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Fabrication of S,N co-doped graphene powders for symmetrical supercapacitors in different aqueous electrolytes

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Abstract

In this study, coin cell symmetrical supercapacitors were obtained using S,N co-doped graphene powders. S,N co-doped graphene powders were prepared using Yucel’s Method with cyclic voltammetry at different potential ranges for selective modification of powders by functional groups. Electrochemical, spectroscopic and microscopic characterization of S,N co-doped graphene powders were carried out. The formation of graphene layers was supported by scanning electron microscopy and Raman analysis. Functional groups formed on the surfaces of S,N co-doped graphene powders were determined by X-ray photoelectron spectroscopy. Specific capacitances of the coin cell symmetrical supercapacitors prepared with S,N co-doped graphene powders were determined by cyclic charge–discharge tests. The highest specific capacitance was 188.3 F.g−1 and the highest energy and power values were determined as 163.4 Wh.kg−1 and 2173.9 W.kg−1, respectively.

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The datasets generated during and/or analysed during the current study are available from the corresponding author on reasonable request.

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Funding

This work was supported by Yildiz Technical University under the contract number of FDK‐2019‐3573.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Art and Sciences, Yildiz Technical University, 34210, Istanbul, Türkiye

    Melih Besir Arvas & Yucel Sahin

  2. Department of Chemistry, Faculty of Science, Istanbul University, 34134, Istanbul, Türkiye

    Melih Besir Arvas

  3. Renewable Energy Division, Institute of Energy, Istanbul Technical University, 34469, Istanbul, Türkiye

    Nilgun Karatepe

  4. Department of Metallurgy and Materials Engineering, Faculty of Chemical and Metallurgical Engineering, Yildiz Technical University, 34210, Istanbul, Türkiye

    Metin Gencten

Authors
  1. Melih Besir Arvas
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Contributions

All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by MBA, NK, MG and YS. The first draft of the manuscript was written by MBA and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

Corresponding author

Correspondence to Yucel Sahin.

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The authors have no relevant financial or non-financial interests to disclose. The authors declare that they have no known personal relationships that could have appeared to influence the work reported in this paper. The authors declare that there are no potential conflicts of interest in any matter.

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Arvas, M.B., Karatepe, N., Gencten, M. et al. Fabrication of S,N co-doped graphene powders for symmetrical supercapacitors in different aqueous electrolytes. J Mater Sci: Mater Electron 34, 1068 (2023). https://doi.org/10.1007/s10854-023-10441-7

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