Abstract
<001> oriented 0.91Bi1/2Na1/2TiO3–0.06BaTiO3–0.03(Na,K)NbO3 (BNT–BT–KNN) lead-free piezoceramics were fabricated by templated grain growth method. A high grain orientation degree (Lotgering factor F is 83 %) was achieved with 5 wt% Bi1/2Na1/2TiO3 (BNT) template content and a maximum strain value of 0.226 % was observed, which was 48.7 % higher than that of randomly oriented samples. However, too much BNT template will result in composition deviation from morphotropic phase boundary of BNT–BT–KNN system and disruption of the non-polar phase at zero electric field. All textured samples with 1–10 wt% template addition showed enhanced strain and large signal piezoelectric coefficient \(d_{33}^{*}\) without disrupting the non-polar phase at zero electric field. The enhanced electric-field-induced strain of the textured sample was primarily attributed to the facilitated phase-transition, which formed a long-range ferroelectric order along the <001> direction.
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The authors acknowledge also the generous support by the National Natural Science Foundation of China under Grant No. 51202074.
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Ma, S., Zhang, Y., Liu, Z. et al. Preparation and enhanced electric-field-induced strain of textured 91BNT–6BT–3KNN lead-free piezoceramics by TGG method. J Mater Sci: Mater Electron 27, 3076–3081 (2016). https://doi.org/10.1007/s10854-015-4132-7
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DOI: https://doi.org/10.1007/s10854-015-4132-7