Skip to main content

Advertisement

SpringerLink
Log in

Promoted supercapacitive performances of electrochemically synthesized poly(3,4-ethylenedioxythiophene) incorporated with manganese dioxide

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

A facile electrochemical codeposition method was developed to prepare the manganese dioxide/poly(3,4-ethylenedioxythiophene) (PEDOT) composite electrodes for supercapacitor applications. Electrode characterizations include Fourier transform infrared spectroscopy, X-ray diffraction, and energy dispersive X-ray spectroscopy, indicating that the MnO2/PEDOT composite is prepared successfully. Electrochemical tests manifest that MnO2/PEDOT composite electrodes have better electrochemical properties than individual MnO2 and PEDOT electrodes. The as-prepared MnO2/PEDOT composite achieves a high areal specific capacitance of 89.7 mF cm−2 at 10 mV s−1, as well as superior rate capability and cycle stability (maintaining 97.1% of initial capacitance for 5000 cycles). The composite we have developed also exhibits superior supercapacitive performances relative to other conducting polymers reported previously, including PEDOT based composite electrodes. These properties of MnO2/PEDOT composite are closely related to the porous microstructures formed and the synergic effect between the two components. The present MnO2/PEDOT based organic–inorganic hybrid materials are very promising for supercapacitor applications.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. X. Peng, H.L. Liu, Q. Yin, J.C. Wu, P.Z. Chen, G.Z. Zhang, G.M. Liu, C.Z. Wu, Y. Xie, Nat. Commun. 7, 11782 (2016)

    Article  Google Scholar 

  2. C. Xu, Z.H. Li, C. Yang, P.C. Zou, B.H. Xie, Z.Y. Lin, Z.X. Zhang, B.H. Li, F.Y. Kang, C.P. Wong, Adv. Mater. 28, 4105–4110 (2016)

    Article  Google Scholar 

  3. J. Yang, C. Yu, X.M. Fan, S.X. Liang, S.F. Li, H.W. Huang, Z. Ling, C. Hao, J.S. Qiu, Energy Environ. Sci. 9, 1299–1307 (2016)

    Article  Google Scholar 

  4. M. Caglar, A. Arslan, R. Kilic, E. Hur, Synth. Met. 206, 8–14 (2015)

    Article  Google Scholar 

  5. Y. Chen, Z.L. Zhang, Z.J. Sui, Z.T. Liu, J.H. Zhou, X.G. Zhou, Int. J. Hydrog. Energy 41, 12136–12145 (2016)

    Article  Google Scholar 

  6. Q.Y. Lv, S. Wang, H.Y. Sun, J. Luo, J. Xiao, J.W. Xiao, F. Xiao, S. Wang, Nano Lett. 16, 40–47 (2016)

    Article  Google Scholar 

  7. P.S. Yang, L. Ma, M.Y. Gan, Y. Lei, X.L. Zhang, M. Jin, G. Fu, J. Mater. Sci. Mater. Electron. 28, 7333–7342 (2017)

    Article  Google Scholar 

  8. Y.C. Zhao, C.A. Wang, Mater. Des. 97, 512–518 (2016)

    Article  Google Scholar 

  9. Z.H. Li, M.F. Shao, L. Zhou, R.K. Zhang, C. Zhang, J.B. Han, M. Wei, D.G. Evans, X. Duan, Nano Energy 20, 294–304 (2016)

    Article  Google Scholar 

  10. E.G. Tolstopjatova, S.N. Eliseeva, A.O. Nizhegorodova, V.V. Kondratiev, Electrochim. Acta 173, 40–49 (2015)

    Article  Google Scholar 

  11. Z.P. Bai, H.J. Li, M.J. Li, C.P. Li, X.F. Wang, C.Q. Qu, B.H. Yang, Int. J. Hydrog. Energy 40, 16306–16315 (2015)

    Article  Google Scholar 

  12. B. Ke, J.X. Wang, D.R. Li, S.Q. Zhao, L.J. Luo, L. Yu, S. Hussain, J. Mater. Sci. Mater. Electron. 28, 418–425 (2017)

    Article  Google Scholar 

  13. S.X. Deng, D. Sun, C.H. Wu, H. Wang, J.B. Liu, Y.X. Sun, H. Yan, Electrochim. Acta 111, 707–712 (2013)

    Article  Google Scholar 

  14. Y.J. Li, G.L. Wang, K. Ye, K. Cheng, Y. Pan, P. Yan, J.L. Yin, D.X. Cao, J. Power Sources 271, 582–588 (2014)

    Article  Google Scholar 

  15. G.A. Snook, P. Kao, A.S. Best, J. Power Sources 196, 1–12 (2011)

    Article  Google Scholar 

  16. P.Y. Tang, Y.Q. Zhao, C.L. Xu, Electrochim. Acta 89, 300–309 (2013)

    Article  Google Scholar 

  17. X. Hu, W. Xiong, W. Wang, S.L. Qin, H.Y. Cheng, Y. Zeng, B. Wang, Z.H. Zhu, ACS Sustain. Chem. Eng. 4, 1201–1211 (2016)

    Article  Google Scholar 

  18. R. Liu, S.B. Lee, J. Am. Chem. Soc. 130, 2942–2943 (2008)

    Article  Google Scholar 

  19. P.T. Sen, A. De, A.D. Chowdhury, S.K. Bandyopadhyay, N. Agnihotri, M. Mukherjee, Electrochim. Acta 108, 265–273 (2013)

    Article  Google Scholar 

  20. K.H. Kim, J.Y. Kim, K.B. Kim, J. Electroceram 29, 149–154 (2012)

    Article  Google Scholar 

  21. Y.J. Yang, W.T. Yuan, S.B. Li, X.J. Yang, J.H. Xu, Y.D. Jiang, Electrochim. Acta 165, 323–329 (2015)

    Article  Google Scholar 

  22. J.P. Liu, J. Jiang, M. Bosman, H.J. Fan, J. Mater. Chem. 22, 2419–2426 (2012)

    Article  Google Scholar 

  23. Y.Y. Horng, Y.C. Lu, Y.K. Hsu, C.C. Chen, L.C. Chen, K.H. Chen, J. Power Sources 195, 4418–4422 (2010)

    Article  Google Scholar 

  24. T. Gao, M. Glerup, F. Krumeich, R. Nesper, H. Fjellvag, P. Norby, J. Phys. Chem. C 112, 13134–13140 (2008)

    Article  Google Scholar 

  25. H.G. Wang, Z.G. Lu, D. Qian, Y.J. Li, W. Zhang, Nanotechnology 18, 115616 (2007)

    Article  Google Scholar 

  26. Y.Q. Han, B. Ding, H. Tong, X.G. Zhang, J. Appl. Polym. Sci. 121, 892–898 (2011)

    Article  Google Scholar 

  27. H.J. Shin, S.S. Jeon, S.S. Im, Synth. Met. 161, 1284–1288 (2011)

    Article  Google Scholar 

  28. L. Chen, C.Z. Yuan, H. Dou, B. Gao, S.Y. Chen, X.G. Zhang, Electrochim. Acta 54, 2335–2341 (2009)

    Article  Google Scholar 

  29. Z. Zhang, X. Zhao, J. Li, ChemNanoMat 2, 196–200 (2016)

    Article  Google Scholar 

  30. Y.Q. Zhao, D.D. Zhao, P.Y. Tang, Y.M. Wang, C.L. Xu, H.L. Li, Mater. Lett. 76, 127–130 (2012)

    Article  Google Scholar 

  31. G.P. Pandey, A.C. Rastogi, Electrochim. Acta 87, 158–168 (2013)

    Article  Google Scholar 

  32. V. Khomenko, E. Frackowiak, F. Béguin, Electrochim. Acta 50, 2499–2506 (2005)

    Article  Google Scholar 

  33. M.H. Yu, Y.X. Zeng, C. Zhang, X.H. Lu, C.H. Zeng, C.Z. Yao, Y.Y. Yang, Y.X. Tong, Nanoscale 5, 10806–10810 (2013)

    Article  Google Scholar 

  34. H.H. Zhou, H.J. Zhai, G.Y. Han, J. Mater. Sci. Mater. Electron. 27, 2773–2782 (2016)

    Article  Google Scholar 

  35. M. Jin, Y.Y. Liu, Y.L. Li, Y.Z. Chang, D.Y. Fu, H. Zhao, G.Y. Han, J. Appl. Polym. Sci. 122, 3415–3422 (2011)

    Article  Google Scholar 

  36. Q.Q. Zhou, Y.R. Li, L. Huang, C. Li, G.Q. Shi, J. Mater. Chem. A 2, 17489–17494 (2014)

    Article  Google Scholar 

  37. M. Szkoda, K. Trzciński, J. Rysz, M. Gazda, K. Siuzdak, A. Lisowska-Oleksiak, Solid State Ionics 302, 197–201 (2017)

    Article  Google Scholar 

  38. H.G. Wei, J.H. Zhu, S.J. Wu, S.Y. Wei, Z.H. Guo, Polymer 54, 1820–1831 (2013)

    Article  Google Scholar 

  39. C. Peng, J. Jin, G.Z. Chen, Electrochim. Acta 53, 525–537 (2007)

    Article  Google Scholar 

  40. H.Y. Mi, X.G. Zhang, X.G. Ye, S.D. Yang, J. Power Sources 176, 403–409 (2008)

    Article  Google Scholar 

  41. Y. Song, J.L. Xu, X.X. Liu, J. Power Sources 249, 48–58 (2014)

    Article  Google Scholar 

  42. J. Yan, E. Khoo, A. Sumboja, P.S. Lee, ACS Nano 4, 4247–4255 (2010)

    Article  Google Scholar 

  43. W.Y. Li, J.N. Xu, Y.S. Pan, L. An, K.B. Xu, G.J. Wang, Z.S. Yu, L. Yu, J.Q. Hu, Appl. Surf. Sci. 357, 1747–1752 (2015)

    Article  Google Scholar 

  44. W.F. Wei, X.W. Cui, W.X. Chen, D.G. Ivey, Chem. Soc. Rev. 40, 1697–1721 (2011)

    Article  Google Scholar 

  45. H.H. Zhou, G.Y. Han, Y.Z. Chang, D.Y. Fu, Y.M. Xiao, J. Power Sources 274, 229–236 (2015)

    Article  Google Scholar 

  46. H.H. Zhou, G.Y. Han, D.Y. Fu, Y.Z. Chang, Y.M. Xiao, H.J. Zhai, J. Power Sources 272, 203–210 (2014)

    Article  Google Scholar 

  47. H.H. Zhou, G.Y. Han, Electrochim. Acta 192, 448–455 (2016)

    Article  Google Scholar 

  48. H.G. Wei, Y.R. Wang, J. Guo, X.R. Yan, R. O’Connor, X. Zhang, N.Z. Shen, B.L. Weeks, X.H. Huang, S.Y. Wei, Z.H. Guo, ChemElectroChem 2, 119–126 (2015)

    Article  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (21601113 and 21573138), the Natural Science Foundation of Shanxi Province (2015021079), the China Postdoctoral Science Foundation (2015M571283), the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi (2017112), and the Sanjin Scholar Distinguished Professors Program.

Author information

Authors and Affiliations

  1. Institute of Molecular Science, Key Laboratory of Materials for Energy Conversion and Storage of Shanxi Province, Key Laboratory of Chemical Biology and Molecular Engineering of Education Ministry, Shanxi University, Taiyuan, 030006, China

    Haihan Zhou, Xiaomin Zhi & Hua-Jin Zhai

Authors
  1. Haihan Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Xiaomin Zhi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Hua-Jin Zhai
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Haihan Zhou or Hua-Jin Zhai.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhou, H., Zhi, X. & Zhai, HJ. Promoted supercapacitive performances of electrochemically synthesized poly(3,4-ethylenedioxythiophene) incorporated with manganese dioxide. J Mater Sci: Mater Electron 29, 3935–3942 (2018). https://doi.org/10.1007/s10854-017-8333-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-017-8333-0

Search

Navigation