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Investigations on synthesis, growth and physicochemical properties of organic nonlinear optical crystal: 2A3C2HP (C5H7N2+.C6H7O7−)

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Abstract

The centro-symmetric single-crystal 2A3C2HP bearing the IUPAC nomenclature of 2-aminopyridin-1-ium 3-carboxy-2-carboxymethyl-2-hydroxypropanoate has been grown by the slow evaporation method, and its molecular structure, crystalline nature, are analyzed by powder X-ray diffraction and FTIR analysis, revealed the existence of functional groups of molecules. UV visible absorption occurs at the lower cut-off wavelength of 265 nm and the optical constants such as absorption coefficient (α), energy band gap (Eg), extinction coefficient (K), refractive index (n = 1.83), the real and imaginary parts of dielectric constants (ε1 and ε2), and dielectric loss were determined from the UV–Vis spectrum. The excitation band gap from the photoluminescence spectrum, the electrochemical band gap from the cyclic voltammeter, and the thermal stability from TG/DTA are determined. The second harmonic generation efficiency is 1.2 times higher than KDP.

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Acknowledgements

The authors thank the management of St. Joseph’s College (Autonomous), Tiruchirappalli 620002, Tamil Nadu, India for the encouragement to carry out this work successfully. The authors thank, DST-FIST, Government of India for funding towards infrastructure and instrumentation facilities at ACIC, St.Joseph’s College (Autonomous), Tiruchirappalli-620002.

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The authors declare that this research finding is not funded by any funding agencies.

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Authors and Affiliations

  1. Department of Physics, St. Joseph’s College (Autonomous), Affiliated to Bharathidasan University, Trichy, Tamil Nadu, 620002, India

    S. Mohanraj, A. Sinthiya & B. Janani

  2. Department of Physics, St. Joseph’s Institute of Technology, OMR, Chennai, Tamil Nadu, 600119, India

    P. Jayaprakash

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  1. S. Mohanraj
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This paper was prepared by the author’s contributions. The first author (SM) prepared the compound, experimental part and drafted the work. The second author (AS) did the Supervision the work and revised the paper for publication. The third author (BJ) did the experimental work. The fourth author (PJ) reviewed the paper.

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Correspondence to A. Sinthiya.

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Mohanraj, S., Sinthiya, A., Janani, B. et al. Investigations on synthesis, growth and physicochemical properties of organic nonlinear optical crystal: 2A3C2HP (C5H7N2+.C6H7O7−). J Mater Sci: Mater Electron 35, 892 (2024). https://doi.org/10.1007/s10854-024-12664-8

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