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Syntheses, Structures and Optical Band Gaps of Two Coordination Polymers with 2D → 3D Polythreaded and Interdigitated Structures

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Abstract

Two coordination polymers [Cu(phen)(L)0.5(H2O)] (1) and [Ni2(phen)2(L)(H2O)0.5]·0.5H2O (2), where phen = 1,10-phenanthroline and H4L = 5,5′-(ethane-1,2-diyl)-bis(oxy)diisophthalic acid, have been synthesized under hydrothermal conditions. In complex 1, the L anions and the phen ligands connect the Cu(II) ions to form a layer. The phen ligands act as arms and thread into the adjacent layer, forming a 2D → 3D polythreaded architecture. In complex 2, the L anions and the phen ligands link the Ni(II) ions to form a layer. Further, the adjacent layers interdigitate each other through intermolecular π − π interactions to generate a 2D → 3D interdigitated architecture. Their structures have been determined by single-crystal X-ray diffraction analyses and further characterized by infrared spectra (IR) and elemental analyses. The thermal properties and optical band gaps of complexes 1 and 2 have also been investigated.

Graphical Abstract

Two interesting 2D → 3D polythreaded and interdigitated coordination polymers based on the flexible 5,5′ -(ethane-1,2-diyl)-bis(oxy)diisophthalic acid have been successfully synthesized, where the thermal properties and optical band gaps of the complexes have also been investigated.

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Acknowledgments

We gratefully acknowledge the financial support from the National Science Foundation of China (21401063, 21403081 and 21202058), the Natural Science Foundation of Jiangsu Province (BK20140452, BK20140453 and BK2011408), the Opening Project of Key Laboratory for Chemistry of Low-Dimensional Materials of Jiangsu Province (JSKC13137).

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Authors and Affiliations

  1. Jiangsu Province Key Laboratory for Chemistry of Low-Dimensional Materials, Huaiyin Normal University, Huaian, 223300, People’s Republic of China

    Wei-Qiu Kan, Yu-He Kan, Hua-You Hu, Ai-Juan Liu, Ye-Qing Shen, Xiao-Dong Liu & Shi-Zheng Wen

  2. School of Physics and Electronic Electrical Engineering, Huaiyin Normal University, Huaian, 223300, People’s Republic of China

    Shi-Zheng Wen

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  1. Wei-Qiu Kan
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  2. Yu-He Kan
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Correspondence to Shi-Zheng Wen.

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Kan, WQ., Kan, YH., Hu, HY. et al. Syntheses, Structures and Optical Band Gaps of Two Coordination Polymers with 2D → 3D Polythreaded and Interdigitated Structures. J Chem Crystallogr 44, 527–533 (2014). https://doi.org/10.1007/s10870-014-0546-y

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  • DOI: https://doi.org/10.1007/s10870-014-0546-y

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