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Two luminescent cadmium(II) coordination compounds based on tetrazole–carboxylates

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Abstract

Tetrazole–carboxylate ligands are excellent building blocks to construct novel coordination architectures. 5-Aminotetrazole-1-isopropionic acid (Hatzipa) and 3,3-di(1H-tetrazol-5-yl)pentanedioic acid (H4dtzpda) were prepared. And reactions of the two ligands with CdCl2·2.5H2O afforded [Cd(atzipa)2(H2O)(EtOH)] (1) and [Cd2(H2dtzpda)2(H2O)3]·3H2O (2), respectively. Compound 1 shows a two-dimensional layer structure, whereas compound 2 is a three-dimensional network composed of Cd2+ and octa-dentate H2dtzpda2− via the tetrazole-N and the carboxylate group in a μ1,1,3-COO mode. The luminescence properties of Hatzipa, H4dtzpda and the compounds were investigated at room temperature in the solid state.

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Acknowledgements

The authors acknowledge financial support from the Natural Science Foundation of Jiangsu Province (Grant No. BK2012210), the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (Grant No. 10KJB430001) and the Opening Fund of Jiangsu Key Laboratory of Advanced Functional Materials (Grant No·12KFJJ010).

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Authors and Affiliations

  1. School of Pharmacy, Guilin Medical University, Guilin, 541004, Guangxi, People’s Republic of China

    Xinyu Hao & Dengfeng Zou

  2. Jiangsu Laboratory of Advanced Functional Material, Department of Chemistry and Material Engineering, Changshu Institute of Technology, Changshu, 215500, Jiangsu, People’s Republic of China

    Xinyu Hao, Yan Li, Jing’ao Ren, Conghao Shi, Yuanhui Liu, Qiaoyun Li & Gaowen Yang

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  1. Xinyu Hao
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  2. Yan Li
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  3. Jing’ao Ren
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  5. Yuanhui Liu
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  7. Dengfeng Zou
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Corresponding authors

Correspondence to Yan Li, Dengfeng Zou or Gaowen Yang.

Electronic supplementary material

Appendix : Supplementary material

Appendix : Supplementary material

CCDC reference numbers 1864125, 1864126 contain the supplementary crystallographic data for compounds 1 and 2, respectively. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html or from the Cambridge Crystallographic Data Centre, 12UnionRoad, Cambridge CB21EZ, UK; fax:(+44) 1223-336-033; or e-mail: deposit@ ccdc.cam.ac.uk.

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Hao, X., Li, Y., Ren, J. et al. Two luminescent cadmium(II) coordination compounds based on tetrazole–carboxylates. J IRAN CHEM SOC 17, 2981–2986 (2020). https://doi.org/10.1007/s13738-020-01976-1

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  • DOI: https://doi.org/10.1007/s13738-020-01976-1

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