Skip to main content
SpringerLink
Log in

Effect of the occupation of Pb and Ti sites on the structural, microstructural and dielectric properties of Y-doped PbTiO3 samples

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Pb1−xYxTiO3 and PbYxTi1−xO3 (x = 0, 2, 5, 8 and 10%) samples were produced using the sol gel process, and their structural, microstructural and dielectric properties investigated. X-ray diffraction results show that a relatively low temperature of calcination of the undoped sample was sufficient to obtain the pure tetragonal structure without the presence of any secondary phases, and that Y3+ ions may occupy both Pb and Ti sites in the PbTiO3 matrix. As a result of doping with Y3+ ions into both Pb and Ti-sites, a strong reduction of the grain size of the undoped sample was revealed by Scanning Electron Microscopy analysis. Relatively high values of the dielectric permittivity were obtained under doping with Y into Ti-sites compared to those recorded under doping into Pb-sites as revealed by dielectric measurements. These values are higher in the case of low Y3+ content. Moreover, dielectric measurements showed that the samples approach their frequency resonance, the latter depending on the temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16
Fig. 17
Fig. 18
Fig. 19
Fig. 20
Fig. 21
Fig. 22
Fig. 23
Fig. 24
Fig. 25
Fig. 26
Fig. 27

Similar content being viewed by others

References

  1. T. Suwannasise, A. Safari, Effect of rare-earth additives on electromechanical properties of modified lead titanate ceramics. J. Am. Ceram. Soc. 76(12), 3155–3158 (1993)

    Article  Google Scholar 

  2. S. Ikegami, I. Udea, T. Nagata, Electromechanical properties of PbTiO3 ceramics containing La and Mn. J. Acoust. Soc. Am. 50, 1060–1066 (1971)

    Article  Google Scholar 

  3. T. Takahashi, Lead titanate ceramic with large piezoelectric anisotropy and their applications. Ceram. Bull. 69, 691–695 (1990)

    Google Scholar 

  4. E.C. Subbarao, J. Am. Ceram. Soc. 43, 119–122 (1960)

    Article  Google Scholar 

  5. T.-Y. Tien, W.G. Carlson, J. Am. Ceram. Soc. 45, 567–571 (1962)

    Article  Google Scholar 

  6. Y. Matsuo, H. Sasaki, J. Am. Ceram. Soc. 49, 229–230 (1966)

    Article  Google Scholar 

  7. I. Ueda, S. Ikegami, Japan J. Appl. Phys. 7, 236–242 (1968)

    Article  Google Scholar 

  8. K.M. Rittenmyer, R.Y. Ting, Piezoelectric and dielectric properties of calcium and samarium modified lead titanate ceramics for hydroacoustic applications. Ferroelectrics 110, 171–182 (1990)

    Article  Google Scholar 

  9. M.M. Nadoliisky, T.K. Vassileva, R.V. Yanchev, Pyroelectric and dielectric properties of modified lead titanate ceramics. Ferroelectrics 118, 111–115 (1991)

    Article  Google Scholar 

  10. K.K. Deb, Pyroelectric characteristics of (Pb0.9Sm0.1) TiO3 ceramics. Ferroelectrics 82, 45–53 (1988)

    Article  Google Scholar 

  11. M. Kobune, S. Fujii, K. Asada, Preparation of Mn-modified tetragonal PZT ceramics and theirpyroelectric properties. J. Ceram. Soc. Jpn. 104, 259–263 (1996)

    Article  Google Scholar 

  12. M.H. Lee, S.H. Bae, A.S. Bhalla, Thermal properties of a pyroelectric-ceramic infrared detector with metallic intermediate layer. Opt. Eng. 37, 1746–1753 (1998)

    Article  Google Scholar 

  13. M. Kellati, S. Sayouri, N. El Moudden, M. Elaatmani, A. Kaal, M. Taibi, Structural and dielectric properties of La-doped Lead titanate ceramics. Mater. Res. Bull. 39, 867–872 (2004)

    Article  Google Scholar 

  14. Y. Guaaybess, L. Zerhouni, E. El Moussafir, A. Laaraj, R. Adhiri, M. Moussetad, Effect of Ce and La substitution on dielectric properties of lead titanate ceramics. J. Mater. Environ. Sci. 6(12), 3491–3495 (2015)

    Google Scholar 

  15. R. Tickoo, R.P. Tandon, K.K. Bamzai, P.N. Kotru, Dielectric and piezoelectric characteristics of samarium modified lead titanate ceramics. Matter. Sci. Eng. B103, 145–151 (2003)

    Article  Google Scholar 

  16. B. Jaffe, W. Cook, H. Jaffe, Piezoelectric Ceramics (Academic Press, London, 1971)

    Google Scholar 

  17. H. Takeuchi, S. Jyomura, E. Yamamoto, Y. Ito, J.I. Acoust, Soc. Am. 72(4), 1114–1120 (1982)

    Google Scholar 

  18. D. Damjanovic, T.R. Gururaja, S.J. Jang, L.E. Cross, Temperature behavior of the complex piezoelectric d31 coefficient in modified lead titanate ceramics. Mater. Lett. 4(10), 414–419 (1986)

    Article  Google Scholar 

  19. V. Singh, K.K. Bamzai, S. Suri, Microstructural, thermal and dielectric characteristics of Yttrium modified Lead Titanate Ceramics. Integr. Ferroelectr. 116, 82–100 (2010)

    Article  Google Scholar 

  20. K. Singh, V. Singh, R. Gupta, K.K. Bamzai, Structural, dielectric, piezoelectric and ferroelectric behavior of rare earth double doped lead titanate ceramics synthesized by solid state method. J. Appl. Phys. (IOSR-JAP) 6(4), 8–14 (2014)

    Article  Google Scholar 

  21. K.R. Han, H.J. Koo, M.-J. Hong, C.S. Lin, J. Am. Soc. 83(4), 97 (2000)

    Google Scholar 

  22. Z. Cai, X. Xing, R. Yu, G. Liu, Q. Xing, J. Alloys Compd. 388(2), 303–313 (2005)

    Article  Google Scholar 

  23. A. Singh, V. Gupta, K. Sreenivas, R.S. Katiyar, Influence of Ca additives on the optical and dielectric studies of sol–gel derived PbTiO3 ceramics. J. Phys. Chem. Solids 68, 119–123 (2007)

    Article  Google Scholar 

  24. S. Mahboob, G. Prasad, G.S. Kumar, Simulation of dielectric and resonance and anti-resonance data using modified Lorentz equation (T and ω simultaneously) of relaxor ferroelectric and piezoelectric ceramics. Bull. Mater. Sci. 42, 56 (2019)

    Article  Google Scholar 

  25. T. Koschny, P. Markosˇ, D.R. Smith, C.M. Soukoulis, Resonant and antiresonant frequency dependence of the effective parameters of metamaterials. Phys. Rev. E 68, 065602(R) (2003)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. LPTA, Fac. Sci. DM, USMBA, BP 1796, Fès-Atlas, Fes, Morocco

    Mounir Belhajji, Salaheddine Sayouri & Aziz Nfissi

  2. LSSC, Fac. Sci & Tech., BP 2202, Fes, Morocco

    Taj-dine Lamcharfi

Authors
  1. Mounir Belhajji
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Salaheddine Sayouri
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Aziz Nfissi
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Taj-dine Lamcharfi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Salaheddine Sayouri.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Belhajji, M., Sayouri, S., Nfissi, A. et al. Effect of the occupation of Pb and Ti sites on the structural, microstructural and dielectric properties of Y-doped PbTiO3 samples. J Mater Sci: Mater Electron 30, 16065–16079 (2019). https://doi.org/10.1007/s10854-019-01977-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-019-01977-8

Search

Navigation