Abstract
Herein, we report a facile and novel hydrothermal growth of Ag-doped MnWO4 material, and its electrocatalytic property towards glucose molecules has been investigated extensively. Crystal structure, morphology, and compositional features of the Ag-MnWO4 material are characterized by XRD and SEM equipped with energy-dispersive X-ray spectroscopy (EDAX). The morphology of the synthesized material is microflower structure, and each microflower consists of numerous nanorods diverging in all directions. The microflowers are homogeneous, well-organized in shape and size, and have grown uniformly. The glucose molecules are detected and sensed by Ag-MnWO4 electrocatalyst through the electrochemical method. The sensitivity of the Ag-MnWO4 material is calculated as 17.9 µAµM−1 cm−2 in the linear range 5–110 µM, and its response time is 8 s, respectively. Further, excellent selectivity and acceptable stability of the material are achieved. It is proposed that Ag-MnWO4 material would be an excellent glucose-sensing material because of its large surface area with enormous active catalytic centers.
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S.F. Clarke, J.R. Foster, Br. J. Biomed. Sci. 69, 83 (2012)
A.D. Association, Diabetes Care 33, S62 (2010)
B.B. Kamble, M. Naikwade, K.M. Garadkar, R.B. Mane, K.K.K. Sharma, B.D. Ajalkar, S.N. Tayade, J. Mater. Sci. Mater. Electron. 30, 13984 (2019)
R. Vivekananth, R.S. Babu, K. Prasanna, C.W. Lee, R.A. Kalaivani, J. Mater. Sci. Mater. Electron. 29, 6763 (2018)
N.H. Cho, J.E. Shaw, S. Karuranga, Y. Huang, J.D. da Rocha Fernandes, A.W. Ohlrogge, B. Malanda, Diabetes Res. Clin. Pract. 138, 271 (2018)
K. Ogurtsova, J.D. da Rocha Fernandes, Y. Huang, U. Linnenkamp, L. Guariguata, N.H. Cho, D. Cavan, J.E. Shaw, L.E. Makaroff, Diabetes Res. Clin. Pract. 128, 40 (2017)
C. Boss, E. Meurville, J.-M. Sallese, P. Ryser, Procedia Chem. 1, 313 (2009)
M. Shehab, S. Ebrahim, M. Soliman, J. Lumin. 184, 110 (2017)
S. Park, H. Boo, T.D. Chung, Anal. Chim. Acta 556, 46 (2006)
B.V. McCleary, J.W. De Vries, J.I. Rader, G. Cohen, L. Prosky, D.C. Mugford, M. Champ, K. Okuma, J. AOAC Int. 93, 221 (2010)
Y. Zou, L. He, K. Dou, S. Wang, P. Ke, A. Wang, RSC Adv. 4, 58349 (2014)
A.A. Saei, J.E.N. Dolatabadi, P. Najafi-Marandi, A. Abhari, M. de la Guardia, Trends Anal. Chem. 42, 216 (2013)
J. Wang, Chem. Rev. 108, 814 (2008)
C. Chen, Q. Xie, D. Yang, H. Xiao, Y. Fu, Y. Tan, S. Yao, RSC Adv. 3, 4473 (2013)
F. Chekin, S. Bagheri, S.B. Abd Hamid, Anal. Methods 4, 2423 (2012)
C. Shan, H. Yang, J. Song, D. Han, A. Ivaska, L. Niu, Anal. Chem. 81, 2378 (2009)
F. Shi, W. Zheng, W. Wang, F. Hou, B. Lei, Z. Sun, W. Sun, Biosens. Bioelectron. 64, 131 (2015)
S. Zhao, K. Zhang, Y. Sun, C. Sun, Bioelectrochemistry 69, 10 (2006)
O. Heyer, N. Hollmann, I. Klassen, S. Jodlauk, L. Bohatý, P. Becker, J.A. Mydosh, T. Lorenz, D. Khomskii, J. Phys. Condens. Matter 18, L471 (2006)
A. Tiwari, V. Singh, T.C. Nagaiah, J. Mater. Chem. A 6, 2681 (2018)
Y. Li, X. Han, T. Yi, Y. He, X. Li, J. Energy Chem. 31, 54 (2019)
T.-F. Yi, C.-L. Hao, C.-B. Yue, R.-S. Zhu, J. Shu, Synth. Met. 159, 1255 (2009)
S. Ratha, R.T. Khare, M.A. More, R. Thapa, D.J. Late, C.S. Rout, RSC Adv. 5, 5372 (2015)
F.X. Wang, S.Y. Xiao, Y.S. Zhu, Z. Chang, C.L. Hu, Y.P. Wu, R. Holze, J. Power Sour. 246, 19 (2014)
X. Chen, G. Wu, P. Jiang, W. Liu, D. Bao, Appl. Phys. Lett. 94, 33501 (2009)
K.K. Naik, A. Gangan, B. Chakraborty, C.S. Rout, Analyst 143, 571 (2018)
K.K. Naik, S. Kumar, C.S. Rout, RSC Adv. 5, 74585 (2015)
K.E. Sickafus, J.M. Wills, N.W. Grimes, J. Am. Ceram. Soc. 82, 3279 (1999)
V.K. Sharma, C.M. Sayes, B. Guo, S. Pillai, J.G. Parsons, C. Wang, B. Yan, X. Ma, Sci. Total Environ. 653, 1042 (2019)
M. Amina, T. Amna, M.S. Hassan, N.M. Al Musayeib, S.S.S. Al-Deyab, M.-S. Khil, Korean J. Chem. Eng. 33, 3169 (2016)
K.K. Naik, A.S. Gangan, A. Pathak, B. Chakraborty, S.K. Nayak, C.S. Rout, ChemistrySelect 2, 5707 (2017)
O.S. Ivanova, F.P. Zamborini, J. Am. Chem. Soc. 132, 70 (2010)
I. Dugdale, M. Fleischmann, W.F.K. Wynne-Jones, Electrochim. Acta 5, 229 (1961)
J.M.M. Droog, P.T. Alderliesten, G.A. Bootsma, J. Electroan. Chem. Interfacial Electrochem. 99, 173 (1979)
R.K. Srivastava, S. Srivastava, T.N. Narayanan, B.D. Mahlotra, R. Vajtai, P.M. Ajayan, A. Srivastava, ACS Nano 6, 168 (2012)
S.-H. Liao, S.-Y. Lu, S.-J. Bao, Y.-N. Yu, M.-Q. Wang, Anal. Chim. Acta 905, 72 (2016)
Z. Shahnavaz, F. Lorestani, W.P. Meng, Y. Alias, J. Solid State Electrochem. 19, 1223 (2015)
Y.-L.T. Ngo, L. Sui, W. Ahn, J.S. Chung, S.H. Hur, Nanoscale 9, 19318 (2017)
M. Sivakumar, R. Madhu, S.-M. Chen, V. Veeramani, A. Manikandan, W.H. Hung, N. Miyamoto, Y.-L. Chueh, J. Phys. Chem. C 120, 17024 (2016)
X. Wu, C. Bao, Q. Niu, W. Lu, Nanotechnology 30, 165501 (2019)
R.X. Zhang, P. Yang, Y.X. Zhang, Mater. Lett. 272, 127850 (2020)
Acknowledgements
Dr. Kusha Kumar Naik would like to thank Dr. Chandra Sekhar Rout, IIT Bhubaneswar, for providing Lab facility to carry out the experiments and characterizations of the synthesized material.
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Manisha, Naik, K.K. High electrocatalytic activity of Ag doped MnWO4 microflowers towards glucose molecules. J Mater Sci: Mater Electron 32, 15182–15189 (2021). https://doi.org/10.1007/s10854-021-06070-7
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DOI: https://doi.org/10.1007/s10854-021-06070-7