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Sm doped BNT–BZT lead-free ceramic for energy storage applications with broad temperature range

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Abstract

Dielectric ceramics with good temperature stability and excellent energy storage performances are in great demand for numerous electrical energy storage applications. In this work, xSm doped 0.5Bi0.51Na0.47TiO3–0.5BaZr0.45Ti0.55O3 (BNT–BZT − xSm, x = 0–0.04) relaxor ferroelectric lead-free ceramics were synthesized by high temperature solid-state sintering for energy storage applications. The grain sizes of BNT–BZT − xSm ceramics exhibited gradually decrease with the increase of Sm doping content, and the temperature stability of dielectric properties were improved due to the significantly reduced dielectric constant at depolarization temperature (Td). It’s worth noting that a good temperature stability with the variation of dielectric constant at − 50–200 °C (Δε) less than 15% was obtained in the BNT–BZT − 0.04Sm ceramic. A high recoverable energy storage density Wrec = 1.12 J/cm3 and high energy storage efficiency η = 89.6%, together with excellent temperature stability from 25 to 200 °C and fast charge–discharge t0.9 = 0.655 µs were achieved in BNT–BZT − 0.04Sm ceramic, demonstrating its potential application for future pulse electric device candidate.

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All data generated or analyzed during this study are included in this published article (and its supplementary information files).

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Acknowledgements

This work was supported by Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory (Grant No. XHT2020-011), Major Program of the Natural Science Foundation of China (Grant No. 51790490), Natural Science Foundation of China (Grant No. 51872213) and Self-determined and Innovative Research Funds of SKLWUT (2021-PY-4).

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Authors and Affiliations

  1. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Material Science and Engineering, International School of Material Science and Engineering, Wuhan University of Technology, Wuhan, 430070, China

    Zixuan Pan, Hua Hao, Dongxu Li, Zhonghua Yao, Minghe Cao & Hanxing Liu

  2. Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory, Xianhu Hydrogen Valley, Foshan, 528200, China

    Hua Hao, Qinghu Guo & Zhonghua Yao

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  1. Zixuan Pan
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  2. Hua Hao
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  3. Dongxu Li
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  4. Qinghu Guo
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Contributions

ZP performed the experiment; ZP performed the data analyses and wrote the manuscript; HH, DL, QG, ZY, MC, HL helped to perform the analysis with constructive discussions.

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Correspondence to Hua Hao.

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Pan, Z., Hao, H., Li, D. et al. Sm doped BNT–BZT lead-free ceramic for energy storage applications with broad temperature range. J Mater Sci: Mater Electron 33, 14644–14654 (2022). https://doi.org/10.1007/s10854-022-08383-7

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