Abstract
In this study, we report the fabrication of WSe2/SnSe2/WSe2 van der Waals (vdW) heterostructures for potential applications as tunnel field-effect transistors (TFETs), bipolar junction transistors (BJTs), diodes, and phototransistors. We performed morphological, electrical, and optoelectronic characterizations of both back-gated WSe2/SnSe2 TFETs and WSe2/SnSe2/WSe2 BJTs. The electrical characterization of the WSe2/SnSe2 vdW-based TFETs exhibited a trend of negative differential resistance originating from band-to-band tunneling. The WSe2/SnSe2 vdW-based photodiode showed maximum photoresponsivity in the TFET of approximately 65 AW-1 at a laser power and wavelength of 0.015 µW and 532 nm, respectively. The results support the application of WSe2, SnSe2, and their heterostructures in multifunctional two-dimensional nanoelectronic devices.
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References
S. Aftab, H.M. Ul Haq, H.M. Ul Haq, S. Yousuf, M.U. Khan, Z. Ahmed, J. Aziz, M.W. Iqbal, A. ur Rehman, M.Z. Iqbal, Van der Waals multi-heterostructures (PN, PIN, and NPN) for dynamic rectification in 2D materials. Adv. Mater. Interfaces 7(24), 2001479 (2020). https://doi.org/10.1002/admi.202001479
X. Guan, X. Yu, D. Periyanagounder, M.R. Benzigar, J.K. Huang, C.H. Lin, J. Kim, S. Singh, L. Hu, G. Liu, D. Li, Recent progress in short-to long‐wave infrared photodetection using 2D materials and heterostructures. Adv. Opt. Mater. 9(4), 2001708 (2021). https://doi.org/10.1002/adom.202001708
G.S. Shanker, A. Biswas, S. Ogale, 2D materials and their heterostructures for photocatalytic water splitting and conversion of CO2 to value chemicals and fuels. J. Phys. Energy 3, 022003 (2021). https://doi.org/10.1088/2515-7655/abdcab
X.T. Liu, J.R. Chen, Y. Wang, S.T. Han, Y. Zhou, Building functional memories and logic circuits with 2D boron nitride. Adv. Funct. Mater. 31(4), 2004733 (2021). https://doi.org/10.1002/adfm.202004733
L. Tong, Z. Peng, R. Lin, Z. Li, Y. Wang, X. Huang, K.H. Xue, H. Xu, F. Liu, H. Xia, P. Wang, 2D materials–based homogeneous transistor-memory architecture for neuromorphic hardware. Science 373(6561), 1353–1358 (2021). https://doi.org/10.1126/science.abg3161
L. Yin, R. Cheng, Z. Wang, F. Wang, M.G. Sendeku, Y. Wen, X. Zhan, J. He, Two-dimensional unipolar memristors with logic and memory functions. Nano Lett. 20(6), 4144–4152 (2020). https://doi.org/10.1021/acs.nanolett.0c00002
S. Conti, L. Pimpolari, G. Calabrese, R. Worsley, S. Majee, D.K. Polyushkin, M. Paur, S. Pace, D.H. Keum, F. Fabbri, G. Iannaccone, Low-voltage 2D materials-based printed field-effect transistors for integrated digital and analog electronics on paper. Nat. Commun. 11(1), 1–9 (2020). https://doi.org/10.1038/s41467-020-17297-z
J. Jiang, Y. Zhang, A. Wang, J. Duan, H. Ji, J. Pang, Y. Sang, X. Feng, H. Liu, L. Han, Construction of high field-effect mobility multilayer MoS2 field-effect transistors with excellent stability through interface engineering. ACS Appl. Electron. Mater. 2(7), 2132–2140 (2020). https://doi.org/10.1021/acsaelm.0c00347
K. Nakamura, N. Nagamura, K. Ueno, T. Taniguchi, K. Watanabe, K. Nagashio, All 2D heterostructure tunnel field-effect transistors: impact of band alignment and heterointerface quality. ACS Appl. Mater. Interfaces 12(46), 51598–51606 (2020). https://doi.org/10.1021/acsami.0c13233
B.W. Su, B.W. Yao, X.L. Zhang, K.X. Huang, D.K. Li, H.W. Guo, X.K. Li, X.D. Chen, Z.B. Liu, J.G. Tian, A gate-tunable symmetric bipolar junction transistor fabricated via femtosecond laser processing. Nanoscale Adv. 2(4), 1733–1740 (2020). https://doi.org/10.1039/D0NA00201A
B.W. Su, X.L. Zhang, B.W. Yao, H.W. Guo, D.K. Li, X.D. Chen, Z.B. Liu, J.G. Tian, Laser writable multifunctional van der Waals heterostructures. Small 16(50), 2003593 (2020). https://doi.org/10.1002/smll.202003593
L. Lucchesi, G. Calogero, G. Fiori, G. Iannaccone, Ballistic two-dimensional lateral heterojunction bipolar transistor. Phys. Rev. Res. 3(2), 023158 (2021). https://doi.org/10.1103/PhysRevResearch.3.023158
A.M. Afzal, M.Z. Iqbal, G. Dastgeer, G. Nazir, S. Mumtaz, M. Usman, J. Eom, WS2/GeSe/WS2 bipolar transistor-based chemical sensor with fast response and recovery times. ACS Appl. Mater. Interfaces 12(35), 39524–39532 (2020). https://doi.org/10.1021/acsami.0c05114
L. Liu, N. Xu, Y. Zhang, P. Zhao, H. Chen, S. Deng, Van der Waals bipolar junction transistor using vertically stacked two-dimensional atomic crystals. Adv. Funct. Mater. 29(17), 1807893 (2019). https://doi.org/10.1002/adfm.201807893
S. Fan, Q.A. Vu, S. Lee, T.L. Phan, G. Han, Y.M. Kim, W.J. Yu, Y.H. Lee, Tunable negative differential resistance in van der Waals heterostructures at room temperature by tailoring the interface. ACS nano. 13(7), 8193–8201 (2019). https://doi.org/10.1021/acsnano.9b03342
J. He, N. Fang, K. Nakamura, K. Ueno, T. Taniguchi, K. Watanabe, K. Nagashio, 2D tunnel field effect transistors (FETs) with a stable charge-transfer‐type p+‐WSe2 source. Adv. Electron. Mater. 4(7), 1800207 (2018). https://doi.org/10.1002/aelm.201800207
N. Oliva, J. Backman, L. Capua, M. Cavalieri, M. Luisier, A.M. Ionescu, WSe2/SnSe2 vdW heterojunction Tunnel FET with subthermionic characteristic and MOSFET co-integrated on same WSe2 flake. NPJ 2D Mater. Appl. 4(1), 1–8 (2020). https://doi.org/10.1038/s41699-020-0142-2
Z. Jin, X. Li, J.T. Mullen, K.W. Kim, Intrinsic transport properties of electrons and holes in monolayer transition-metal dichalcogenides. Phys. Rev. B 90(4), 045422 (2014). https://doi.org/10.1103/PhysRevB.90.045422
A. Allain, A. Kis, Electron and hole mobilities in single-layer WSe2. ACS Nano 8(7), 7180–7185 (2014). https://doi.org/10.1021/nn5021538
J. Kim, H. Park, S. Yoo, Y.H. Im, K. Kang, J. Kim, Defect-Engineered n‐Doping of WSe2 via Argon Plasma Treatment and Its Application in Field‐Effect Transistors. Adv. Mater. Interfaces 8(14), 2100718 (2021). https://doi.org/10.1002/admi.202100718
J.S. Narro-Rios, M. Ramachandran, D. Martínez-Escobar, A. Sánchez-Juárez, Ultrasonic spray pyrolysis deposition of SnSe and SnSe2 using a single spray solution. J. Semicond. 34(1), 013001 (2013). https://doi.org/10.1088/1674-4926/34/1/013001
X. Yan, C. Liu, C. Li, W. Bao, S. Ding, D.W. Zhang, P. Zhou, Tunable SnSe2/WSe2 heterostructure tunneling field effect transistor. Small 13(34), 1701478 (2017). https://doi.org/10.1002/smll.201701478
X. Li, X. Dai, H. Xu, K. Shen, J. Guo, C. Li, G. Zou, K.L. Choy, I.P. Parkin, Z. Guo, H. Liu, Multifunctional two-dimensional glassy graphene devices for vis-NIR photodetection and volatile organic compound sensing. Sci. China Mater. 64(8), 1964–1976 (2021). https://doi.org/10.1007/s40843-020-1601-9
S. Guo, K. Wu, C. Li, H. Wang, Z. Sun, D. Xi, S. Zhang, W. Ding, M.E. Zaghloul, C. Wang, F.A. Castro, Integrated contact lens sensor system based on multifunctional ultrathin MoS2 transistors. Matter 4(3), 969–985 (2021). https://doi.org/10.1016/j.matt.2020.12.002
M.M. Furchi, D.K. Polyushkin, A. Pospischil, T. Mueller, Mechanisms of photoconductivity in atomically thin MoS2. Nano Lett. 14(11), 6165–6170 (2014). https://doi.org/10.1021/nl502339q
M.H. Doan, Y. Jin, S. Adhikari, S. Lee, J. Zhao, S.C. Lim, Y.H. Lee, Charge transport in MoS2/WSe2 van der Waals heterostructure with tunable inversion layer. ACS Nano 11(4), 3832–3840 (2017). https://doi.org/10.1021/acsnano.7b00021
E.P. Mukhokosi, B. Roul, S.B. Krupanidhi, K.K. Nanda, Toward a fast and highly responsive SnSe2-based photodiode by exploiting the mobility of the counter semiconductor. ACS Appl. Mater. Interfaces 11(6), 6184–6194 (2019). https://doi.org/10.1021/acsami.8b16635
D.S. Schulman, A.J. Arnold, S. Das, Contact engineering for 2D materials and devices. Chem. Soc. Rev. 47(9), 3037–3058 (2018). https://doi.org/10.1039/C7CS00828G
M. Zhang, X. Liu, X. Duan, S. Zhang, C. Liu, D. Wan, G. Li, Z. Xia, Z. Fan, L. Liao, Schottky-contacted WSe2 hot-electron photodetectors with fast response and high sensitivity. ACS Photon. 9(1), 132–137 (2022). https://doi.org/10.1021/acsphotonics.1c01256
H.J. Jin, C. Park, K.J. Lee, G.H. Shin, S.Y. Choi, Ultrasensitive WSe2/a-In2Se3 NIR photodetector based on ferroelectric gating effect. Adv. Mater. Technol. 6(11), 2100494 (2021). https://doi.org/10.1002/admt.202100494
X. Tian, Y. Liu, Van der Waals heterojunction ReSe2/WSe2 polarization-resolved photodetector. J. Semicond. 42(3), 032001 (2021). https://doi.org/10.1088/1674-4926/42/3/032001
S. Ghosh, A. Varghese, K. Thakar, S. Dhara, S. Lodha, Enhanced responsivity and detectivity of fast WSe2 phototransistor using electrostatically tunable in-plane lateral pn homojunction. Nat. Commun. 12(1), 1–9 (2021). https://doi.org/10.1038/s41467-021-23679-8
W. Gao, Z. Zheng, L. Huang, J. Yao, Y. Zhao, Y. Xiao, J. Li, Self-powered SnS1–x Se x alloy/silicon heterojunction photodetectors with high sensitivity in a wide spectral range. ACS Appl. Mater. Interfaces 11(43), 40222–40231 (2019). https://doi.org/10.1021/acsami.9b12276
M. Vemula, S. Veeralingam, S. Badhulika, Hybrid 2D/0D SnSe2-SnO2 vertical junction based high performance broadband photodetector. J. Alloys Compd. 883, 160826 (2021). https://doi.org/10.1016/j.jallcom.2021.160826
M. Kang, S. Rathi, I. Lee, L. Li, M.A. Khan, D. Lim, Y. Lee, J. Park, A.T. Pham, A.T. Duong, S. Cho, Photodetector based on multilayer SnSe2 field effect transistor. J. Nanosci. Nanotechnol. 18(6), 4243–4247 (2018). https://doi.org/10.1166/jnn.2018.15189
Acknowledgements
This work was supported by the Brain Pool Program through the National Research Foundation of Korea (NRF), funded by the Ministry of Science and ICT (NRF-2019H1D3A1A01102658). This study was supported by a research fund from Chosun University (2021).
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Abderrahmane, A., Woo, C. & Ko, P.J. Multifunctional WSe2/SnSe2/WSe2 van der Waals heterostructures. J Mater Sci: Mater Electron 33, 11841–11850 (2022). https://doi.org/10.1007/s10854-022-08147-3
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DOI: https://doi.org/10.1007/s10854-022-08147-3