Abstract
LiFePO4 thin films are grown by pulsed laser deposition technique in relation to deposition parameters. Different characterizations such as XRD, SEM, Raman, and electrochemical studies are undertaken on the prepared samples. Structural phase of the deposited thin film expresses the orthorhombic Pnma olivine. LiFePO4 thin films grown on Pyrex glass substrate have harsh surface with a few dispatches of grains, whereas the thin films deposited on ITO-coated glass substrate have demonstrated exceptionally fine and uniform particles without dispatches of grains. Raman peaks are situated at 1237.7 and 1416 cm−1. From the conductivity studies, the conductivity has been raised for the Pyrex glass up to 1.1 × 10−4 S cm−1 at 373 K, whereas in case of ITO-coated glass, the conductivity has been enhanced up to 1.6 × 10−4 S cm−1 at 373 K. The transmission spectra change CC from obscurity state to free state from 15 to 83% at around 39 cm2 C−1. CV of LiFePO4 thin film on ITO-coated glass substrate has exhibited the anodic and cathodic peaks at 3.2 and 3.19 V. These outcomes demonstrate that the determination of a suitable substrate is significant for creating the film terminal with the high rate limit, particularly in considering the utilization of microbatteries.
Similar content being viewed by others
References
A. Manikandan, M. Durka, M. Amutha Selvi, S. Arul Antony, J. Nanosci. Nanotechnol. 16(1), 448–456 (2016)
Y. Slimani, A. Baykal, M. Amir, N. Tashkandi, A. Manikandan, Ceram. Int. 44(13), 15995–16004 (2018)
A. Manikandan, R. Sridhar, S.A. Antony, S. Ramakrishna, J. Mol. Struct. 1076, 188–200 (2014)
A. Silambarasu, A. Manikandan, K. Balakrishnan, J. Supercond. Nov. Magn. 30(9), 2631–2640 (2017)
A. Manikandan, M. Durka, S. Arul Antony, Adv. Sci. Eng. 7(1), 33–36 (2015)
R. Bomila, S. Srinivasan, S. Gunasekaran, A. Manikandan, J. Supercond. Nov. Magn 31(3), 855–864 (2016)
A.T. Ravichandran, J. Srinivas, R. Karthick, A. Manikandan, A. Baykal, Ceram. Int. 44(11), 13247–13252 (2018)
S. Asiri, M. Sertkol, S. Guner, H. Gungunes, K.M. Batoo, T.A. Saleh, H. Sozeri, M.A. Almessiere, A. Manikandan, A. Baykal, Ceram. Int. 44(5), 5751–5759 (2018)
Y.J. Kim, H. Kim, B. Kim, D. Ahl, J.G. Lee, T. Kim, D. Son, J. Cho, Y. Kim, B. Park, Chem. Mater. 15, 1505–1507 (2003)
C. Julien, M.A. Camacho-Lopez, L. Escobar-Alarcón, E. Haro-Poniatowski, Mater. Chem. Phys. 68, 210–216 (2000)
S. Yu, W. Yang, L. Li, W. Zhang, Sol. Energy Mater. Sol. Cells 144, 652–656 (2016)
E. Priyadharshini, S. Suresh, S. Gunasekaran, S. Srinivasan, A. Manikandan, Phys B 569, 8–13 (2019)
M. Anandha Jothi, D. Vanitha, N. Nallamuthu, A. Manikandan, S. Asath Bahadur, Phys B 580(1), 411940 (2019)
E. Priyadharshini, S. Suresh, S. Srinivasan, A. Manikandan, Phys B 566, 17–22 (2019)
V. Parameswaran, N. Nallamuthu, P. Devendran, E.R. Nagarajan, A. Manikandan, Phys B 515, 89–98 (2017)
R. Liu, J. Chen, Z. Li, Q. Ding, A. Xiaoshuai, Y. Pan, Z. Zheng, M. Yang, D. Fu, Mater. 11, 2243–2251 (2018)
L. Chen, Z. Chen, S. Liu, H. Zhang, Q. Huang, Int. J. Electrochem. Sci. 13, 5413–5424 (2018)
H. Xia, S.B. Tang, L. Lu, J. Korean Phys. Soc. 51, 1055–1062 (2007)
S. Passerini, B. Scrosati, J. Electrochem. Soc. 141, 889–895 (1994)
M. Broussely, F. Perton, J. Labat, R.J. Staniewicz, A. Romero, J. Power Sources 217, 43–44 (1993)
F. Yu, J. Zhang, Y. Yang, G. Song, J. Power Sources 195, 6873–6878 (2010)
A. Qiu, Q. Zhang, H. Hu, J. Wang, J. Liu, Y. Xia, Y. Zeng, X. Wang, Z. Liu, Electrochim. Acta 123, 317–324 (2014)
K. Nakura, K. Ariyoshi, H. Yoshizawa, T. Ohzuku, J. Electrochem. Soc. 162, A622–A628 (2015)
N. Paul, J. Wandt, S. Seidlmayer, S. Schebesta, M.J. Mühlbauer, O. Dolotko, H.A. Gasteiger, R. Gilles, J. Power Sources 345, 85–96 (2017)
L. Gao, Z. Xu, S. Zhang, J. Xu, K. Tang, Solid State Ionics 305, 52–56 (2017)
D.P. Tran, H.I. Lu, C.K. Lin, Coatings 8, 212–227 (2018)
M. Boehme, C. Charton, Surf. Coat. Technol. 200, 932–935 (2005)
D.P. Tran, H.I. Lu, C.K. Lin, Surf. Coat. Technol. 283, 298–310 (2015)
J. Lee, M.A. Petruska, S. Sun, J. Phys. Chem. 118(22), 12017–12021 (2014)
J. Xie, N. Imanishi, T. Zhang, A. Hirano, Y. Takeda, O. Yamamoto, Electrochim. Acta 54, 4537–4631 (2009)
M. Köhler, F. Berkemeier, T. Gallasch, G. Schmitz, J. Power Sources 236, 61–67 (2013)
A. Yada, Y. Iriyama, S.K. Jeong, T. Abe, M. Inaba, Z. Ogumi, J. Power Sources 146, 559–564 (2005)
A. Khoobi, S. Mehdi Ghoreishi, B. Mohsen, M. Shaterian, M. Salavati-Niasari, Colloids Surf. B Biointerfaces 123, 648–656 (2014)
A. Khoobi, S.M. Ghoreishi, S. Masoum, M. Behpour, Bioelectrochem. 94, 100–107 (2013)
A. Khoobi, A. Mohammad Attaran, M. Yousof, M. Enhessari, J. Nanostructure Chem. 9, 29–37 (2019)
A. Salehabadi, M. Salavati-Niasari, T. Gholami, A. Khoobi, Int. J. Hydrogen Energ 43, 9713–9721 (2018)
S. Yang, P.Y. Zavalij, M.S. Whittingham, Electrochem. Commun. 3, 505–507 (2001)
F. Sauvage, E. Baudrin, L. Gengembre, J.M. Tarascon, Solid State Ionics 176, 1869–1876 (2005)
J. Sun, K. Tang, X. Yu, H. Li, X. Huang, Thin Solid Films 517, 2618–2622 (2009)
S.W. Song, R.P. Reade, R. Kostecki, K.A. Striebel, J. Electrochem. Soc. 153, A12–A19 (2006)
Z.G. Lu, M.F. Lo, C.Y. Chung, J. Phys. Chem. C 112, 7069–7075 (2008)
K. Tang, X. Yu, J. Sun, H. Li, X. Huang, Electrochim. Acta 56, 4869–4875 (2011)
Z.G. Lu, H. Cheng, M.F. Lo, C.Y. Chung, Adv. Funct. Mater. 17, 3885–3896 (2007)
J. Ma, Q.Z. Qin, J. Power Sources 148, 66–71 (2005)
A.J. Fisher, V.M. Hart Prieto, M. Saiful Islam, Chem. Mater. 20, 5907–5915 (2008)
N. Kuwata, R. Kumar, K. Toribami, T. Suzuki, T. Hattori, Solid State Ionics 177, 2827–2832 (2006)
H.C. Dinh, S.I. Mho, Y. Kang, I.H. Yeo, J. Power Sources 244, 189–195 (2013)
S. Novikova, S. Yaroslavtsev, V. Rusakov, A. Chekannikov, T. Kulova, A. Skundin, A. Yaroslavtsev, J. Power Sources 300, 444–452 (2015)
M. Chen, L. Shao, H. Yang, T. Ren, G. Du, Z. Yuan, Electrochim. Acta 167, 278–286 (2015)
J.Z. Li, S.Y. Wang, L.H. Wei, Z. Liu, Y.W. Tian, Int. J. Electrochem. Sci. 10, 6135–6145 (2015)
R. Chen, Y. Wu, X.Y. Kong, J. Power Sources 258, 246–252 (2014)
X. Zeng, Q. Liu, M. Chen, L. Leng, T. Shu, L. Du, H. Song, S. Liao, Electrochim. Acta 177, 277–282 (2015)
N. Yabuuchi, T. Ohzuku, J. Power Sources 146, 636–639 (2005)
C.L. Liao, K.Z. Fung, J. Power Sources 128, 263–269 (2004)
Acknowledgements
The author, Jaesool Shim, is thankful to the financial assistance supported by National Research Foundation of Korea (NRF) funded by the Korea government (2017R1A4A1015581, 2019R1F1A1060655 and 2018R1A2B6002849).
Funding
There are no funding sources for this article work.
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
Conflict of interest
The authors declare that there is no conflict of interest regarding the publication of this paper.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Koutavarapu, R., Shim, J. & Rao, M.C. Substrate effect on structural and electrochemical properties of LiFePO4 thin films grown by pulsed laser deposition. J Mater Sci: Mater Electron 31, 5040–5046 (2020). https://doi.org/10.1007/s10854-020-03037-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-020-03037-y