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Development of sustainable polybenzoxazine-based organic–inorganic hybrid nanocomposites for high voltage insulator applications

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Abstract

The benzoxazines made from cardanol-aniline (C-a), bisphenol-A-aniline (BA-a), and bisphenol-F-aniline (BF-a) were separately reacting with paraformaldehyde through Mannich condensation reaction. Hybrid polymeric blends of binary and ternary compositions were developed using DGEBA, C-a and BA-a/BF-a matrices. Bio-silica was obtained from rice-husk, which was functionalized using glycidoxypropyltrimethoxysilane, reinforced with combinations of binary and ternary blends of epoxy/benzoxazine resins, and then cured with triethylenetetramine (teta). From thermogravimetric analysis, it was inferred that 100 wt% of bio-silica reinforced hybrid poly(C-a/BA-a/DGEBA) and poly(C-a/BF-a/DGEBA) composite samples possess better thermal stability than that of neat matrices. Among the composites, silica reinforced composites possess a lower dielectric constant than that of other composites. The value of break down voltage of 100 wt% of bio-silica reinforced polymer composites namely, poly(DGEBA-teta), poly(C-a 50wt%/DGEBA 50 wt%), poly(C-a/BA-a/DGEBA) and poly(C-a/BF-a/DGEBA) were observed at 25.93, 31.44, 31.74 and 32.30 kV, respectively. According to the data obtained from different experimental studies, hybrid composites made of epoxy resin and benzoxazine with bio-silica reinforcement possess better performance characteristics and can be considered a better suited material for high voltage insulation applications.

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Data availability

The datasets generated during and/or analysed during the current study are available from the corresponding author on reasonable request.

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Acknowledgements

The authors thank the PSG Management, Secretary, and Principal, PSG Institute of Technology and Applied Research, Neelambur, Coimbatore, India, for their moral and financial support.

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No funds, grants, or other support was received.

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Authors and Affiliations

  1. Polymer Engineering Laboratory, PSG Institute of Technology and Applied Research, Coimbatore, 641 062, India

    M. Mohamed Iqbal, Subasri Appasamy, Balaji Krishnasamy, Hariharan Arumugam & Alagar Muthukaruppan

  2. Department of Electrical and Electronics Engineering, PSG Institute of Technology and Applied Research, Coimbatore, 641 062, India

    M. Mohamed Iqbal & C. L. Vasu

  3. Department of Electrical and Electronics Engineering, National Engineering College, Kovilpatti, 628 503, India

    R. V. Maheshwari & B. Vigneshwaran

Authors
  1. M. Mohamed Iqbal
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  2. Subasri Appasamy
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  3. Balaji Krishnasamy
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  4. Hariharan Arumugam
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  5. R. V. Maheshwari
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  6. B. Vigneshwaran
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  7. C. L. Vasu
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  8. Alagar Muthukaruppan
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Contributions

MMI, SA: Synthesis, Methodology, Characterization, Investigation. HA: Writing—original draft, Conceptualization, Methodology, Characterization, Investigation, Supervision. BK: Methodology, Review and Editing, Project adminisation. RVM, BV: Characterization, Validation. CLV: Methodology, Validation. AM: Resources, Validation, Supervision.

Corresponding authors

Correspondence to Hariharan Arumugam or Alagar Muthukaruppan.

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Iqbal, M.M., Appasamy, S., Krishnasamy, B. et al. Development of sustainable polybenzoxazine-based organic–inorganic hybrid nanocomposites for high voltage insulator applications. J Mater Sci: Mater Electron 34, 603 (2023). https://doi.org/10.1007/s10854-022-09805-2

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