Skip to main content
Log in

Improvement in dielectric properties of the three-phase GN–BaTiO3–PEK nanocomposites with and without silane coupling agent

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Graphite nanoplatelets (GN)-barium titanate (BaTiO3)-polyetherketone (PEK) nanocomposites containing 3-aminopropyltriethoxy silane-treated and untreated BaTiO3 nanoparticles were successfully fabricated. A dielectric constant of ~ 13.9 was obtained for 50 wt%-treated BaTiO3–PEK nanocomposite. The nanocomposites showed a weak frequency-dependent dielectric constant with dissipation factor lower than 0.03. Fourier transform infrared spectroscopy confirmed the compatibility between the treated BaTiO3 nanoparticles and PEK. Interestingly, a similar value of dielectric constant was obtained for the nanocomposites containing 0.3 wt% GN and 30 wt% BaTiO3, thus decreasing the density of the materials without compromising dielectric properties. The nanocomposites exhibited thermal stability above 560 °C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. R.R. Tummala, E.J. Rymaszewski, A.G. Klopfenstein, Microelectronics Packaging Handbook, 2nd edn. (Springer, Dordrecht, 2012)

    Google Scholar 

  2. J. Prymark, S. Bhattacharya, K. Paik, R.R. Tummala, Fundamentals of Microsystems Packaging, 1st edn. (McGraw-Hill, New York, 2001)

    Google Scholar 

  3. J. Lu, C.P. Wong, IEEE Trans. Dielectr. Electr. Insul. 15, 1322 (2008)

    Article  CAS  Google Scholar 

  4. Z. Dang, J. Yuan, J. Zha, T. Zhou, Progr. Mater. Sci. 57, 660 (2012)

    Article  CAS  Google Scholar 

  5. S. George, M.T. Sebastian, Compos. Sci. Technol. 69, 1298 (2009)

    Article  CAS  Google Scholar 

  6. S.O. Kasap, Principles of Electronic Materials and Devices, 3rd edn. (McGraw-Hill, New York, 2006)

    Google Scholar 

  7. R. K. Goyal, A. B. Kulkarni, J. Phys. D 45, 465302 (2012).

  8. V. Prateek, R.K. Thakur, Gupta. Chem. Rev. 116, 4260 (2016)

    Article  CAS  Google Scholar 

  9. R.K. Goyal, V.V. Madav, P.R. Pakankar, S.P. Butee, J. Electr. Mater. 40, 2240 (2011)

    Article  CAS  Google Scholar 

  10. R.K. Goyal, S.S. Katkade, D.M. Mule, Composite B 44, 128 (2013)

    Article  CAS  Google Scholar 

  11. K.R. Kambale, R. Goyal, S.P. Butee, R. Parsewar, H. Gawade, S. Shro, Comput. Commun. 5, 8 (2017)

    Article  Google Scholar 

  12. S. Liu, S. Xue, S. Xiu, B. Shen, J. Zhai, Nat. Publ. Gr. 6, 1 (2016)

    Google Scholar 

  13. A.A. Thanki, R.K. Goyal, Mater. Chem. Phys. 183, 447 (2016)

    Article  CAS  Google Scholar 

  14. H. Tang, J. Zhong, J. Yang, Z. Ma, J. Electr. Mater. 40, 141 (2011)

    Article  CAS  Google Scholar 

  15. C. Ehrhardt, C. Fettkenhauer, J. Glenneberg, W. Münchgesang, C. Pientschke, T. Großmann, M. Zenkner, G. Wagner, H.S. Leipner, A. Buchsteiner, M. Diestelhorst, S. Lemm, H. Beige, S.G. Ebbinghaus, Mater. Sci. Eng. B 178, 881 (2013)

    Article  CAS  Google Scholar 

  16. G. Panomsuwan, S. Kaewwata, H. Manuspiya, H. Ishida, in Proc. 2nd IEEE Int. Conf. Nano/Micro Eng. Mol. Syst. IEEE NEMS 2007, 497 (2007).

  17. W. Xu, Y. Ding, S. Jiang, W. Ye, X. Liao, H. Hou, Polym. Comput. 37, 794 (2016)

    Article  CAS  Google Scholar 

  18. P.K. Sain, R.K. Goyal, A.K. Bhargava, Y.V.S.S. Prasad, J. Appl. Polym. Sci. 39913, 1 (2014)

    Google Scholar 

  19. W. Yang, S. Yu, S. Luo, R. Sun, W. Liao, C. Wong, J. Alloys Compd. 620, 315 (2015)

    Article  CAS  Google Scholar 

  20. P. Kim, S.C. Jones, P.J. Hotchkiss, J.N. Haddock, B. Kippelen, S.R. Marder, J.W. Perry, Adv. Mater. 19, 7 (2007)

    Google Scholar 

  21. Z. Dang, H. Wang, H. Xu, H. Wang, Appl. Phys. Lett. 89, 1 (2006)

    Article  Google Scholar 

  22. Y. Lu, S. Zhang, Z. Geng, Y. Du, K. Zhu, RSC Adv. 6, 72999 (2016)

    Article  CAS  Google Scholar 

  23. S. Siddabattuni, Scholars’ Mine D. Dissertations, 1954 (2011) http://scholarsmine.mst.edu/doctoral_dissertations/1954.

  24. P. Kim, N.M. Doss, J.P. Tillotson, P.J. Hotchkiss, M. Pan, S.R. Marder, J. Li, J.P. Calame, J. W. Perry 3, 2581 (2009)

    CAS  Google Scholar 

  25. X. Yang, Q. Wang, Y. Zhang, Z. Jiang, Polym. J. 44, 1042 (2012)

    Article  CAS  Google Scholar 

  26. Yu. Ke, Y. Niu, Y. Zhou, Y. Bai, H. Wang, J. Am. Ceram. Soc. 2524, 2519 (2013)

    Google Scholar 

  27. S.K. Bhattacharya, R.R. Tummala, J. Mater. Sci. Mater. Electr. 11, 253 (2000)

    Article  CAS  Google Scholar 

  28. X. Liao, H. Hou, Mater. Lett. 135, 158 (2014)

    Article  Google Scholar 

  29. Z. Wang, W. Zhou, X. Sui, L. Dong, J. Reinf. Plastics Comp. 34, 1126 (2015)

    Article  Google Scholar 

  30. L. Qi, B.I. Lee, W.D. Samuels, G.J. Exarhos, S.G. Parler, C. Dubilier, S. Carolina, J. Appl. Polym. Sci. 102, 967 (2005)

    Article  Google Scholar 

  31. P. K. Sain, R. K. Goyal, Y. V. S. S. Prasad, A. K. Bhargava, Mater. Res. Exp. 3, 085016 (2016).

  32. Y. Cui, X. Wang, Q. Chi, J. Dong, T. Ma, J. Mater. Sci. Mater. Electron. 28, 11900 (2017)

    Article  CAS  Google Scholar 

  33. G. Wang, A.C.S. Appl, Mater. Interfaces 2, 1290 (2010)

    Article  CAS  Google Scholar 

  34. C. Yu, D. Wu, Y. Liu, H. Qiao, Z. Yu, A. Dasari, Compos. Sci. Technol. 71, 1706 (2011)

    Article  CAS  Google Scholar 

  35. C. Zhang, Q. Chi, J. Dong, Y. Cui, X. Wang, L. Liu, Nat. Publ. Gr. 6, 33508 (2016)

    CAS  Google Scholar 

  36. C. Nan, Y. Shen, J. Ma, Annu. Rev. Mater. Res. 40, 131 (2010)

    Article  CAS  Google Scholar 

  37. P.K. Sain, R.K. Goyal, Y.V.S.S. Prasad, K.B. Sharma, A.K. Bhargava, J. Appl. Polym. Sci. 42443, 1 (2015)

    Google Scholar 

  38. P.K. Sain, R.K. Goyal, Y.V.S.S. Prasad, A.K. Bhargava, J. Electr. Mater. 46, 458 (2016)

    Article  Google Scholar 

  39. R. K. Goyal S. D. Bhosale, S. D. Gaikwad, R. D. Gadve. Mater. Sci. Eng. B. 265, 115038 (2021).

  40. L. Ramajo, M.S. Castro, M.M. Reboredo, Composite A 38, 1852 (2007)

    Article  Google Scholar 

  41. R. Aepuru, V.M. Gaikwad, R. Udayabhaskar, H.S. Panda, M.R. Viswanathan, J. Mater. Sci. 31, 13477 (2020)

    CAS  Google Scholar 

Download references

Acknowledgements

The Ghardha Chemicals Ltd. Thane, India is highly acknowledged for providing PEK powder for the research.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to R. K. Goyal.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Goyal, R.K., Tamhane, P. & Tambat, S. Improvement in dielectric properties of the three-phase GN–BaTiO3–PEK nanocomposites with and without silane coupling agent. J Mater Sci: Mater Electron 32, 28468–28479 (2021). https://doi.org/10.1007/s10854-021-07228-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-021-07228-z

Navigation