Abstract
Research on the semiconductors available for thermal neutron detection is of great significance for the development of thermal neutron detection technology and alleviating the dependence on rare \(^3\)He resources. Hexagonal boron nitride (h-\(^{10}\)BN) materials have attracted wide attention in the thermal neutron detection field because of their higher \(^{10}\)B content and unique two-dimensional layered lattice structure. Based on the metal organic chemical vapor deposition (MOCVD) method, a 70 \(\upmu \hbox {m}\) h-\(^{10}\)BN semiconductor detector was fabricated and experimentally studied. The product of the carrier mobility and lifetime (\(\mu \tau\)) of the semiconductor was 1.62\(\times 10^{-7}\) \(\hbox {cm}^2\)/V. The time response of the detector was less than 12 ns, and the charge collection efficiency (CCE) was more than 90%. The effects on detection performance of the electric field distribution were studied. At 700 V, the maximum depth at which charges were able to be collected was approximately 50 \(\upmu \hbox {m}\). The energy spectrum of the h-\(^{10}\)BN to thermal neutrons was observed with distinct peaks. The results indicate that h-\(^{10}\)BN has great potential in thermal neutron detection due to its high reaction section, compact volume and short trapping distance.
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Vitullo F, Lamirand V, Mosset J-B, Frajtag P, Pakari O, Perret G, Pautz A (2020) A mm\(^{3}\) fiber-coupled scintillator for in-core thermal neutron detection in CROCUS. IEEE Trans. Nucl. Sci. 67(4):625–635
Miller SR, Marshall MSJ, Wart M, Crha J, Trtik P, Nagarkar VV (2020) High-resolution thermal neutron imaging with \(^{10}\)Boron/CsI: tl scintillator screen. IEEE Trans. Nucl. Sci. 67(8):1929–1933
Hidaka H, Mizutani Y, Yoneda S (2020) Estimation of thermal and epithermal neutron fluences at the lunar surface from isotopic compositions of rare earth elements. Astrophys. J. 904(2):183
Boffy R, Martel L, Schweins R, Somers J, Beaucour J, Bermejo FJ (2021) A NMR and SANS study of alkali-borosilicate behaviour under thermal neutron irradiation. J. Nucl. Mater. 544(152699):152699
Testov DA, Briançon C, Dmitriev SN, Yeremin AV, Penionzhkevich YE, Pyatkov YV, Sokol EA (2009) Applications of \(^{3}\)He neutron detectors. Phys. At. Nucl. 72(1):1–5
Fares M, Messai A, Begaa S, Salem M, Negara K, Debili MY, Messaoudi M (2021) \(^{3}\)He proportional counter development for thermal neutron detection. Radiat. Detect. Technol. Meth. 5(2):264–272
Wang CL (2021) Gd-containing scintillators for thermal neutron detection via graph-based particle discrimination. Rev. Sci. Instrum. 92(10):103304
Vuong PQ, Kim HJ, Khan A, Khan S, Kim SH, Park H, Kim J (2020) Silver-doped LiI crystal: a sensitive thermal neutron detector with pulse shape discrimination. IEEE Trans. Nucl. Sci. 67(10):2290–2294
Zhu Z, Sun Z, Zou J, Tang B, Xiu Q, Wang R, Qu J, Deng W, Wang S, Peng J, Wang Z, Tang B, Zhang H (2020) Fabrication and performance evaluation of GaN thermal neutron detectors with \(^{6}\)LiF conversion layer. Chin. Physics B 29(9):090401
Lee C-Y, Ban C-M, Lee H-R, Choo K-N, Jun B-H (2019) Thermal and fast neutron detection through high-purity single-crystal CVD diamonds. Appl. Radiat. Isot. 152:25–29
Tupitsyn E, Bhattacharya P, Rowe E, Matei L, Groza M, Wiggins B, Burger A, Stowe A (2012) Single crystal of LiInSe\(_{2}\) semiconductor for neutron detector. Appl. Phys. Lett. 101(20):202101
Jiang Y, Wu J, Yin Y, Lu Y, Wu K, Fan X, Lei J (2019) Improving thermal-neutron detection efficiency of silicon neutron detectors using the combined layers of \(^{10}\)B\(_{4}\)C on \(^{6}\)LiF. Nucl. Instrum. Methods Phys. Res. A 932:50–55
Camacho-Mojica DC, López-Urías F (2016) Extended line defects in BN, GaN, and AlN semiconductor materials: Graphene-like structures. Chem. Phys. Lett. 652:73–78
Croci G, Muraro A, Cippo EP, Tardocchi M, Grosso G, Albani G, Angella G, Defendi I, Hall-Wilton R, Höglund C, Raspino D, Rhodes N, Robinson L, Schmidt S, Schooneveld E, Zeitelhack K, Gorini G (2018) A high-efficiency thermal neutron detector based on thin 3D \(^{10}\)B \(_{4}\)C converters for high-rate applications. EPL (Europhysics Letters) 123(5):52001
Roth M, Mojaev E, Khakhan O, Fleider A, Dul’kin E, Schieber M (2014) Composite boron nitride neutron detectors. J. Cryst. Growth 401:791–794
McGregor DS, Unruh TC, McNeil WJ (2008) Thermal neutron detection with pyrolytic boron nitride. Nucl. Instrum. Methods Phys. Res. A 591(3):530–533
Hushur A, Manghnani MH, Werheit H, Dera P, Williams Q (2016) High-pressure phase transition makes boron carbide a wide-gap semiconductor. J. Phys. Condens. Matter 28(4):045403
Chica DG, He Y, McCall KM, Chung DY, Pak RO, Trimarchi G, Liu Z, De Lurgio PM, Wessels BW, Kanatzidis MG (2020) Direct thermal neutron detection by the 2D semiconductor \(^{6}\)LiInP\(_{2}\)Se\(_{6}\). Nature 577(7790):346–349
Maity A, Grenadier SJ, Li J, Lin JY, Jiang HX (2021) Hexagonal boron nitride: epitaxial growth and device applications. Prog. Quantum Electron. 76(100302):100302
Roy S, Zhang X, Puthirath AB, Meiyazhagan A, Bhattacharyya S, Rahman MM, Babu G, Susarla S, Saju SK, Tran MK, Sassi LM, Saadi MASR, Lai J, Sahin O, Sajadi SM, Dharmarajan B, Salpekar D, Chakingal N, Baburaj A, Shuai X, Adumbumkulath A, Miller KA, Gayle JM, Ajnsztajn A, Prasankumar T, Harikrishnan VVJ, Ojha V, Kannan H, Khater AZ, Zhu Z, Iyengar SA, Autreto PAdS, Oliveira EF, Gao G, Birdwell AG, Neupane MR, Ivanov TG, Taha-Tijerina J, Yadav RM, Arepalli S, Vajtai R, Ajayan PM (2021) Structure properties and applications of two-dimensional hexagonal boron nitride. Adv Mater. 33(44):2101589
Maity A, Doan TC, Li J, Lin JY, Jiang HX (2016) Realization of highly efficient hexagonal boron nitride neutron detectors. Appl. Phys. Lett. 109(7):072101
Doan TC, Li J, Lin JY, Jiang HX (2016) Bandgap and exciton binding energies of hexagonal boron nitride probed by photocurrent excitation spectroscopy. Appl. Phys. Lett. 109(12):122101
Li J, Dahal R, Majety S, Lin JY, Jiang HX (2011) Hexagonal boron nitride epitaxial layers as neutron detector materials. Nucl. Instrum. Methods Phys. Res. A 654(1):417–420
Ahmed K, Dahal R, Weltz A, Lu JJ-Q, Danon Y, Bhat IB (2017) Metalorganic chemical vapor deposition of hexagonal boron nitride on (001) sapphire substrates for thermal neutron detector applications. Vacuum 137:81–84
Maity A, Grenadier SJ, Li J, Lin JY, Jiang HX (2019) High sensitivity hexagonal boron nitride lateral neutron detectors. Appl. Phys. Lett. 114(22):222102
Mballo A, Ahaitouf A, Sundaram S, Srivastava A, Ottapilakkal V, Gujrati R, Vuong P, Karrakchou S, Kumar M, Li X, Halfaya Y, Gautier S, Voss PL, Salvestrini JP, Ougazzaden A (2022) Natural boron and \(^{10}\)B-enriched hexagonal boron nitride for high-sensitivity self-biased metal-semiconductor-metal neutron detectors. ACS Omega 7(1):804–809
Ahmed K, Dahal R, Weltz A, Lu J-Q, Danon Y, Bhat IB (2016) Growth of hexagonal boron nitride on (111) Si for deep UV photonics and thermal neutron detection. Appl. Phys. Lett. 109(11):113501
Meng J, Wang D, Cheng L, Gao M, Zhang X (2019) Recent progress in synthesis, properties, and applications of hexagonal boron nitride-based heterostructures. Nanotechnology 30(7):074003
Doan TC, Li J, Lin JY, Jiang HX (2014) Charge carrier transport properties in layer structured hexagonal boron nitride. AIP Adv. 4(10):107126
Grenadier S, Maity A, Li J, Lin JY, Jiang HX (2019) Lateral charge carrier transport properties of B-10 enriched hexagonal BN thick epilayers. Appl. Phys. Lett. 115(7):072108
Doan TC, Li J, Lin JY, Jiang HX (2017) Response of alpha particles in hexagonal boron nitride neutron detectors. Appl. Phys. Lett. 110(21):213502
Almohammad M, Li J, Lin JY, Jiang HX (2021) Charge collection and trapping mechanisms in hexagonal boron nitride epilayers. Appl. Phys. Lett. 119(22):221111
Maity A, Grenadier SJ, Li J, Lin JY, Jiang HX (2020) High efficiency hexagonal boron nitride neutron detectors with 1 cm\(^{2}\) detection areas. Appl. Phys. Lett. 116(14):142102
Ahmed K, Dahal R, Weltz A, Lu JJ-Q, Danon Y, Bhat IB (2017) Solid-state neutron detectors based on thickness scalable hexagonal boron nitride. Appl. Phys. Lett. 110(2):023503
Jiang HX, Lin JY (2017) Review–hexagonal boron nitride epilayers: growth, optical properties and device applications. ECS J. Solid State Sci. Technol. 6(2):3012–3021
Tingsuwatit A, Maity A, Grenadier SJ, Li J, Lin JY, Jiang HX (2022) Boron nitride neutron detector with the ability for detecting both thermal and fast neutrons. Appl. Phys. Lett. 120(23):232103
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This work is funded by The National Natural Science Foundation of China (No. 12050005, 12105230).
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HS contributed to methodology, formal analysis, writing–original draft preparation. WF contributed to methodology, validation, supervision. CL contributed to conceptualization, writing–review and editing. LY contributed to investigation, visualization, software. RJ contributed to data curation, funding acquisition. OX contributed to conceptualization, project administration.
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He, S., Wang, F., Chen, L. et al. The performance of a high-resistance semiconductor detector based on h-\(^{10}\)BN with thermal neutron detection capability. J Mater Sci 58, 12288–12297 (2023). https://doi.org/10.1007/s10853-023-08795-8
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DOI: https://doi.org/10.1007/s10853-023-08795-8