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Synthesis and Crystal Structure of Three Alkaline Earth Coordination Compounds Based on 1,2,5-Thiadiazole-3,4-Dicarboxylic Acid Ligand

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Abstract

1,2,5-thiadiazole-3,4-dicarboxylic acid (H2 tdzdc) ligand has been used to construct three coordination compounds [Mg(tdzdc)(H2O)4](1), [Ca(tdzdc)(H2O)2]n(2) and [Sr(tdzdc)(H2O)3]n(3) by the solvothermal reaction. Single-crystal structure analyses reveal a mononuclear coordination structure for compound 1 and two dimensional coordination structure both for compound 2 and 3. Furthermore, all of these three compounds comprise any amount of hydrogen bond interactions, which extends their crystal structure into three dimensional (3D) frameworks. Different crystal structure of compounds 1–3 reveals diversified coordination modes of H2 tdzdc ligand toward alkaline earth metal ions, depending mainly on the radius and the electron shell number of metal ions used.

Graphical Abstract

Based on 1,2,5-thiadiazole-3,4-dicarboxylic acid (H2 tdzdc) ligand, three new alkaline earth metal compound were synthesized with different structure.

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References

  1. Kitagawa S, Kitaura R, Noro S (2004) Angew Chem Int Ed 43:2334–2375

    Article  CAS  Google Scholar 

  2. Tian D, Chen Q, Li Y, Zhang YH, Chang Z, Bu XH (2014) Angew Chem Int Ed 53:837–841

    Article  CAS  Google Scholar 

  3. Wang ZL, Fang WH, Yang GY (2010) Chem Commun 46:8216–8218

    Article  CAS  Google Scholar 

  4. Liao PQ, Zhou DD, Zhu AX, Jiang L, Lin RB, Zhang JP, Chen XM (2012) J Am Chem Soc 134:17380–17383

    Article  CAS  Google Scholar 

  5. Li JR, Tao Y, Yu Q, Bu XH, Sakamoto H, Kitagawa S (2008) Chem Eur J 14:2771–2776

    Article  CAS  Google Scholar 

  6. Chen Q, Chang Z, Song WC, Song H, Song HB, Hu TL, Bu XH (2013) Angew Chem Int Ed 52:11550–11553

    Article  CAS  Google Scholar 

  7. Jin Z, Zhao H, Zhao XJ, Fang QR, Long JR, Zhu GS (2010) Chem Commun 46:8612–8614

    Article  CAS  Google Scholar 

  8. Xie YB, Yang H, Wang ZU, Liu YY, Zhou HC, Li JR (2014) Chem Commun 50:563–565

    Article  CAS  Google Scholar 

  9. Li JR, Yu JM, Lu WG, Sun LB, Sculley J, Balbuena PB, Zhou HC (2013) Nat Commun 4:1538. doi:10.1038/ncomms2552

    Article  Google Scholar 

  10. Hou C, Liu Q, Fan J, Zhao Y, Wang P, Sun WY (2012) Inorg Chem 51:8402–8408

    Article  CAS  Google Scholar 

  11. Wang J, Lin Z, Ou YC, Yang NL, Zhang YH, Tong ML (2007) Inorg Chem 47:190–199

    Article  Google Scholar 

  12. Liu YL, Kravtsov V, Walsh RD, Poddar P, Srikanthc H, Eddaoudi M (2004) Chem Commun 24:2806–2807

    Article  Google Scholar 

  13. Zou RQ, Sakurai H, Xu Q (2006) Angew Chem Int Ed 45:2542–2546

    Article  CAS  Google Scholar 

  14. Cheng AL, Liu N, Zhang JY, Gao EQ (2007) Inorg Chem 46:1034–1035

    Article  CAS  Google Scholar 

  15. Alkordi MH, Brant JA, Wojtas L, Kravtsov VC, Cairns AJ, Eddaoudi M (2009) J Am Chem Soc 131:17753–17755

    Article  CAS  Google Scholar 

  16. Zheng ZB, Wu RT, Li JK, Sun YF (2009) J Coord Chem 62:2324–2336

    Article  CAS  Google Scholar 

  17. Yue YF, Wang BW, Gao EQ, Fang CJ, He C, Yan CH (2007) Chem Commun 20:2034–2036

    Article  Google Scholar 

  18. Zhao TT, Jing XM, Wang J, Wang DM, Li GH, Huo QS, Liu YL (2012) Cryst Growth Des 12:5456–5461

    Article  CAS  Google Scholar 

  19. Tomura M, Yamashita Y (2010) Struct Chem 21:107–111

    Article  CAS  Google Scholar 

  20. Kundu T, Sahoo SC, Banerjee R (2012) Chem Commun 48:4998–5000

    Article  CAS  Google Scholar 

  21. Foo ML, Horike S, Inubushi Y, Kitagawa S (2012) Angew Chem Int Ed 51:6107–6111

    Article  CAS  Google Scholar 

  22. Zurawski A, Rybak JC, Meyer LV, Matthes PR, Stepanenko V, Dannenbauer N, Würthner F, Müller-Buschbaum K (2012) Dalton Trans 41:4067–4078

    Article  CAS  Google Scholar 

  23. Li JR, Yu Q, Tao Y, Bu XH et al (2007) Chem Commun 22:2290–2292

    Article  Google Scholar 

  24. Bruker AXS (1998) SAINT Software Reference Manual, Madison

  25. Sheldrick GM (1996) SADABS, Siemens Area Detector Absorption Corrected Software, University of Göttingen, Germany

  26. Sheldrick GM (1997) SHELXTL NT Version 5.1. Program for Solution and Refinement of Crystal Structures, University of Göttingen, Germany

Download references

Acknowledgments

This work was financially supported by MOE Innovation Team of China (IRT13022), the National Science Foundation of China (21371102), National Innovative Research Program for Undergraduates (201210055032, Henan Province Key Scientific Research Projects (122102210395), and Pingdingshan Key Scientific Research Projects (2013066).

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Authors and Affiliations

  1. College of Chemical and Materials Engineering, Henan University of Urban Construction, Pingdingshan, 367044, Henan, China

    Zhen-Xin Zhao & Bu-Wei Ma

  2. Key Laboratory Advanced Energy Materials Chemistry, Ministry of Education, Nankai University, Tianjin, 300071, China

    Zhen-Xin Zhao, Bo-Yu Zhou, Li-Fu Wang, Guo-Jian Ren & Ying-Hui Zhang

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  1. Zhen-Xin Zhao
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  2. Bu-Wei Ma
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  3. Bo-Yu Zhou
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  6. Ying-Hui Zhang
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Correspondence to Ying-Hui Zhang.

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Zhao, ZX., Ma, BW., Zhou, BY. et al. Synthesis and Crystal Structure of Three Alkaline Earth Coordination Compounds Based on 1,2,5-Thiadiazole-3,4-Dicarboxylic Acid Ligand. J Chem Crystallogr 44, 443–449 (2014). https://doi.org/10.1007/s10870-014-0535-1

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  • DOI: https://doi.org/10.1007/s10870-014-0535-1

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