Abstract
A set of glasses composed of seven samples was prepared using the fast cooling mechanism for glass preparation. The synthesis processes based on the molar chemical formula; (60 − x) mole% B2O3—x mole% P2O5—25 mol% Na2O—15 mol% FeO, where x = 0, 10, 20, 30, 40, 50 and 60 mol%. The obtained samples represented three different types of oxide glasses, pure borate glass (x = 0), Borophosphate glass (x = 10, 20, 30, 40, 50), and pure phosphate glass (x = 60). FTIR showed the non-crystalline natures of the as-prepared samples, and also, showed that some Iron cations share the tetrahedral glass positions as FeO4 to act as a glass network formers. At the same time, some other occupied the octahedral vacancies as FeO6 to act as a glass network modifiers. As B2O3 replaced by P2O5, all the density, molar volume, calculated static refractive index, and metallization factor increased. The Phy-X/PSD software was used to study the gamma attenuation and buildup parameters EBF and EABF for the studied glasses in the range of photon energy from 0.015 to 15 MeV. Phosphate-rich glasses showed comparable shielding ability concerning some standard glass samples (RS-253-G18, RS-360, and RS-520).
Similar content being viewed by others
References
G. Susoy, Effect of TeO2 additions on nuclear radiation shielding behavior of Li2O–B2O3–P2O5–TeO2 glass-system. Ceram. Int. 46(3), 3844–3854 (2020). https://doi.org/10.1016/j.ceramint.2019.10.108
G. Lakshminarayana, S.O. Baki, A. Lira, I.V. Kityk, U. Caldiño, K.M. Kaky, M.A. Mahdi, Structural, thermal and optical investigations of Dy3+-doped B2O3–WO3–ZnO–Li2O–Na2O glasses for warm white light emitting applications. J. Lumin. 186, 283–300 (2017). https://doi.org/10.1016/j.jlumin.2017.02.049
H.O. Tekina, O. Kilicoglu, E. Kavaz, E.E. Altunsoy, M. Almatari, O. Agar, M.I. Sayyed, The investigation of gamma-ray and neutron shielding parameters of Na2OCaO–P2O5–SiO2 bioactive glasses using MCNPX code. Results Phys. 12, 1797–1804 (2019). https://doi.org/10.1016/j.rinp.2019.02.017
H.O. Tekina, E. Kavaz, E.E. Altunsoy, O. Kilicoglu, O. Agar, T.T. Erguzel, M.I. Sayyed, An extensive investigation on gamma-ray and neutron attenuation parameters of cobalt oxide and nickel oxide substituted bioactive glasses. Ceram. Int. 45, 9934–9949 (2019). https://doi.org/10.1016/j.ceramint.2019.02.036
M.I. Sayyeda, K.M. Kaky, D.K. Gaikwad, O. Agar, U.P. Gawai, S.O. Baki, Physical, structural, optical and gamma radiation shielding properties of borate glasses containing heavy metals (Bi2O3/MoO3). Non-Cryst. Solids 507, 30–37 (2019). https://doi.org/10.1016/j.jnoncrysol.2018.12.010
M.G. Dong, O. Agar, H.O. Tekin, O. Kilicoglu, K.M. Kaky, M.I. Sayyed, A comparative study on gamma photon shielding features of various germanate glass systems. J. Compos. B Eng. 165, 636–647 (2019). https://doi.org/10.1016/j.compositesb.2019.02.022
H.O. Tekina, E.E. Altunsoy, E. Kavaz, M.I. Sayyed, O. Agar, M. Kamislioglu, Photon and neutron shielding performance of boron phosphate glasses for diagnostic radiology facilities. J. Results Phys. 12, 1457–1464 (2019). https://doi.org/10.1016/j.rinp.2019.01.060
M.I. Sayyed, Bismuth modified shielding properties of zinc boro-tellurite glasses. J. Alloy. Comp. 688, 111–117 (2016). https://doi.org/10.1016/j.jallcom.2016.07.153
R. El-Mallawany, M.I. Sayyed, M.G. Dong, Comparative shielding properties of some tellurite glasses: Part 2. J. Non-Cryst. Solids 474, 16–23 (2017). https://doi.org/10.1016/j.jnoncrysol.2017.08.011
A. Kumar, Gamma ray shielding properties of PbO–Li2O–B2O3 glasses. J. Radiat. Phys. Chem. 136, 50–53 (2017). https://doi.org/10.1016/j.radphyschem.2017.03.023
L. Muñoz-Senovilla, G. Tricot, F. Muñoz, Kinetic fragility and structure of lithium borophosphate glasses analysed by 1D/2D NMR. Phys. Chem. Chem. Phys. 19, 22777–22784 (2017). https://doi.org/10.1039/c7cp04171c
A.J. Parsons, N. Sharmin, S.I.S. Shaharuddin, M. Marshall, Viscosity profiles of phosphate glasses through combined quasi-static and bob-in-cup methods. J. Non-Cryst. Solids 408, 76–86 (2015). https://doi.org/10.1016/j.jnoncrysol.2014.10.014
I.W. Donald, Preparation, properties and chemistry of glass and glass-ceramic-to-metal seals and coatings. J. Mater. Sci. 28, 2841–2886 (1993)
Y.S. Kim, K.H. Lee, T.H. Kim, Y.J. Jung, B.K. Ryu, Nucleation and crystallization of phosphate glass for a PDP barrier rib by differential thermal analysis. Electron. Mater. Lett. 4, 1 (2008)
H. Takebe, T. Harada, M. Kawabata, Effect of B2O3 addition on the thermal properties and density of barium phosphate glasses. J. Non-Cryst. Solids 352, 709–713 (2006). https://doi.org/10.1016/j.jnoncrysol.2005.11.066
J.F. Ducel, J.J. Videau, Physical and chemical characterizations of sodium borophosphate glasses. Mater. Lett. 13, 271–274 (1992). https://doi.org/10.1016/0167-577X(92)90230-H
P. Subbalakshmi, N. Veeraiah, Study of CaO–WO3–P2O5 glass system by dielectric properties, IR spectra and differential thermal analysis. J. Non-Cryst. Solids 298, 89–98 (2002). https://doi.org/10.1016/S0022-3093(01)01039-0
P.S. Gahlot, V.P. Seth, A. Agarwal, N. Kisore, S.K. Gupta, M. Arora, D.R. Goyal, Influence of ZnO on optical properties and dc conductivity of vanadyl-doped alkali bismuthate glasses. Radiat. Eff. Defects Solids 159, 223–231 (2004). https://doi.org/10.1080/1042015042000209334
M.V. Rao, V.V.R.K. Kumar, N.K. Shihab, D.N. Rao, Z-scan studies of barium bismuth borate glasses. Opt. Mater. 84, 178–183 (2018). https://doi.org/10.1016/j.optmat.2018.06.066
M.S. Al-Buriahi, Y.S. Rammah, Investigation of the physical properties and gamma-ray shielding capability of borate glasses containing PbO, Al2O3 and Na2O. Appl. Phys. A 125, 717 (2019). https://doi.org/10.1007/s00339-019-3020-z
Y. Al-Hadeethi, M.I. Sayyed, Y.S. Rammah, Investigations of the physical, structural, optical and gamma-rays shielding features of B2O3–Bi2O3–ZnO–CaO glasses. Ceram. Int. 45, 20724–20732 (2019). https://doi.org/10.1016/j.ceramint.2019.07.056
A. Magistris, G. Chiodelli, M. Villa, Lithium borophosphate vitreous electrolytes. J. Power Sources 14, 87–91 (1985). https://doi.org/10.1016/0378-7753(85)88016-2
E.I. Kamitsos, M.A. Karakassides, Structural studies of binary and pseudo binary sodium borate glasses of high sodium content. Phys. Chem. Glasses 30, 229 (1989)
O. Cozar, I. Ardelean, I. Bratu, S. Siman, C. Craciun, L. David, C. Cafen, IR and EPR studies on some lithium-borate glasses with vanadium ions. J. Mol. Struct. 563–564, 421–425 (2001)
C. Gejke, E. Zanghellini, J. Swenson, L. Börjess, Microscopic structure of tin-borate and tin-boratephosphate glasses. J. Power Sources 119–121, 576–580 (2003). https://doi.org/10.1016/S0378-7753(03)00290-8
A.J. Parsons, L.D. Burling, C.A. Scotchford, G.S. Walker, C.D. Rudd, Properties of sodium-based ternary phosphate glasses produced from readily available phosphate salts. J. Non-Cryst. Solids 352, 5309–5317 (2006). https://doi.org/10.1016/j.jnoncrysol.2006.08.043
P.Y. Shih, S.W. Yung, T.S. Chin, Thermal and corrosion behavior of P2O5–Na2O–CuO glasses. J. Non-Cryst. Solids 224, 143–152 (1998). https://doi.org/10.1016/S0022-3093(97)00460-2
N. Sharmin, C.D. Rudd, Structure, thermal properties, dissolution behaviour and biomedical applications of phosphate glasses and fibres: a review. J. Mater. Sci. 52(15), 8733–8760 (2017). https://doi.org/10.1007/s10853-017-0784-4
M.A. Villegas, J.F. Navarro, Physical and structural properties of glasses in the TeO2–TiO2–Nb2O5 system. J. Eur. Ceram. Soc. 27(7), 2715 (2007). https://doi.org/10.1016/j.jeurceramsoc.2006.12.003
J. Allison, K. Amako, J. Apostolakis, H. Araujo, P.A. Dubois, M. Asai, G. Barrand, R. Capra, S. Chauvie, R. Chytracek, G.A.P. Cirrone, G. Cooperman, G. Cosmo, G. Cuttone, G.G. Daquino, M. Donszelmann, M. Dressel, G. Folger, F. Foppiano, J. Generowicz, V. Grichine, S. Guatelli, P. Gumplinger, A. Heikkinen, I. Hrivnacova, A. Howard, S. Incerti, V. Ivanchenko, T. Johnson, F. Jones, T. Koi, R. Kokoulin, M. Kossov, H. Kurashige, V. Lara, S. Larsson, F. Lei, F. Longo, M. Maire, A. Mantero, B. Mascialino, I. McLaren, P.M. Lorenzo, K. Minamimoto, K. Murakami, P. Nieminen, L. Pandola, S. Parlati, L. Peralta, J. Perl, A. Pfeiffer, M.G. Pia, A. Ribon, P. Rodrigues, G. Russo, S. Sadilov, G. Santin, T. Sasaki, D. Smith, N. Starkov, S. Tanaka, E. Tcherniaev, B. Tomé, A. Trindade, P. Truscott, L. Urban, M. Verderi, A. Walkden, J.P. Wellisch, D.C. Williams, D. Wright, H. Yoshida, M. Peirgentili, Geant4 developments and applications. IEEE Trans. Nucl. Sci. (2006). https://doi.org/10.1109/TNS.2006.869826
L.S. Waters, G.W. McKinney, J.W. Durkee, M.L. Fensin, J.S. Hendricks, M.R. James, R.C. Johns, D.B. Pelowitz, The MCNPX Monte Carlo radiation transport code. AIP Conf. Proc. (2007). https://doi.org/10.1063/1.2720459
G. Battistoni, F. Broggi, M. Brugger, M. Campanella, M. Carboni, A. Empl, A. Fassò, E. Gadioli, F. Cerutti, A. Ferrari, A. Ferrari, M. Lantz, A. Mairani, M. Margiotta, C. Morone, S. Muraro, K. Parodi, V. Patera, M. Pelliccioni, L. Pinsky, J. Ranft, S. Roesler, S. Rollet, P.R. Sala, M. Santana, L. Sarchiapone, M. Sioli, G. Smirnov, F. Sommerer, C. Theis, S. Trovati, R. Villari, H. Vincke, H. Vincke, V. Vlachoudis, J. Vollaire, N. Zapp, Applications of FLUKA Monte Carlo code for nuclear and accelerator physics. Nucl. Instruments Methods Phys. Res. Sect. B Beam Interact. With Mater. Atoms (2011). https://doi.org/10.1016/j.nimb.2011.04.028
L. Gerward, N. Guilbert, K.B. Jensen, H. Levring, WinXCom - a program for calculating X-ray attenuation coefficients. Radiat. Phys. Chem. (2004). https://doi.org/10.1016/j.radphyschem.2004.04.040
E. Şakar, Ö.F. Özpolat, B. Alım, M.I. Sayyed, M. Kurudirek, Phy-X/PSD: development of a user friendly online software for calculation of parameters relevant to radiation shielding and dosimetry. Radiat. Phys. Chem. (2020). https://doi.org/10.1016/j.radphyschem.2019.108496
G. Lakshminarayana, M.G. Dong, M.S. Al-Buriahi, A. Kumar, D.-E. Lee, J. Yoon, T. Park, B2O3–Bi2O3–TeO2–BaO and TeO2–Bi2O3–BaO glass systems: a comparative assessment of gamma-ray and fast and thermal neutron attenuation aspects. J. Appl. Phys. A 126, 202–220 (2020). https://doi.org/10.1007/s00339-020-3372-4
Y. Al-Hadeethi, M.I. Sayyed, O. Agard, Ionizing photons attenuation characterization of quaternary tellurite–zinc–niobium–gadolinium glasses using Phy-X/PSD software. J. Non-Cryst. Solids 538, 120044–120048 (2020). https://doi.org/10.1016/j.jnoncrysol.2020.120044
A.S. Abouhaswa, M.S. Al-Buriahi, M. Chalermpon, Y.S. Rammah, Influence of ZrO2 on gamma shielding properties of lead borate glasses. Appl. Phys. A 126, 78–89 (2020). https://doi.org/10.1007/s00339-019-3264-7
A. Aşkın, Assesment of the gamma and neutron shielding capabilities of the borotellurite glass quaternary containing heavy metal oxide using Geant4 and Phy-X/PSD database A. Ceram. Int. 46, 14090–14096 (2020). https://doi.org/10.1016/j.ceramint.2020.02.209
Y. Al-Hadeethi, M.I. Sayyed, J. Kaewkhao, A. Askin, B.M. Rafah, E.M. Mkawi, R. Rajaramakrishna, Physical, structural, optical, and radiation shielding properties of B2O3–Gd2O3–Y2O3 glass system. Appl. Phys. A 125, 852–857 (2019). https://doi.org/10.1007/s00339-019-3115-6
I. Kashif, H. Farouk, A.M. Sanad, S.A. Aly, Structural studies of some V2O5–P2O5–B2O3–Fe2O3 glass systems. J. Mater. Sci. 27, 122–126 (1992)
E.I. Kamitsos, M.A. Karakassides, Structural studies of binary and pseudo binary sodium borate glasses of high sodium content. J. Phys. Chem. Glasses 30, 19–26 (1989)
S. Kumar, P. Vinatier, A. Levasseur, K.J. Rao, Investigations of structure and transport in lithium and silver borophosphate glasses. J. Solid State Chem. 177, 1723–1737 (2004). https://doi.org/10.1016/j.jssc.2003.12.034
E.I. Kamitsos, A.P. Patsis, M.A. Karakassides, G.D. Chryssikos, Infrared reflectance spectra of lithium borate glasses. J. Non-Cryst. Solids 126, 52–67 (1990). https://doi.org/10.1016/0022-3093(90)91023-K
O. Cozar, I. Ardelean, I. Bratu, S. Simom, C. Craciun, L. David, C. Cefan, IR and EPR studies on some lithium-borate glasses with vanadium ions. J. Mol. Struct. 563–564, 421–425 (2001). https://doi.org/10.1016/S0022-2860(01)00442-2
P.S. Anantha, K. Hariharan, Structure and ionic transport studies of sodium borophosphate glassy system. Mater. Chem. Phys. 89, 428–437 (2005). https://doi.org/10.1016/j.matchemphys.2004.09.029
J. Swenson, L. Börjesson, Intermediate-range structure and conductivity of fast ion-conducting borate glasses. J. Non-Crystal. Solids 232–234, 658–664 (1998). https://doi.org/10.1016/S0022-3093(98)00435-9
A.H. Verhoef, H.W. Den-Hartog, Infrared spectroscopy of network and cation dynamics in binary and mixed alkali borate glasses. J. Non-Cryst. Solids 182, 221–234 (1995). https://doi.org/10.1016/0022-3093(94)00555-9
R.D. Husung, M. Robert Doremus, The infrared transmission spectra of four silicate glasses before and after exposure to water. J. Mater. Res. 5(10), 2209–2217 (1990). https://doi.org/10.1557/JMR.1990.2209
E.I. Kamitsos, M.A. Karakassides, G.D. Chryssikos, A vibrational study of lithium sulfate based fast ionlc conducting borate glasses. J. Phys. Chem. 90, 4528–4533 (1986). https://doi.org/10.1021/j100410a010
N. Eissa, W. El-Meliegy, S. El Minyawi, N. Sheta, H. Sallam, Mossbauer effect, electron spin resonance, and electrical conductivity studies of the effect of iron on the magnetic and electrical properties of sodium silicate glass. J. Phys. Chem. Glasses 34, 31–34 (1993)
H.A. Saudi, H.M. Gomaa, M.I. Sayyed, I.V. Kityk, Investigation of bismuth silicate glass system modified by vanadium and copper cations for structural and gamma-ray shielding properties. J. SN Appl. Sci. 1, 218 (2019). https://doi.org/10.1007/s42452-019-0197-x
M. Hossam, Gomaa, influence of Bi2O3 on the physical and electrical properties of some Boro-Iron glasses. J. Non-Crystal. Solids 481, 51–58 (2018). https://doi.org/10.1016/j.jnoncrysol.2017.10.012
H.M. Gomaa, S.M.E.L. Katlawy, A new empirical method for estimating the refractive index of oxide glasses using internal structure information. Am. J. Mater. Synth. Process. 2(6), 94–96 (2017). https://doi.org/10.11648/j.ajmsp.20170206.14
H.A. Saudi, H.M. Gomaa, The effect of Nb2O5 on fast neutron removal cross section, optical, and structural properties of some calcium borate oxide glasses containing Bi3+ ions. J Radiat. Detect. Technol. Methods (2019). https://doi.org/10.1007/s41605-018-0083-x
M.Y. Hassaan, H.A. Saudi, H.M. Gomaa, A.S. Morsy, Optical properties of bismuth borate glasses doped with zinc and calcium oxides. J. Mater. Appl. 9(1), 46–54 (2020). https://doi.org/10.32732/jma.2020.9.1.46
M.J. Berger and J.H. Hubbell, XCOM: Photon Cross Sections on a Personal Computer, United States: NBSIR (1987) 3597. https://doi.org/10.2172/6016002
T. Kaura, J. Sharma, T. Singh, Review on scope of metallic alloys in gamma rays shield designing. J. Prog. Nucl. Energy 113, 95–113 (2019). https://doi.org/10.1016/j.pnucene.2019.01.016
M.I. Sayyed, F. Laariedh, A. Kumr, M.S. Al-Buriahi, Experimental studies on the gamma photons-shielding competence of TeO2–PbO–BaO–Na2O–B2O3 glasses. J. Appl. Phys. A 126, 4 (2020). https://doi.org/10.1007/s00339-019-3182-8
G. Lakshminarayana, M.G. Dong, A. Kumar, Y. Elmahroug, A. Wagh, D.-E. Lee, J. Yoon, T. Park, Assessment of gamma-rays and fast neutron beam attenuation features of Er2O3-doped B2O3–ZnO–Bi2O3 glasses using XCOM and simulation codes (MCNP5 and Geant4). Appl. Phys. A (2019). https://doi.org/10.1007/s00339-019-3099-2
S.R. Manohara, S.M. Hanagodimath, K.S. Thind, L. Gerward, On the effective atomic number and electron density: a comprehensive set of formulas for all types of materials and energies above 1 keV. Nucl. Instrum. Methods Phys. Res. B 266, 3906–3912 (2008). https://doi.org/10.1016/j.nimb.2008.06.034
M. Almatari, Gamma radiation shielding properties of glasses within the TeO2–TiO2–ZnO system. Radiochim. Acta 107, 1–6 (2019). https://doi.org/10.1515/ract-2018-3058
S.R. Manohara, S.M. Hanagodimath, L. Gerward, Energy absorption buildup factors for thermoluminescent dosimetric materials and their tissue equivalence. Radiat. Phys. Chem. 79, 575–582 (2010). https://doi.org/10.1016/j.radphyschem.2010.01.002
A.A. El-Maaref, K.H.S. Shaaban, M. Abdelawwad, Y.B. Saddeek, Optical characterizations and Judd-Ofelt analysis of Dy3+ doped borosilicate glasses. J. Opt. Mater. 72, 169–176 (2017). https://doi.org/10.1016/j.optmat.2017.05.062
Funding
The authors express their appreciation to the Deanship of Scientific Research at King Khalid University for funding this work through research groups program under Grant Number R.G.P.2/61/40.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
All the authors declare that there is no any conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Gomaa, H.M., Zahran, H.Y. & Yahia, I.S. Influence of the structural matrix on the attenuation parameters of some iron-borophosphate glasses. J Mater Sci: Mater Electron 32, 21135–21154 (2021). https://doi.org/10.1007/s10854-021-06613-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-021-06613-y