Skip to main content
SpringerLink
Log in

Synthesis, Structure and Characterization of Two Borates Templated by Organic Super Base

  • Original Paper
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

Two templated borates [HDBU][B5O6(OH)4] and [HDBN][B5O6(OH)4] (denoted 1 and 2, DBU=1,8-diazabicyclo[5.4.0]undec-7-ene and DBN=1,5-diazabicyclo[4.3.0]non-5-ene) have been synthesized by solvent evaporation in this work. The crystal structure of 1 is reported and consists of superbase cations and [B5O6(OH)4]− anions. The [B5O6(OH)4]− anions are connected together by H-bonds to form a supramolecular framework in which the [HDBU]+ cations are located. Crystal data for 1 are as following: Triclinic, P-1(NO.2), a = 9.5380(7) Å, b = 9.9420(8) Å, c = 10.5633(7) Å, α = 66.697(3)°, β = 66.457(3)°, γ = 87.720(4)°, Z = 2. Additionally, structures of the obtained templated borates have been further confirmed by Elemental Analysis, FTIR, PXRD, TG and DSC techniques.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. J. D. Grice, P. C. Burns, and F. C. Hawthorne (1999). Can. Mineral. 37, 731–762.

    CAS  Google Scholar 

  2. P. Becker (1998). Adv. Mater. 10, 979–992.

    Article  CAS  Google Scholar 

  3. P. Dekker, J. M. Dawes, J. A. Piper, Y. Liu, and J. Wang (2001). Opt. Commun. 195, 431–436.

    Article  CAS  Google Scholar 

  4. E.-R. Wang, J.-H. Huang, Yu Su-Juan, Y.-Z. Lan, J.-W. Cheng, and G.-Y. Yang (2017). Inorg. Chem. 56, 6780–6783.

    Article  CAS  Google Scholar 

  5. G. Shi, Y. Wang, F. Zhang, B. Zhang, Z. Yang, X. Hou, S. Pan, and K. R. Poeppelmeier (2017). J. Am. Chem. Soc. 139, 10645–10648.

    Article  CAS  Google Scholar 

  6. F. Lin, Y. Dong, J. Peng, L. Wang, and W. Li (2016). Phase Transit. 89, 558–567.

    Article  CAS  Google Scholar 

  7. W. Chao, L. Li, J. Song, G. Yang, M. G. Humphrey, and C. Zhang (2017). Inorg. Chem. 56, 1340–1348.

    Article  Google Scholar 

  8. D. A. Keszler (1999). Curr. Opin. Solid State Mater. Sci. 4, 155–162.

    Article  CAS  Google Scholar 

  9. E. Kaewnuam, N. Wantana, H. J. Kim, and J. Kaewkhao (2017). J. Non-Cryst. Solids 464, 96–103.

    Article  CAS  Google Scholar 

  10. A. M. Smith, L. Trotochaud, M. S. Burke, and S. W. Boettcher (2015). Chem. Commun. 51, 5261–5263.

    Article  CAS  Google Scholar 

  11. C. Huang, J.-H. Zhang, C.-L. Hu, X. Xu, F. Kong, and J.-G. Mao (2014). Inorg. Chem. 53, 3847–3853.

    Article  CAS  Google Scholar 

  12. D. M. Schubert, M. Z. Visi, S. Khan, and C. B. Knobler (2008). Inorg. Chem. 47, 4740–4745.

    Article  CAS  Google Scholar 

  13. L.-Z. Wu, L. Cheng, J.-N. Shen, and G.-Y. Yang (2013). CrystEngComm 15, 4483–4488.

    Article  CAS  Google Scholar 

  14. M. A. Beckett, S. J. Coles, P. N. Horton, and C. L. Jones (2017). Eur. J. Inorg. Chem. 38–39, 4510–4518.

    Article  Google Scholar 

  15. Y. Yang, S. Pan, J. Han, X. Hou, Z. Zhou, W. Zhao, Z. Chen, and M. Zhang (2011). Cryst. Growth Des. 11, 3912–3916.

    Article  CAS  Google Scholar 

  16. C.-Y. Pan, L.-J. Zhong, L. Jing, D.-G. Li, F.-H. Zhao, and H.-M. Yang (2014). Z. Anorg. Allg. Chem. 640, 352–356.

    Article  CAS  Google Scholar 

  17. W. Yao, X. Jiang, H. Huang, X. Tao, X. Wang, Z. Lin, and C. Chen (2013). Inorg. Chem. 52, 8291–8293.

    Article  CAS  Google Scholar 

  18. C.-Y. Pan, G.-M. Wang, S.-T. Zheng, and G.-Y. Yang (2007). Z. Anorg. Allg. Chem. 633, 336–340.

    Article  CAS  Google Scholar 

  19. M. A. Beckett, P. N. Horton, S. J. Coles, and D. W. Martin (2011). Inorg. Chem. 50, 12215–12218.

    Article  CAS  Google Scholar 

  20. M. A. Beckett, P. N. Horton, M. B. Hursthouse, J. L. Timmis, and K. S. Varma (2012). Dalton Trans. 41, 4396–4403.

    Article  CAS  Google Scholar 

  21. C.-Y. Pan, G.-M. Wang, S.-T. Zheng, and G.-Y. Yang (2007). J. Solid State Chem. 180, 1553–1558.

    Article  CAS  Google Scholar 

  22. Y. Yang, S. Pan, X. Hou, X. Dong, S. Xin, Z. Yang, M. Zhang, W. Zhao, and Z. Chen (2012). CrystEngComm 14, 6720–6725.

    Article  CAS  Google Scholar 

  23. Z. Wang, M. Zhang, S. Pan, Y. Wang, H. Zhang, and Z. Chen (2014). Dalton Trans. 43, 2828–2834.

    Article  CAS  Google Scholar 

  24. C.-Y. Pan, L.-J. Zhong, F.-H. Zhao, Y.-Z. Luo, and D.-G. Li (2015). Inorg. Chem. 54, 403–405.

    Article  CAS  Google Scholar 

  25. S. Yang, G. Li, S. Tian, F. Liao, M. Xiong, and J. Lin (2007). J. Solid State Chem. 180, 2225–2232.

    Article  CAS  Google Scholar 

  26. R. Cong, T. Yang, H. Li, F. Liao, Y. Wang, and J. Lin (2010). Eur. J. Inorg. Chem. 10, 1703–1709.

    Article  Google Scholar 

  27. C.-A. Chen, Q. Wei, B.-F. Yang, and G.-Y. Yang (2017). J. Cluster Sci. 28, 2157–2165.

    Article  CAS  Google Scholar 

  28. M.-S. Wang, G.-C. Guo, W.-T. Chen, X. Gang, W.-W. Zhou, K.-J. Wu, and J.-S. Huang (2007). Angew. Chem. Int. Ed. 46, 3909–3911.

    Article  CAS  Google Scholar 

  29. S. Wang, E. V. Alekseev, J. Diwu, H. M. Miller, A. G. Oliver, G. Liu, W. Depmeier, and T. E. Albrecht-Schmitt (2011). Chem. Mater. 23, 2931–2939.

    Article  CAS  Google Scholar 

  30. M.-C. Liu, P. Zhou, H.-G. Yao, S.-H. Ji, R.-C. Zhang, M. Ji, and Y.-L. An (2009). Eur. J. Inorg. Chem. 31, 4622–4624.

    Article  Google Scholar 

  31. H.-Q. Wu, P. Ju, H. He, B.-F. Yang, and G.-Y. Yang (2013). Inorg. Chem. 52, 10566–10570.

    Article  CAS  Google Scholar 

  32. P. Zhao, Z.-E. Lin, Q. Wei, L. Cheng, and G.-Y. Yang (2014). Chem. Commun. 50, 3592–3594.

    Article  CAS  Google Scholar 

  33. S.-J. Yu, X.-Y. Gu, T.-T. Deng, J.-H. Huang, J.-W. Cheng, and G.-Y. Yang (2017). Inorg. Chem. 56, 12695–12698.

    Article  CAS  Google Scholar 

  34. Q. Wei, Y.-J. Zhang, Y. Song, G.-Y. Yang, and X.-D. Zou (2016). Dalton Trans. 45, 13937–13943.

    Article  CAS  Google Scholar 

  35. C.-Y. Pan, D.-Y. Wu, Y.-Z. Luo, F.-H. Zhao, and H.-M. Yang (2016). J. Cluster Sci. 27, 85–93.

    Article  CAS  Google Scholar 

  36. C.-Y. Pan, L.-J. Zhong, F.-H. Zhao, H.-M. Yang, and J. Zhou (2015). Chem. Commun. 51, 753–756.

    Article  CAS  Google Scholar 

  37. K. Zhou, Y.-Z. Luo, Z.-Q. Liu, C.-Y. Pan, J. Li, Y.-Y. Zheng, and F.-H. Zhao (2017). Inorg. Chim. Acta 465, 26–30.

    Article  CAS  Google Scholar 

  38. C.-Y. Pan, Y.-Z. Luo, D.-G. Li, F.-H. Zha, L. Jing, and C. Rong (2015). J. Cluster Sci. 26, 1633–1644.

    Article  CAS  Google Scholar 

  39. L.-Z. Wu, L. Cheng, and G.-Y. Yang (2013). J. Cluster Sci. 24, 811–820.

    Article  CAS  Google Scholar 

  40. R. Pan, B.-B. Yang, G.-M. Wang, and G.-Y. Yang (2017). Inorg. Chem. Commun. 76, 26–29.

    Article  CAS  Google Scholar 

  41. M. A. Beckett (2016). Coord. Chem. Rev. 323, 2–14.

    Article  CAS  Google Scholar 

  42. L. Wei, B.-F. Yang, H. He, and G.-Y. Yang (2014). J. Cluster Sci. 25, 617–626.

    Article  CAS  Google Scholar 

  43. Y. Liu, H. He, B.-F. Yang, Q. Zhang, and G.-Y. Yang (2015). J. Cluster Sci. 26, 1537–1545.

    Article  CAS  Google Scholar 

  44. T.-J. Zhang, R. Pan, H. He, B.-F. Yang, and G.-Y. Yang (2016). J. Cluster Sci. 27, 625–633.

    Article  CAS  Google Scholar 

  45. S.-Y. Li and Z.-H. Liu (2016). J. Therm. Anal. Calorim. 126, 913–918.

    Article  CAS  Google Scholar 

  46. M. A. Beckett, S. J. Coles, R. A. Davies, P. N. Horton, and C. L. Jones (2015). Dalton Trans. 44, 7032–7040.

    Article  CAS  Google Scholar 

  47. D. J. Heldebrant, P. G. Jessop, C. A. Thomas, C. A. Eckert, and C. L. Liotta (2005). J. Org. Chem. 70, 5335–5338.

    Article  CAS  Google Scholar 

  48. W. Zhang and M. Shi (2006). Org. Biomol. Chem. 4, 1671–1674.

    Article  CAS  Google Scholar 

  49. J. M. Khurana, B. Nand, and P. Saluja (2010). Tetrahedron 66, 5637–5641.

    Article  CAS  Google Scholar 

  50. M. A. Beckett, P. N. Horton, S. J. Coles, D. A. Kose, and A. Kreuziger (2012). Polyhedron 38, 157–161.

    Article  CAS  Google Scholar 

  51. R. Watari, Y. Kayaki, S. Hirano, N. Matsumoto, and T. Ikariya (2015). Adv. Synth. Catal. 357, 1369–1373.

    Article  CAS  Google Scholar 

  52. J. Zheng, J.-H. Lin, X.-Y. Deng, and J.-C. Xiao (2015). Org. Lett. 17, 532–535.

    Article  CAS  Google Scholar 

  53. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, and H. Puschmann (2009). J. Appl. Cryst. 42, 339–341.

    Article  CAS  Google Scholar 

  54. G. M. Sheldrick (2015). Acta Cryst. A71, 3–8.

    Google Scholar 

  55. G. M. Sheldrick (2015). Acta Cryst. C71, 3–8.

    Google Scholar 

  56. J. Li, S. Xia, and S. Gao (1995). Spectrochim. Acta A 51, 519–532.

    Article  Google Scholar 

  57. G. Xiong, G. Lan, H. Wang, and C. Huang (1993). J. Raman Spectrosc. 24, 785–789.

    Article  CAS  Google Scholar 

  58. M. A. Beckett, P. N. Horton, M. B. Hursthouse, D. A. Knoxa, and J. L. Timmis (2010). Dalton Trans. 39, 3944–3951.

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 21671044), Star of Science and Technology of Guangdong Pearl River (No. 201610010042), the Excellent Young Teacher Development Project of Universities in Guangdong Province (No. YQ2015054), and State Key Laboratory of Silicon Materials, Zhejiang University.

Author information

Authors and Affiliations

  1. School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006, Guangdong, China

    Jun-Xia Deng, Chun-Yang Pan, Yuan Liu, Jun Li & Feng-Hua Zhao

Authors
  1. Jun-Xia Deng
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Chun-Yang Pan
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yuan Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jun Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Feng-Hua Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Chun-Yang Pan.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 21 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Deng, JX., Pan, CY., Liu, Y. et al. Synthesis, Structure and Characterization of Two Borates Templated by Organic Super Base. J Clust Sci 29, 403–409 (2018). https://doi.org/10.1007/s10876-017-1327-5

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10876-017-1327-5

Keywords

Search

Navigation