Abstract
High-performance CX stainless steel was successfully manufactured using selective laser melting (SLM) technology, and different types of post-heat treatments were adopted for ameliorating the mechanical properties of as-built specimens. The microstructure evolution process (i.e., cell structures, cellular dendritic grains and blocky grains containing substructures) was explained using the rapid solidification theory after SLM. Nanoprecipitates and their hardening behavior in the SLM CX stainless steels in the as-built and solution-aged state were detected by transmission electron microscope (TEM). The results of high-resolution TEM showed that the massive needle-like nanoprecipitates with a size range of 3–25 nm (as-built sample) and 7–30 nm (solution-aged sample) were evenly distributed in the martensite matrix. In the meantime, the strengthening mechanism was analyzed and discussed. Moreover, various post-heat treatments exhibited a great influence upon the mechanical performances of the SLM CX stainless steel samples. The average micro-hardness of the SLM CX stainless steel parts was found to extremely improve from 357 HV0.2 (as-built sample) to 514 HV0.2 (solution-aged sample). On the contrary, the total impact energy (Wt) of the SLM CX stainless steel parts decreased from 83.8 J in the as-built condition to 5.3 J in the solution-aged condition.
Similar content being viewed by others
References
Fakić B, Ćubela D (2013) Review of the Development of Research in the Design of Semi Austenitic Stainless Steel 17-7PH. J Trends Dev Mach Assoc Technol 17(1):57–60
Materials Information Company (1991) ASM International Handbook Committee. Properties and selection: irons steels and high performance alloys. ASM Handbook, pp 1872–1873. https://doi.org/10.31399/asm.hb.v01.a0001046
Guo Z, Sha W, Vaumousse D (2003) Microstructural evolution in a PH13-8 stainless steel after ageing. Acta Mater 51:101–116. https://doi.org/10.1016/S1359-6454(02)00353-1
Alafaghani A, Qattawi A, Castañón MAG (2018) Effect of manufacturing parameters on the microstructure and mechanical properties of metal laser sintering parts of precipitate hardenable metals. Int J Adv Manuf Technol 99:2491–2507. https://doi.org/10.1007/s00170-018-2586-5
Thomas G, Bell WL, Otte HM (1965) Interpretation of electron diffraction patterns from thin platelets. Phys Status Solidi B 12:353–366
Nakagawa H, Miyazaki T, Yokota H (2000) Effects of aging temperature on the microstructure and mechanical properties of 1.8Cu-7.3Ni-15.9Cr-1.2Mo-low C, N martensitic precipitation hardening stainless steel. J Mater Sci 35:2245–2253. https://doi.org/10.1023/A:1004778910345
Sen D, Patra AK, Mazumder S et al (2004) Carbide precipitates in solution-quenched PH13-8 Mo stainless steel: a small-angle neutron scattering investigation. Pramana J Phys 63:321–326. https://doi.org/10.1007/BF02704992
Hsiao CN, Chiou CS, Yang JR (2002) Aging reactions in a 17-4 PH stainless steel. Mater Chem Phys 74:134–142. https://doi.org/10.1016/S0254-0584(01)00460-6
Li X, Zhang J, Wang Y et al (2016) Effect of hydrogen on tensile properties and fracture behavior of PH 13-8 Mo steel. Mater Des 108:608–617. https://doi.org/10.1016/j.matdes.2016.06.110
Aizawa T, Yoshino T, Morikawa K, Yoshihara SI (2019) Microstructure of plasma nitrided AISI420 martensitic stainless steel at 673 K. Crystals. https://doi.org/10.3390/cryst9020060
Matsuzawa C, Yasuhara T, Nishizawa H, Aoki N, Takano MK (2019) Manufacturing method of mechanical component using martensitic stainless steel, rotating device, rolling bearing and rolling bearing unit. US Patent 10,494,692, 3 Dec 2019
Yan X, Chen C, Zhao R et al (2018) Selective laser melting of WC reinforced maraging steel 300: microstructure characterization and tribological performance. Surf Coat Technol 371:355–365. https://doi.org/10.1016/j.surfcoat.2018.11.033
Yan X, Yin S, Chen C et al (2018) Effect of heat treatment on the phase transformation and mechanical properties of Ti6Al4V fabricated by selective laser melting. J Alloys Compd 764:1056–1071. https://doi.org/10.1016/j.jallcom.2018.06.076
Yan X, Li Q, Yin S et al (2019) Mechanical and in vitro study of an isotropic Ti6Al4V lattice structure fabricated using selective laser melting. J Alloys Compd 782:209–223. https://doi.org/10.1016/j.jallcom.2018.12.220
Gardan J (2017) Additive manufacturing technologies: state of the art and trends. Addit Manuf Handb Prod Dev Def Ind 7543:149–168. https://doi.org/10.1201/9781315119106
Vithani K, Goyanes A, Jannin V et al (2019) An overview of 3D printing technologies for soft materials and potential opportunities for lipid-based drug delivery systems. Pharm Res. https://doi.org/10.1007/s11095-018-2531-1
Chen C, Xie Y, Yan X et al (2019) Effect of hot isostatic pressing (HIP) on microstructure and mechanical properties of Ti6Al4V alloy fabricated by cold spray additive manufacturing. Addit Manuf 27:595–605. https://doi.org/10.1016/j.addma.2019.03.028
Huang C, Yan X, Zhao L et al (2019) Ductilization of selective laser melted Ti6Al4V alloy by friction stir processing. Mater Sci Eng, A 755:85–96. https://doi.org/10.1016/j.msea.2019.03.133
Murr LE, Martinez E, Hernandez J et al (2012) Microstructures and properties of 17-4 PH stainless steel fabricated by selective laser melting. J Mater Res Technol 1:167–177. https://doi.org/10.1016/S2238-7854(12)70029-7
EOS GmbH—Electro Optical Systems (2019) EOS Stainless Steel 17-4PH. https://www.eos.info/en
Sarkar S, Mukherjee S, Kumar CS, Kumar Nath A (2020) Effects of heat treatment on microstructure, mechanical and corrosion properties of 15-5 PH stainless steel parts built by selective laser melting process. J Manuf Process 50:279–294. https://doi.org/10.1016/j.jmapro.2019.12.048
Yin S, Chen C, Yan X et al (2018) The influence of aging temperature and aging time on the mechanical and tribological properties of selective laser melted maraging 18Ni-300 steel. Addit Manuf 22:592–600. https://doi.org/10.1016/j.addma.2018.06.005
Palousek D, Kocica M, Pantelejev L et al (2019) SLM process parameters development of Cu-alloy Cu7.2Ni1.8Si1Cr. Rapid Prototype J 25:266–276. https://doi.org/10.1108/RPJ-06-2017-0116
GmbH E (2019) Material data sheet—FlexLine EOS StainlessSteel CX. https://cdn0.scrvt.com/eos/1801f2663ea474ba/efe087ff3cad/StainlessSteel-CX-M280_Material_data_sheet_09-15_en.pdf
Harvey RF, Lake O (1972) Precipitation hardening steel
Utsunomiya T, Hoshino K, Hirotsu S (1991) Martensitic precipitation-hardenable stainless steel
ASTM E 23–12c (2013) Standard test methods for notched bar impact testing of metallic materials. Standards 1:1–25. https://doi.org/10.1520/E0023-12C.2
Yao C, Xu B, Huang J et al (2010) Study on the softening in overlapping zone by laser-overlapping scanning surface hardening for carbon and alloyed steel. Opt Lasers Eng 48:20–26. https://doi.org/10.1016/j.optlaseng.2009.05.001
Li Y, Gu D (2014) Thermal behavior during selective laser melting of commercially pure titanium powder: numerical simulation and experimental study. Addit Manuf 1:99–109. https://doi.org/10.1016/j.addma.2014.09.001
Tiller WA, Jackson KA, Rutter JW, Chalmers B (1953) The redistribution of solute atoms during the solidification of metals. Acta Metall 1:428–437
Rutter JW, Chalmers B (1953) A prismatic substructure formed during solidification of metals. Can J Phys 31:15–39. https://doi.org/10.1139/p53-003
Mullins WW, Sekerka RF (1964) Stability of a planar interface during solidification of a dilute binary alloy. J Appl Phys 35:444–451. https://doi.org/10.1063/1.1713333
Mullins WW, Sekerka RF (1963) Morphological stability of a particle growing by diffusion or heat flow. J Appl Phys 34:323–329. https://doi.org/10.1063/1.1702607
Baker JC, Gahn JW (1969) Solute trapping by rapid solidification. Acta Metall 17:575–578. https://doi.org/10.1016/0001-6160(69)90116-3
Liu F, Sommer F, Bos C, Mittemeijer EJ (2007) Analysis of solid state phase transformation kinetics: models and recipes. Int Mater Rev 52:193–212. https://doi.org/10.1179/174328007X160308
Vasudevan VK, Kim SJ, Wayman CM (1990) Precipitation reactions and strengthening behavior in 18 Wt Pct nickel maraging steels. Metall Trans A Phys Metall Mater Sci 21:2655–2668. https://doi.org/10.1007/BF02646061
Morris JW (2011) On the ductile-brittle transition in lath martensitic steel. ISIJ Int 51:1569–1575. https://doi.org/10.2355/isijinternational.51.1569
American Society for Testing and Materials (2018) E2298-18: standard test method for instrumented impact testing of metallic materials. https://doi.org/10.1520/E2298-18.2
Marietta M, Systems E (2008) Charpy impact test results on five materials and 2-mm A N D 8-mm Strikers * portions of this document may be eligible in electronic image products. Images are produced from the best available original
Acknowledgements
As one of the authors, Cheng Chang is grateful for the financial support from the program of China Scholarship Council (Grant #: 201801810106). As one of the authors, Xingchen Yan, is grateful for the financial supports provided founds of Sciences Platform Environment and Capacity Building Projects of GDAS (Grant #: 2019GDASYL-0402006, 2019GDASYL-0502006, 2019GDASYL-0402004, 2018GDASCX-0402, 2018GDASCX-0111 and 2019GDASYL-0501009), Guangzhou Project of Science & Technology (Grant #: 201909010008, 201807010030), Guangdong province Science and Technology Plan Projects (Grant #: 2017A070701027, 2017A070702016, 2014B070705007 and 2017B030314122).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Chang, C., Yan, X., Bolot, R. et al. Influence of post-heat treatments on the mechanical properties of CX stainless steel fabricated by selective laser melting. J Mater Sci 55, 8303–8316 (2020). https://doi.org/10.1007/s10853-020-04566-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-020-04566-x