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Fabrication and self-assembly of the tetrahedron dimpled colloidal particles

  • Polymers & biopolymers
  • Published:
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Abstract

Highly monodisperse, tetrahedral colloidal particles featuring four spherical dimples arranged symmetrically one per face were synthesized via classical seeded polymerization. The depth and number of dimples on the surface of the particles could be precisely tuned by varying the operation parameters including temperature, the compound solvent polarity, and 2-ethylhexylmethacrylate (EHMA) monomer concentration. The formation mechanism of the anisotropic colloidal particles was ascribed to the phase separation of polystyrene phase and PEHMA phase. Furthermore, the obtained tetrahedron dimpled colloidal particles were assembled with well-matched spherical particles via depletion interaction and centrifugal force, forming a colloidal cluster with a well-defined complex structure. These anisotropic colloidal particles and the various structures assembled from them can be used potentially as the basic building blocks to construct multi-dimension materials.

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Acknowledgements

We gratefully acknowledge the support of National Natural Science Foundation of China (Grant No. 52076082).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Guangdong Provincial Key Lab of Green Chemical Product Technology, South China University of Technology, Guangzhou, 510640, People’s Republic of China

    Xiaofeng Huang, Liujun Song, Xiang Jiang & Xinya Zhang

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  1. Xiaofeng Huang
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  2. Liujun Song
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  3. Xiang Jiang
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  4. Xinya Zhang
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Correspondence to Xiang Jiang or Xinya Zhang.

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Huang, X., Song, L., Jiang, X. et al. Fabrication and self-assembly of the tetrahedron dimpled colloidal particles. J Mater Sci 57, 7400–7415 (2022). https://doi.org/10.1007/s10853-022-07087-x

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