Abstract
The novel few-layers MoS2 sensitized Ag–TiO2 were prepared through hydrothermal method, photoreduction method and spin-coating method, respectively. The microstructure, surface morphology, chemical composition and ultraviolet–visible absorbance of the samples were investigated systematically. The results indicated that the Ag nanoparticles and few-layers MoS2 were deposited successfully on the surface of TiO2 NRAs. The visible photocatalytic activity was estimated by degradation of methylene blue solution. The results indicated that the photocatalytic properties of MoS2/Ag–TiO2 was larger than pure TiO2 NRAs and Ag–TiO2. The significantly increased photocatalytic properties was attributed to the stronger visible light capture capability and the enhanced electron–hole pairs separation.
Similar content being viewed by others
References
A. Fujishima, K. Honda, Electrochemical photolysis of water at a semiconductor electrode. Nature 238, 37 (1972)
T. Ali, Y.M. Hunge, A. Venkatraman, UV assisted photoelectrocatalytic degradation of reactive red 152 dye using spray deposited TiO2 thin films. J. Mater. Sci. Mater. Electron. 29, 1209–1215 (2017)
Y.M. Hunge, A.A. Yadav, V.L. Mathe, Oxidative degradation of phthalic acid using TiO2 photocatalyst. J. Mater. Sci. Mater. Electron. 29, 6183–6187 (2018)
Y.-C. Pu, G. Wang, K.-D. Chang, Y. Ling, Y.-K. Lin, B.C. Fitzmorris, C.-M. Liu, X. Lu, Y. Tong, J.Z. Zhang, Y.-J. Hsu, Y. Li, Au nanostructure-decorated TiO2 nanowires exhibiting photoactivity across entire UV-visible region for photoelectrochemical water splitting. Nano Lett. 13, 3817–3823 (2013)
M. Ni, M.K.H. Leung, D.Y.C. Leung, K. Sumathy, A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production. Renew. Sustain. Energy Rev. 11, 401–425 (2007)
C. Liu, F. Shang, G. Pan, F. Wang, Z. Zhou, W. Gong, Z. Zi, Y. Wei, X. Chen, J. Lv, G. He, M. Zhang, X. Song, Z. Sun, Preparation and photocatalytic activity of MgxZn1–xO thin films on silicon substrate through sol-gel process. Appl. Surf. Sci. 305, 753–759 (2014)
W. Gong, G. Pan, F. Shang, F. Wang, Z. Zhou, C. Liu, M. Zhao, Z. Zi, Y. Wei, J. Lv, X. Chen, G. He, M. Zhang, X. Song, Z. Sun, Effect of ethylene glycol monomethyl ether ratio in mixed solvent on surface morphology, wettability and photocatalytic properties of ZnO thin films. J. Mater. Sci. Mater. Electron. 25, 2948–2956 (2014)
Y.M. Hunge, A.A. Yadav, V.L. Mathe, Ultrasound assisted synthesis of WO3-ZnO nanocomposites for brilliant blue dye degradation. Ultrason. Sonochem. 45, 116–122 (2018)
Y.M. Hunge, M.A. Mahadik, V.S. Mohite, S.S. Kumbhar, N.G. Deshpande, K.Y. Rajpure, A.V. Moholkar, P.S. Patil, C.H. Bhosale, Photoelectrocatalytic degradation of methyl blue using sprayed WO3 thin films. J. Mater. Sci. Mater. Electron. 27, 1629–1635 (2016)
Y.M. Hunge, A.A. Yadav, M.A. Mahadik, V.L. Mathe, C.H. Bhosale, A highly efficient visible-light responsive sprayed WO3/FTO photoanode for photoelectrocatalytic degradation of brilliant blue. J. Taiwan Inst. Chem. Eng. 85, 273–281 (2018)
Y.M. Hunge, A.A. Yadav, M.A. Mahadik, R.N. Bulakhe, J.J. Shim, V.L. Mathe, C.H. Bhosale, Degradation of organic dyes using spray deposited nanocrystalline stratified WO3/TiO2 photoelectrodes under sunlight illumination. Opt. Mater. 76, 260–270 (2018)
Z. Yin, Z. Wang, Y. Du, X. Qi, Y. Huang, C. Xue, H. Zhang, Full solution-processed synthesis of all metal oxide-based tree-like heterostructures on fluorine-doped tin oxide for water splitting. Adv. Mater. 24, 5374–5378 (2012)
T. Ohno, M. Akiyoshi, T. Umebayashi, K. Asai, T. Mitsui, M. Matsumura, Preparation of S-doped TiO2 photocatalysts and their photocatalytic activities under visible light. Appl. Catal. A Gen. 265, 115–121 (2004)
J. Wang, D.N. Tafen, J.P. Lewis, Z. Hong, A. Manivannan, M. Zhi, M. Li, N. Wu, Origin of photocatalytic activity of nitrogen-doped TiO2 nanobelts. J. Am. Chem. Soc. 131, 12290–12297 (2009)
J.G. Yu, J.F. Xiong, B. Cheng, S.W. Liu, Fabrication and characterization of Ag-TiO2 multiphase nanocomposite thin films with enhanced photocatalytic activity. Appl. Catal. B Environ. 60, 211–221 (2005)
H. Eom, J.-Y. Jung, Y. Shin, S. Kim, J.-H. Choi, E. Lee, J.-H. Jeong, I. Park, Strong localized surface plasmon resonance effects of Ag/TiO2 core-shell nanowire arrays in UV and visible light for photocatalytic activity. Nanoscale 6, 226–234 (2014)
Y. Yang, J. Wen, J. Wei, X. Rui, S. Jing, C. Pan, Polypyrrole-decorated Ag-TiO2 nanofibers exhibiting enhanced photocatalytic activity under visible-light illumination. ACS Appl. Mater. Interfaces 5, 6201 (2013)
J. Tao, Z. Gong, G. Yao, Y. Cheng, M. Zhang, J. Lv, S. Shi, G. He, X. Chen, Z. Sun, Enhanced photocatalytic and photoelectrochemical properties of TiO2 nanorod arrays sensitized with CdS nanoplates. Ceram. Int. 42, 11716–11723 (2016)
Y. Wang, W. Yang, X. Chen, J. Wang, Y. Zhu, Photocatalytic activity enhancement of core-shell structure g-C3N4@TiO2 via controlled ultrathin g-C3N4 layer. Appl. Catal. B Environ. 220, 337–347 (2018)
A. Ali, W.-C. Oh, Synthesis of Ag2Se-graphene-TiO2 nanocomposite and analysis of photocatalytic activity of CO2 reduction to CH3OH. Bull. Mater. Sci. 40, 1319–1328 (2017)
X.-B. Xiang, Y. Yu, W. Wen, J.-M. Wu, Construction of hierarchical Ag@TiO2@ZnO nanowires with high photocatalytic activity. New J. Chem. 42, 265–271 (2018)
C. Ma, X. Wang, H. Luo, D. Zhang, Synthesis of Ag/TiO2 core-shell nanowires with enhanced stability of photocatalytic activity. J. Mater. Sci. Mater. Electron. 28, 10715–10719 (2017)
X. Liu, L. Chen, Q. Liu, J. He, K. Li, W. Yu, J.-P. Ao, K.-W. Ang, Band alignment of atomic layer deposited TiO2/multilayer MoS2 interface determined by X-ray photoelectron spectroscopy. J. Alloys Compd. 698, 141–146 (2017)
Q. Xiang, J. Yu, M. Jaroniec, Synergetic effect of MoS2 and graphene as cocatalysts for enhanced photocatalytic H2 production activity of TiO2 nanoparticles. J. Am. Chem. Soc. 134, 6575–6578 (2012)
F. Zhao, Y. Rong, J. Wan, Z. Hu, Z. Peng, B. Wang, MoS2 quantum dots@TiO2 nanotube composites with enhanced photoexcited charge separation and high-efficiency visible-light driven photocatalysis. Nanotechnology 29, 105403 (2018)
L. Zheng, S. Han, H. Liu, P. Yu, X. Fang, Hierarchical MoS2 nanosheet@TiO2 nanotube array composites with enhanced photocatalytic and photocurrent performances. Small 12, 1527–1536 (2016)
W. Zhou, Z. Yin, Y. Du, X. Huang, Z. Zeng, Z. Fan, H. Liu, J. Wang, H. Zhang, Synthesis of few-layer MoS2 nanosheet-coated TiO2 nanobelt heterostructures for enhanced photocatalytic activities. Small 9, 140–147 (2013)
F. Xu, Y. Yuan, D. Wu, M. Zhao, Z. Gao, K. Jiang, Synthesis of ZnO/Ag/graphene composite and its enhanced photocatalytic efficiency. Mater. Res. Bull. 48, 2066–2070 (2013)
Y. Sun, H. Lin, C. Wang, Q. Wu, X. Wang, M. Yang, Morphology-controlled synthesis of TiO2/MoS2 nanocomposites with enhanced visible-light photocatalytic activity. Inorg. Chem. Front. 5, 145–152 (2018)
F. Ye, H. Li, H. Yu, S. Chen, X. Quan, Hydrothermal fabrication of few-layer MoS2 nanosheets within nanopores on TiO2 derived from MIL-125(Ti) for efficient photocatalytic H2 evolution. Appl. Surf. Sci. 426, 177–184 (2017)
Y.M. Liang, N. Guo, L.L. Li, R.Q. Li, G.J. Ji, S.C. Gan, Facile synthesis of Ag/ZnO micro-flowers and their improved ultraviolet and visible light photocatalytic activity. N. J. Chem. 40, 1587–1594 (2016)
J. Zhao, P. Zhang, J. Fan, J. Hu, G. Shao, Constructing 2D layered MoS2 nanosheets-modified Z-scheme TiO2/WO3 nanofibers ternary nanojunction with enhanced photocatalytic activity. Appl. Surf. Sci. 430, 466–474 (2018)
C.D. Gu, C. Cheng, H.Y. Huang, T.L. Wong, N. Wang, T.Y. Zhang, Growth and photocatalytic activity of dendrite-like ZnO@Ag heterostructure nanocrystals. Cryst. Growth Des. 9, 3278–3285 (2009)
Y. Zheng, L. Zheng, Y. Zhan, X. Lin, Q. Zheng, K. Wei, Ag/ZnO heterostructure nanocrystals: synthesis, characterization, and photocatalysis. Inorg. Chem. 46, 6980–6986 (2007)
W. Teng, Y. Wang, H.H. Huang, X. Li, Y. Tang, Enhanced photoelectrochemical performance of MoS2 nanobelts-loaded TiO2 nanotube arrays by photo-assisted electrodeposition. Appl. Surf. Sci. 425, 507–517 (2017)
J. Lv, W. Gong, K. Huang, J. Zhu, F. Meng, Effect of annealing temperature on photocatalytic activity of ZnO thin films prepared by sol–gel method. Superlatt. Microstruct. 50, 98–106 (2011)
Z. Zhou, F. Shang, G. Pan, F. Wang, C. Liu, W. Gong, Z. Zi, Y. Wei, J. Lv, X. Chen, Enhanced photocatalytic activity of Mg0.05 Zn0.95O thin films prepared by sol–gel method through a cycle. J. Mater. Sci. Mater. Electron. 25, 2053–2059 (2014)
Y.X. Lei, J.P. Zhou, Q.U. Hassan, J.Z. Wang, One-step synthesis of NiTe2 nanorods coated with few-layers MoS2 for enhancing photocatalytic activity. Nanotechnology 28, 495602 (2017)
Acknowledgements
This work was supported by National Natural Science Foundation of China (Nos. 51701001, 51102072, 51472003, 51572002), Natural Science Foundation of Anhui Higher Education Institution of China (Nos. KJ2015ZD32, KJ2017A924, KJ2017A002), Doctor Scientific Research Fund of Anhui University (No. J01001927), Youth Core Teacher Fund of Anhui University (No. J01005111) and Foundation of Co-operative Innovation Research Center for Weak Signal-Detecting Materials and Devices Integration Anhui University (Nos. Y01008411, WRXH201703).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Lv, J., Miao, R., Zhang, M. et al. Few-layers MoS2 sensitized Ag–TiO2 nanocomposite thin film for enhancing photocatalytic activity. J Mater Sci: Mater Electron 29, 16282–16288 (2018). https://doi.org/10.1007/s10854-018-9717-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-018-9717-5