Skip to main content
SpringerLink
Log in

Low temperature sintering and microwave dielectric properties of CoZrNb2O8 ceramics with H3BO3 addition

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

The effects of H3BO3 additive on the sintering behavior, phase composition, microstructure and microwave dielectric properties of CoZrNb2O8 ceramics were investigated based on the research of pure-phase CoZrNb2O8 (CZN) ceramics. When 2.5 wt% H3BO3 was added to CoZrNb2O8 ceramics, the sintering temperatures significantly decreased from 1250 to 1200 °C due to the formation of liquid phase. The ceramic sintered at 1200 °C for 4 h exhibited excellent microwave dielectric properties of ε r = 21.62, Q·f = 40,200 GHz and τ f  = −16.38 ppm/ °C. Compared to the results of CZN ceramics, the H3BO3 additives effectively lowered the sintering temperature of CZN ceramics due to the liquid phase effect without detrimental effect on the properties.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. A.T. Vanderah, Science 298, 1182 (2002)

    Article  Google Scholar 

  2. I.M. Reaney, D. Iddles, J. Am. Ceram. Soc. 89, 2063 (2006)

    Google Scholar 

  3. H. Ohsato, Ceram. Int. 38, S141 (2012)

    Article  Google Scholar 

  4. H.T. Wu, L.P. Zhao, J. Univ. Jinan (Sci. and Tech.) 30, 177 (2016)

    Google Scholar 

  5. J.K. Plourde, D.F. Linn, H.M.J. O’Bryan, J.J. Thompson, J. Am. Ceram. Soc. 58, 418 (1975)

    Article  Google Scholar 

  6. P. Zhang, Z.K. Song, Y. Wang, Y.M. Han, H.L. Dong, L.X. Li, J. Alloys Compd. 581, 741 (2013)

    Article  Google Scholar 

  7. M. Guo, G. Dou, Y.X. Li, S.P. Gong, J. Mater. Sci.: Mater. Electron. 26, 608 (2015)

    Google Scholar 

  8. G.G. Yao, C.J. Pei, J.G. Xu, P. Liu, J.P. Zhou, H.W. Zhang, J. Mater. Sci.: Mater. Electron. 26, 7719 (2015)

    Google Scholar 

  9. R. Muhammad, Y. Iqbal, J. Mater. Sci. Mater. Electron. 26, 9092 (2015)

    Article  Google Scholar 

  10. A. Manan, D.N. Khan, A. Ullah, J. Mater. Sci. Mater. Electron. 26, 2066 (2015)

    Article  Google Scholar 

  11. A. Baumgarte, R. Blachnik, J. Alloys Compd. 215, 117 (1994)

    Article  Google Scholar 

  12. S.D. Ramarao, V.R.K. Murthy, Scr. Mater. 69, 274 (2013)

    Article  Google Scholar 

  13. H.T. Wu, Z.B. Feng, Q.J. Mei, J.D. Guo, J.X. Bi, J. Alloys Compd. 648, 368 (2015)

    Article  Google Scholar 

  14. M.T. Sebastian, H. Jantunen, Int. Mater. Rev. 53, 57 (2008)

    Article  Google Scholar 

  15. Y.C. Zhang, Z.X. Yue, Z.L. Gui, L.T. Li, J. Electroceram. 14, 67 (2005)

    Article  Google Scholar 

  16. X.P. Lu, Y. Zheng, B. Zhou, J. Electroceram. 31, 360 (2013)

    Article  Google Scholar 

  17. T.W. Zhang, R.Z. Zuo, Cream. Int. 40, 15677 (2014)

    Article  Google Scholar 

  18. H.T. Wu, J.D. Guo, J.X. Bi, Q.J. Mei, J. Alloys Compd. 661, 535 (2016)

    Article  Google Scholar 

  19. H.M. Rietveld, J. Appl. Crystallogr. 2, 65 (1969)

    Article  Google Scholar 

  20. B.W. Hakki, P.D. Coleman, IEEE Trans. 8, 402 (1960)

    Google Scholar 

  21. W.E. Courtney, IEEE Trans. 18, 476 (1970)

    Google Scholar 

  22. K.M. Manu, P.S. Anjana, M.T. Sebastian, Mater. Lett. 65, 565 (2011)

    Article  Google Scholar 

  23. P.V. Bijumon, M.T. Sebastian, Mater. Sci. Eng. B 123, 31 (2005)

    Article  Google Scholar 

  24. S.D. Ramarao, V.R.K. Murthy, Dalton Trans. 44, 2311 (2015)

    Article  Google Scholar 

  25. L.X. Li, H. Sun, H.C. Cai, X.S. Lv, J. Alloys Compd. 639, 516 (2015)

    Article  Google Scholar 

  26. R.D. Shannon, J. Appl. Phys. 73, 348 (1993)

    Article  Google Scholar 

  27. A.J. Bosman, E.E. Havinga, Phys. Rev. 129, 1593 (1963)

    Article  Google Scholar 

  28. D.H. Kang, K.C. Nam, H.J. Cha, J. Eur. Ceram. Soc. 26, 2117 (2006)

    Article  Google Scholar 

  29. Q. Zeng, W. Li, J.L. Shi, J.K. Guo, H. Chen, M.L. Liu, J. Eur. Ceram. Soc. 27, 261 (2007)

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by the project development plan of science and technology of Jinan City (No. 201303061), Jinan City Youth Science and Technology Star Project (No. 2013035), the National Training Plan Innovation Project of college students (No. 201510427001) and National Natural Science Foundation (No. 51472108) and Study Abroad Programs by Shandong Province Government.

Author information

Authors and Affiliations

  1. School of Materials Science and Engineering, University of Jinan, Jinan, 250022, China

    J. X. Bi, C. F. Xing, X. S. Jiang, C. H. Yang & H. T. Wu

Authors
  1. J. X. Bi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. C. F. Xing
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. X. S. Jiang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. C. H. Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. H. T. Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to H. T. Wu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bi, J.X., Xing, C.F., Jiang, X.S. et al. Low temperature sintering and microwave dielectric properties of CoZrNb2O8 ceramics with H3BO3 addition. J Mater Sci: Mater Electron 27, 6564–6569 (2016). https://doi.org/10.1007/s10854-016-4601-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-016-4601-7

Keywords

Search

Navigation