Abstract
Doping at the possible A or B site in the ABO3 perovskite can alter the structural, morphological and optical properties of the compounds. Perovskite alkaline earth stannate BaSnO3 doped with Fe resulted in BaSn1-xFexO3 compounds having different concentrations (x = 0.00, 0.01, 0.02, 0.03, 0.05 and 0.07) were prepared by solid-state method. The Rietveld analyzes were performed to determine the phase purity and the changes in structural parameters. Morphological analysis identifies the formation of hexagonal nanorods with doping. The non-linear optical property of the prepared samples shows optical power limiting behavior. Magnetic property signifies the existence of ferromagnetic order and EPR studies reveal the possible ferromagnetic ordering of Fe-doped samples. Dielectric loss decreases with Fe doping and has a gradual decrease in the higher frequency regime and has applications in high frequency devices.
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John, J., S, S., Pillai.S, S. et al. Effect of Fe doping on the structural, morphological, optical, magnetic and dielectric properties of BaSnO3. J Mater Sci: Mater Electron 32, 11763–11780 (2021). https://doi.org/10.1007/s10854-021-05806-9
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DOI: https://doi.org/10.1007/s10854-021-05806-9