-dicarbonyl substituted furans. Adv Synth Catal 356:2459–2464
Yue Y, Sun Y, Zhao S, Yan X, Li R, Shi Y, Zhuo K, Liu J (2016) Chloroacetate promotes and participates in the oxidative annulation of pyridines/isoquinoline by using oxygen and oxidant. An Asian Journal. doi:10.1002/asia.201601233
Başoğlu A, Tosun G, Ocak M, Alp H, Yaylı N, Ocak Ü (2015) A simple and time-saving method for iron determination based on fluorescence quenching of an azaflavanon-3-ol compound. J Agric Food Chem 63:2654–2659
Çağlar Y, Saka ET, Alp H, Kantekin H, Ocak U, Ocak M (2016) A simple spectrofluorimetric method based on quenching of a nickel(II)-Phthalocyanine complex to determine iron (III). J Fluoresc 26:1381–1389
Mohsin HF (2013) Synthesis of some new pyrimidines from chalcone containing an imin group. Asian J Research Chem 6:849–854
Kudale SD, Deodhar MN (2012) Synthesis and evaluation of some coumarin containing potential antimicrobial agents. 9:2493–2500
Kalanithi M, Rajarajan M, Tharmaraj P, Sheela CD (2012) Spectral, biological screening of metal chelates of chalcone based Schiff bases of N-(3-aminopropyl) imidazole. Spectrochim Acta A 87:155–162
Bourson J, Valeur B (1989) Ion-responsive fluorescent compounds. 2. Cation-steered intramolecular charge transfer in a crowned merocyanine. J Phys Chem 93:3871–3876
Guilbault GG (1990) Practical Fluorescence, 2nd edn. Marcel Dekker, New York
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Özbek, N., Alp, H., Çelik, G. et al. A Simple Spectrofluorimetric Method for Iron Determination with a Chalcone-Based Schiff Base. J Fluoresc 27, 635–641 (2017). https://doi.org/10.1007/s10895-016-1992-z
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DOI: https://doi.org/10.1007/s10895-016-1992-z