Abstract
In the current study, a novel and highly sensitive gas sensing material for the detection of NO gas was reported. Copper doped zinc oxide nanostructures (Zn1−xCuxO, where x = 0.25 steps) were grown as a semiconducting sensor material by using Successive Ionic Layer Adsorption and Reaction (SILAR) method. The structural, morphological and optical properties of nanostructures were investigated by X-Ray Diffractometer (XRD), Scanning Electron Microscope (SEM) and UV–visible spectrometer. NO gas sensing measurements were carried out as a function of temperature and gas concentrations. The sensors exhibited acceptable responses towards 50 ppb NO gas at operating temperature of 55 °C. The sensors were optimized and the maximum response of 8% was obtained for the Zn0.75Cu0.25O sensor. To increase sensor selectivity, zeolite A (LTA) microporous film, used as a filter, was coated on the optimized Zn0.75Cu0.25O sensor by using secondary growth method. zeolite A coated Zn0.75Cu0.25O sensor exhibited both high selectivity and high response towards NO gas. The detection limit of the zeolite coated Zn0.75Cu0.25O sensor was shifted to 20 ppb for NO gas at operating temperature of 25 °C.
Similar content being viewed by others
References
A. Mirzaei, S. Park, H. Kheel, G.-J. Sun, S. Lee, C. Lee, Ceram. Intern. 42(5), 6187–6197 (2016)
Y. Li, D. Deng, X. Xing, N. Chen, X. Liu, X. Xiao, Y. Wang, Sens. Actuators 237, 133–141 (2016)
E. Comini, Mater. Today 19(10), 559–567 (2016)
Y. Li, J.-C. Liu, X.-X. Lian, T. Lü, F.-X. Zhao, Trans. Nonferrous Met. Soc. China 25, 3657–3663 (2015)
M. Hjiri, L. El Mir, S.G. Leonardi, A. Pistone, L. Mavilia, G. Neri, Sens. Actuators B 196, 413–420 (2014)
H. Gómez-Pozos, E.J.L. Arredondo, A.M. Álvarez, R. Biswal, Y. Kudriavtsev, J.V. Pérez, Y.L. Casallas-Moreno, M.L.O. Amador, Materials 9, 87 (2016). doi:10.3390/ma9020087
L. Chow, O. Lupan, G. Chai, H. Khallaf, L.K. Ono, B.R. Cuenya, I.M. Tiginyanu, V.V. Ursaki, V. Sonte, A. Schulte, Sens. Actuators A 189, 399–408 (2013)
X. Liu, S. Cheng, H. Liu, S. Hu, D. Zhang, H. Ning, Sensors 12, 9635–9665 (2012)
J.N. Zemel, Thin Solid Films 163, 189–202 (1988)
C.O. Park, S.A. Akbar, J. Hwang, Mater. Chem. Phys. 75, 56–60 (2002)
M. Vilaseca, J. Coronas, A. Cirera, A. Cornet, J.R. Morante, J. Santamaria, Sens. Actuators B 124, 99–110 (2007)
D.J. Wales, J. Grand, V.P. Ting, R.D. Burke, K.J. Edler, C.R. Bowen, S. Mintova, A.D. Burrows, Chem. Soc. Rev. 44, 4290–4321 (2015)
G. Zhang, M. Liu, Sens. Actuator B 69, 144–152 (2000)
S. Shinohara, Y. Chiyomaru, F. Sassa, C. Liu, K. Hayashi, Sensors 16, 5–10 (2016)
P.T. Hernandez, S.M.V. Hailes, I.P. Parkin, Sens. Actuators 242, 1281–1295 (2017)
S.N. Talapaneni, J. Grand, S. Thomas, H.A. Ahmed, S. Mintova, Mater. Des. 99, 574–580 (2016)
M.M. Momeni, A.A. Mozafari, J. Mater. Sci. Mater. Electron. 27(10), 10658–10666 (2016)
H.D. Dhaygude, S.K. Shinde, N.B. Velhal, M.V. Takale, V.J. Fulari, Mater. Res. Expr. 3, 086402 (2016)
T. Çorlu, I. Karaduman, M.A. Yildirim, A. Ateş, S. Acar, J. Electron. Mater. 46(7), 3995–4002 (2017)
S. Mintova, S. Mo, T. Bein, Chem. Mater. 13, 901–905 (2001)
I. Karaduman, O. Barin, D.E. Yıldız, S. Acar, J. Appl. Phys. 118, 174501 (2015)
I. Karaduman, E. Er, H. Çelikkan, N. Erk, S. Acar, J. Alloy. Compd. 722, 569–578 (2017)
M.A. Yıldırım, S.T. Yıldırım, A. Ateş, J. Alloys Compd. 701, 37–42 (2017)
Y. Caglar, D.D. Oral, M. Caglar, S. Ilican, M.A. Thomas, K. Wu, Z. Sun, J. Cui, Thin Solid Films 520, 6642–6647 (2012)
N.L. Tarwal, A.R. Patil, N.S. Harale, A.V. Rajgure, S.S. Suryavanshi, W.R. Bae, P.S. Patil, J.H. Kim, J.H. Jang, J. Alloys Compd. 598, 282–288 (2014)
Z. Zhang, J.B. Yi, J. Ding, L.M. Wong, H.L. Seng, S.J. Wang, J.G. Tao, G.P. Li, G.Z. Xing, T.C. Sum, C.H. Alfred Huan, T. Wu, J. Phys. Chem. C 112, 9579–9585 (2008)
Z.B. Bahsi, A.Y. Oral, Opt. Mater. 29, 672–678 (2007)
C. Feng, C. Wang, P. Cheng, X. Li, B. Wang, Y. Guan, J. Ma, H. Zhang, Y. Sun, P. Sun, J. Zheng, G. Lu, Sens. Actuators 221, 434–442 (2015)
C. Zhao, J. Fu, Z. Zhang, E. Xie, RSC Adv. 3, 4018–4023 (2013)
C. Sun, G. Maduraiveeran, P. Dutta, Sens. Actuators B 186, 117–125 (2013)
S. Mondal, P.K. Dutta, G.W. Hunter, B.J. Ward, D. Laskowski, R.A. Dweik, Sens. Actuators B 158, 292–298 (2011)
L.-Y. Hong, H.-W. Ke, C.-E. Tsai, H.-N. Lin, Mater. Lett. 185, 243–246 (2016)
J.G. Monroy, J. Gonzalez-Jimenez, J.L. Blanco, Sensors 12, 13664–13680 (2012)
X. Liu, B. Cheng, J. Hu, H. Qin, M. Jiang, Sens. Actuators B 133, 340–344 (2008)
W.-T. Koo, S.-J. Choi, N.-H. Kim, J.-S. Jang, I.-D. Kim, Sens. Actuators B 223, 301–310 (2016)
V. Krivetskiy, A. Ponzoni, E. Comini, S. Badalyan, M. Rumyantseva, A. Gaskova, Electroanalysis 22(23), 2809–2816 (2010)
D. Sett, D. Basak, Sens. Actuators B 243, 475–483 (2017)
J. Liu, T. Wang, B. Wang, P. Sun, Q. Yang, X. Liang, H. Song, Gi Lu, Sens. Actuators B 245, 551–559 (2017)
J. Wang, J. Yang, N. Han, X. Zhou, S. Gong, J. Yang, P. Hu, Y. Chen, Mater. Des. 121, 69–76 (2017)
R. Xu, W. Pang, J. Yu, Q. Huo, J. Chen, (Wiley, Singapore, 2007)
K. Alberti, F. Fetting, Sens. Actuators B 21(1), 39–50 (1994)
X. Xu, J. Wang, Y. Long, Sensors 6, 1751–1764 (2006)
M. Vilaseca, J. Coronas, A. Cirera, A. Cornet, J.R. Morante, J. Santamaria, Catal. Today 82, 179–185 (2003)
M. Vilaseca, J. Coronas, A. Cirera, A. Cornet, J.R. Morante, J. Santamaria, Sens. Actuators B 133, 435–441 (2008)
W.L. Rauch, M. Liu, J. Mater. Sci. 38, 4307–4317 (2003)
A. Zampieri, A. Dubbe, W. Schwieger, A. Avhale, R. Moos, Microporous Mesoporous Mater. 111, 530–535 (2008)
A. Groß, G. Beulertz, I. Marr, D.J. Kubinski, J.H. Visser, R. Moos, Sensors 12, 2831–2850 (2012)
F.I. Khan, A.K. Ghoshal, J. Loss Prev. Process Ind. 13, 527–545 (2000)
E. Liu, B. Sarkar, Z. Chen, R. Naidu, Microporous Mesoporous Mater. 225, 450–455 (2016)
WEB (2017) http://www.niox.com/en/about-niox-products/NIOX-MINO/. Accessed 21 Jul 2017
Acknowledgements
This work was supported by TUBITAK with Project No: 115M658 and Gazi University Scientific Research Fund Project No: 05/2016-21.
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Galioglu, S., Karaduman, I., Çorlu, T. et al. Zeolite A coated Zn1−XCuXO MOS sensors for NO gas detection. J Mater Sci: Mater Electron 29, 1356–1368 (2018). https://doi.org/10.1007/s10854-017-8042-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-017-8042-8