Abstract
Thickness and direct band gap are two important parameters affecting the photovoltaic performance of BiFeO3 (BFO)-based thin film. In this paper, thickness effects on the microstructure and insulating properties of BFO thin film are firstly explored. The minimum leakage current density (2.18 × 10− 5 A/cm2 at 200 kV/cm) of 200 nm thin film is obtained due to a well-crystallized polycrystalline structure with high densification. On the basis, FTO/TiO2/BFO and FTO/ZnO/BFO heterostructures are proposed and successfully prepared. It turns out that with the introduction of TiO2 and ZnO acting as electron transport layer, both heterostructures possess enhanced absorption intensity and exhibit a significant red-shift, which can be ascribed to the reduced direct band gap (Eg) of 2.66 and 2.63 eV, respectively. Particularly, ZnO/BFO possess enhanced photovoltaic with relatively large Voc, Jsc, FF and η values of 1.32 V, 3.63 mA/cm2, 0.59 and 2.86, respectively. Our results demonstrate that the introduction of electron transport layer tends to be an effective way in improving the photovoltaic performance of BFO-based films.
Similar content being viewed by others
References
H. Wang, H. Xu, C. Zeng, Y. Shen, Y.-H. Lin, C.-W. Nan, J. McKittrick, J. Am. Ceram. Soc. 99, 1133–1136 (2016)
Y. Sun, F. Guo, Q. Lu, S. Zhao, Ceram. Int. 44, 13994–13998 (2018)
H. Li, J. Zhu, Q. Wu, J. Zhuang, H. Guo, Z. Ma, Y. Ye, Ceram. Int. 43, 13063–13068 (2017)
R.M. Swanson, Photovoltaics Res. Appl. 14, 443–453 (2006)
A. Skoczek, T. Sample, E.D. Dunlop, Photovoltaics Res. Appl. 17, 227–240 (2009)
Y. Han, Y. Ma, C. Quan, N. Gao, Q. Zhang, W. Mao, J. Zhang, J. Yang, X.a. Li, W. Huang, Ceram. Int. 41, 2476–2483 (2015)
C. Nie, S. Zhao, Y. Bai, Q. Lu, Ceram. Int. 42, 14036–14040 (2016)
Z. Lin, W. Cai, W. Jiang, C. Fu, C. Li, Y. Song, Ceram. Int. 39, 8729–8736 (2013)
H.J. Feng, K. Yang, W. Deng, M. Li, M. Wang, B. Duan, F. Liu, J. Tian, X. Guo, Phys. Chem. Chem. Phys. 17, 26930–26936 (2015)
H. Mai, T. Lu, Q. Li, Q. Sun, K. Vu, H. Chen, G. Wang, M.G. Humphrey, F. Kremer, L. Li, R.L. Withers, Y. Liu, ACS Appl. Mat. Interfaces. 10, 29786–29794 (2018)
M. Chen, J. Ding, J. Qiu, N. Yuan, Mater. Lett. 139, 325–328 (2015)
S. Sharma, M. Tomar, A. Kumar, N.K. Puri, V. Gupta, J. Phys. Chem. Solids 93, 63–67 (2016)
F. Wu, Y. Guo, B. Guo, Y. Zhang, H. Li, H. Liu, J. Phys. D 46, 365304 (2013)
Q. Zhang, C.S. Dandeneau, X. Zhou, G. Cao, Adv. Mater. 21, 4087–4108 (2009)
B. Parida, A. Singh, M. Oh, M. Jeon, J.-W. Kang, H. Kim, Mater. Today Commun. 18, 176–183 (2019)
J. Song, J. Bian, E. Zheng, X.-F. Wang, W. Tian, T. Miyasaka, Chem. Lett. 44, 610–612 (2015)
R. Djamil, K. Aicha, A. Souifi, D. Fayçal, Thin Solid Films. 623, 1–7 (2017)
M. Wu, C. Zhang, S. Yu, L. Li, Ceram. Int. 44, 11466–11471 (2018)
P. Chen, P. Li, J. Zhai, B. Shen, F. Li, S. Wu, Ceram. Int. 43, 13371–13376 (2017)
M. Li, H. Sun, X. Liu, H. Sui, P. Liu, Mater. Lett. 219, 4–7 (2018)
H.-J. Feng, M. Wang, F. Liu, B. Duan, J. Tian, X. Guo, J. Alloys Compd. 628, 311–316 (2015)
G.E. Eperon, S.D. Stranks, C. Menelaou, M.B. Johnston, L.M. Herz, H.J. Snaith, Energy Environ. Sci. 7, 982–988 (2014)
S.Y. Yang, L.W. Martin, S.J. Byrnes, T.E. Conry, S.R. Basu, D. Paran, L. Reichertz, J. Ihlefeld, C. Adamo, A. Melville, Y.H. Chu, C.H. Yang, J.L. Musfeldt, D.G. Schlom, J.W. Ager, R. Ramesh, Appl. Phys. Lett. 95, 062909 (2009)
S.J. Roh, R.S. Mane, S.K. Min, W.J. Lee, C.D. Lokhande, S.H. Han, Appl. Phys. Lett. 89, 253512 (2006)
Y. Zhao, K. Zhu, J. Phys. Chem. Lett. 4, 2880–2884 (2013)
C.-H. Chiang, C.-G. Wu, Nat. Photon. 10, 196–200 (2016)
Acknowledgements
This work was supported by the National Natural Science Foundation of China (Grant Nos. U1806221, 51672198, 51272191), Innovation and Development Project of Zibo City (2017CX01A022), Instruction & Development Project for National Funding Innovation Demonstration Zone of Shandong Province (2016-181-11, 2017-41-1, 2017-41-3, 2018ZCQZB01), and Central Guiding Local Science and Technology Development Special Funds (Grant No. 2060503).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Ke, H., Sun, H.J., Liu, X.F. et al. Enhanced photovoltaic behavior of thickness-dependent BiFeO3-based heterostructures via the introduction of electron transport layers. J Mater Sci: Mater Electron 30, 8018–8023 (2019). https://doi.org/10.1007/s10854-019-01123-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-019-01123-4