Abstract
The MoS2/Ag/AgBr composite with ultrathin-MoS2 layers was prepared by the methods of ultrasonic liquid exfoliation and ion exchange. The composition and micromorphology of ultrathin-MoS2/Ag/AgBr were detected by XRD, EDS, SEM and TEM in detail. The element mapping showed that the samples were well-distributed. The MoS2 in samples and the number of plies were detected by Raman spectra specifically. The results indicated that the photocatalytic performance of the as-prepared samples would increase by 50% when the average thickness of MoS2 was about 4 nm. The enhanced photocatalytic performance of ultrathin-MoS2/Ag/AgBr composite is attributed to the modified conduction band of MoS2 by reducing the layers of MoS2 to fit the potential of O2/O·−2. In particular, this work would expand the scope of application of MoS2 in photodegradation.
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References
Zang Y, Farnood R (2008) Photocatalytic activity of AgBr/TiO2 in water under simulated sunlight irradiation. Appl Catal B Environ 79:334–340
Gou W, Wu P, Jiang D, Ma X (2015) Synthesis of AgBr@Bi2O3 composite with enhanced photocatalytic performance under visible light. J Alloy Compd 646:437–455
Wang P, Huang B, Zhang X, Qin X, Jin H, Dai Y, Wang Z, Wei J, Zhan J, Wang S, Wang J, Whangbo M (2009) Highly efficient visible-light plasmonic photocatalyst Ag@AgBr. Chem Eur J 15:1821–1824
Wang P, Huang B, Qin X, Zhang X, Dai Y, Wei J, Whangbo M (2008) Ag@AgCl: a highly efficient and stable photocatalyst active under visible light. Angew Chem Int Ed 47:7931–7933
Jiang J, Li H, Zhang L (2012) New insight into daylight photocatalysis of AgBr@Ag: synergistic effect between semiconductor photocatalysis and plasmonic photocatalysis. Chem Eur J 18:6360–6369
Dai K, Lu L, Dong J, Ji Z, Zhu G, Liu Q, Liu Z, Zhang Y, Li D, Liang C (2013) Facile synthesis of a surface plasmon resonance-enhanced Ag/AgBr heterostructure and its photocatalytic performance with 450 nm LED illumination. Dalton Trans 42:4657–4662
Yang Y, Guo W, Guo Y, Zhao Y, Yuan X, Guo Y (2014) Fabrication of Z-scheme plasmonic photocatalyst Ag@AgBr/g-C3N4 with enhanced visible-light photocatalytic activity. J Hazard Mater 271:150–159
Wen X, Niu C, Zhang L, Liang C, Guo H, Zeng G (2018) Photocatalytic degradation of ciprofloxacin by a novel Z-scheme CeO2–Ag/AgBr photocatalyst: influencing factors, possible degradation pathways, and mechanism insight. J Catal 358:141–154
Huang X, Zeng Z, Zhang H (2013) Metal dichalcogenide nanosheets: preparation, properties and applications. Chem Soc Rev 42:1934–1946
Venkata Subbaiah Y, Saji K, Tiwari A (2016) Atomically thin MoS2: a versatile nongraphene 2D material. Adv Funct Mater 26:2046–2069
Ganatra R, Zhang Q (2014) Few-Layer MoS2: a promising layered semiconductor. ACS Nano 8:4074–4099
Xiang Q, Yu J, Jaroniec M (2012) Synergetic effect of MoS2 and graphene as cocatalysts for enhanced photocatalytic H2 production activity of TiO2 nanoparticles. J Am Chem Soc 134:6575–6578
Han B, Liu S, Zhang N, Xua Y, Tang Z (2017) One-dimensional CdS@MoS2 core–shell nanowires for boosted photocatalytic hydrogen evolution under visible light. Appl Catal B Environ 202:298–304
Chang K, Hai X, Pang H, Zhang H, Shi L, Liu G, Liu H, Zhao G, Li M, Ye J (2016) Targeted synthesis of 2H- and 1T-phase MoS2 monolayers for catalytic hydrogen evolution. Adv Mater 28:10033–10041
Kanhere P, Chen Z (2014) A review on visible light active provskite-based photocatalysts. Molecules 19:19995–20022
Tong H, Ouyang S, Bi Y, Umezawa N, Oshikiri M, Ye J (2012) Nano-photocatalytic materials: possibilities and challenges. Adv Mater 24:229–251
Mak K, Lee C, Hone J, Shan J, Heinz T (2010) Atomically thin MoS2: a new direct-gap semiconductor. Phys Rev Lett 105:136805. https://doi.org/10.1103/PhysRevLett.105.136805
Qi Y, Zheng Y, Yin H, Song X (2017) Enhanced visible light photocatalytic activity of AgBr on 001 facets exposed to BiOCl. J Alloy Compd 712:535–542
Zhou K, Mao N, Wang H, Peng Y, Zhang H (2011) A mixed-solvent strategy for efficient exfoliation of inorganic graphene analogues. Angew Chem Int Ed 50:10839–10842
Wang K, Wang J, Fan J, Lotya M, O’Neill A, Fox D, Feng Y, Zhang X, Jiang B, Zhao Q, Zhang H, Coleman J, Zhang L, Blau W (2013) Ultrafast saturable absorption of two-dimensional MoS2 nanosheets. ACS Nano 7:9260–9267
Lee C, Yan H, Brus L, Heinz T, Hone J, Ryu S (2010) Anomalous lattice vibrations of single and few-layer MoS2. ACS Nano 4:2695–2700
Hwang D, Suh D (2017) Evolution of a high local strain in rolling up MoS2 sheets decorated with Ag and Au nanoparticles for surface-enhanced Raman scattering. Nanotechnology 28:025603. https://doi.org/10.1088/1361-6528/28/2/025603
Che H, Chen J, Huang K, Hu W, Hu H, Liu X, Che G, Liu C, Shi W (2016) Construction of SrTiO3/Bi2O3 heterojunction towards to improved separation efficiency of charge carriers and photocatalytic activity under visible light. J Alloy Compd 688:882–890
Zhang Y, Park M, Kim H, Park S (2016) In-situ synthesis of graphene oxide/BiOCl heterostructured nanofibers for visible-light photocatalytic investigation. J Alloy Compd 686:106–114
Ye L, Liu J, Gong C, Tian L, Peng T, Zan L (2012) Two different roles of metallic Ag on Ag/AgX/BiOX (X = Cl, Br) visible light photocatalysts: surface plasmon resonance and Z-scheme bridge. ACS Catal 2:1677–1683
Kowalska E, Mahaney O, Abe R, Ohtani B (2010) Visible-light-induced photocatalysis through surface plasmon excitation of gold on titania surfaces. Phys Chem Chem Phys 12:2344–2355
Kamimura S, Miyazaki T, Zhang M, Li Y, Tsubota T, Ohno T (2016) (Au@Ag)@Au double shell nanoparticles loaded on rutile TiO2 for photocatalytic decomposition of 2-propanol under visible light irradiation. Appl Catal B Environ 180:255–262
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This work was supported by the National Natural Science Foundation of China (11674336, 51522105 and 11374312).
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Zhang, F., Yin, Y., Li, F. et al. Fabrication of ultrathin-MoS2/Ag/AgBr composite with enhanced photocatalytic activity. J Mater Sci 55, 2166–2175 (2020). https://doi.org/10.1007/s10853-019-04089-0
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DOI: https://doi.org/10.1007/s10853-019-04089-0